Partial Least Square
Mostrando 1-12 de 91 artigos, teses e dissertações.
-
1. QUANTITATIVE SPECIATION OF THE LIQUID PHASE BY FTIR SPECTROSCOPY IN THE SYSTEM AMP-PZ-CO2-H2O
This work reports a multivariate calibration partial least square regression (PLS) model to quantify the liquid-phase concentrations of 2-amino-2-methyl-1-propanol (AMP), piperazine (PZ), bicarbonate, PZ monocarbamate, and PZ dicarbamate during the absorption/desorption process by Fourier Transform Mid-Infrared spectroscopy (mid-FTIR). The model could predic
Química Nova. Publicado em: 2022
-
2. Simultaneous Quantification of Amorphous and Crystalline Valsartan in Tablets Using Raman Spectroscopy and Chemometrics Tools
Valsartan is an antihypertensive active pharmaceutical ingredient (API), it is used in the amorphous state in the commercial products. As amorphous materials are metastable, amorphous valsartan can crystallize to valsartan E, promoting changes in the dissolution and bioavailability of the drug. Tablets containing metastable forms of APIs need special conditi
Journal of the Brazilian Chemical Society. Publicado em: 2022
-
3. DETERMINING FACTORS OF ENTREPRENEURIAL INTENTION: A STUDY WITH ENTREPRENEURS AND POTENTIAL ENTREPRENEURS OF THE STATE OF ACRE
RESUMO Objetivo - Analisar, sob a ótica da Teoria do Comportamento Planejado, os fatores determinantes da intenção empreendedora de empreendedores e potenciais empreendedores do Acre. Design / metodologia / abordagem - A pesquisa abrangeu egressos do Seminário Empretec (SEBRAE), utilizando a metodologia quantitativa de Modelagem em Equações Estrutu
Revista de Administração da UFSM. Publicado em: 2022
-
4. Quantification of Carbon Dioxide (CO2), Methane (CH4), and Nitrous Oxide (N2O) Using Near Infrared Spectroscopy and Multivariate Calibration in High Humidity Levels
In this work we developed a promising analytical method combining Fourier transform near-infrared (FT-NIR) spectroscopic technique and first-order multivariate calibration using partial least-squares (PLS) model to simultaneously quantify the main greenhouse gases (GHG’s): methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and water vapor (H2O). The
Journal of the Brazilian Chemical Society. Publicado em: 2022
-
5. PhotoMetrix UVC: A New Smartphone-Based Device for Digital Image Colorimetric Analysis Using PLS Regression
A novel free PhotoMetrix UVC is proposed for both the operation of a universal serial bus video camera (UVC) and multivariate image analysis, allowing a full solution for point-of-use analysis. A UVC was placed in an open-source 3D-printed chamber illuminated by a white light-emitting diode (LED) with controlled intensity of light. The digital images capture
J. Braz. Chem. Soc.. Publicado em: 2021-03
-
6. Quick Identification of the Time of Maturation of Artisanal Minas Cheese by FTIR-ATR Spectroscopy and Multivariate Techniques
The objective of this work is the identification of cheese maturation time using attenuated total reflection Fourier transform spectroscopy (FTIR-ATR) data and analytical measurements associated with chemometrics techniques. Minas artisanal cheeses were collected from 8 producers matured at times 1, 7, 14, 21, 28, 45 and 60 days, fractioned in rind and crumb
J. Braz. Chem. Soc.. Publicado em: 2020-10
-
7. Determination of Ethanol in Gel Hand Sanitizers Using Mid and Near Infrared Spectroscopy
Alcohol-based gel hand sanitizers became very popular during the COVID-19 (coronavirus disease 2019) pandemic. In Brazil, several irregular factories emerged requiring an efficient control by the police and regulatory agencies to guarantee product quality. This problem required a method to determine ethanol content, which led to the development of two method
J. Braz. Chem. Soc.. Publicado em: 2020-09
-
8. 1H NMR and Chemometric Methods to Estimate the Octane Number in Brazilian C Gasolines
Brazilian gasoline type C can be purchased with octane number as the main difference. This quality parameter directly affects the price. Intermediate formulations may not be easily distinguished from conform samples due to similarity in visual appearance and physicochemical properties. The use of anhydrous ethanol as an additive also influences the octane va
J. Braz. Chem. Soc.. Publicado em: 2020-08
-
9. Prediction of quality parameters of food residues using NIR spectroscopy and PLS models based on proximate analysis
Abstract The real-time prediction in biorefinery industries has become essential. Models using partial least square regression (PLS) were developed to predict moisture, ash, volatile matter, fixed carbon and organic matter of coconut and coffee residues. In this study, 49 samples were collected and near infrared spectroscopy were applied to predict moisture,
Food Sci. Technol. Publicado em: 2020-06
-
10. Prediction of quality parameters of food residues using NIR spectroscopy and PLS models based on proximate analysis
Abstract The real-time prediction in biorefinery industries has become essential. Models using partial least square regression (PLS) were developed to predict moisture, ash, volatile matter, fixed carbon and organic matter of coconut and coffee residues. In this study, 49 samples were collected and near infrared spectroscopy were applied to predict moisture,
Food Sci. Technol. Publicado em: 28/10/2019
-
11. Influence of Particles Size on NIR Spectroscopic Estimations of Charcoal Properties
ABSTRACT The objective of this study was to evaluate the influence of particle size of charcoal samples on the predictive model statistics of charcoal chemical composition based on the NIR spectroscopy. Spectra of Acacia and of Eucalyptus charcoal were collected in the 100, 60 and 40 mesh granulometry, besides the powder remaining at the bottom of the sieves
Floresta Ambient.. Publicado em: 09/09/2019
-
12. A Regional Legacy Soil Dataset for Prediction of Sand and Clay Content with Vis-Nir-Swir, in Southern Brazil
ABSTRACT The success of soil prediction by VIS-NIR-SWIR spectroscopy has led to considerable investment in large soil spectral libraries. The aims of this study were 1) to develop a soil VIS-NIR-SWIR spectroscopy approach using legacy soil samples to improve spectral soil information in a regional scale; (2) to compare six spectral preprocessing techniques;
Rev. Bras. Ciênc. Solo. Publicado em: 15/08/2019