Oxidation
Mostrando 1-12 de 6602 artigos, teses e dissertações.
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1. Bimetallic Au-Pd/α-MoO3 Catalyst with High Oxygen Vacancies for Selective Oxidation of Cinnamyl Alcohol
Supported Au-Pd nanoparticles (NPs) have been extensively studied in alcohol oxidation reactions. However, few studies use reducible metal oxides as support, which can activate oxygen molecules and boost the selectivity of the reaction. In this work, Au-Pd NPs were supported on α-MoO3 and evaluated in the selective oxidation of cinnamyl alcohol without solv
Journal of the Brazilian Chemical Society. Publicado em: 2023
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2. SALICILATOS COMO INIBIDORES DO PROCESSO OXIDATIVO MEDIADO POR COBRE E FERRO NO BIODIESEL B100
Biodiesel is a renewable fuel produced from vegetable oils and animal fats transesterification. However, due to its chemical characteristics, it is susceptible to oxidation causing losses to its manufacturers and users. In this work a series of salicylates were synthesized and employed as secondary antioxidants in biodiesel B100. The accelerated oxidation te
Química Nova. Publicado em: 2022
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3. Boosting the Photocurrent of the WO3/BiVO4 Heterojunction by Photoelectrodeposition of the Oxy-Hydroxide-Phosphates Based on Co, Fe, or Ni
Here we investigated the photoelectrodeposition of oxygen-evolving catalysts (OECs) based on oxy-hydroxides-phosphates of Co, Fe, or Ni (CoPi, FePi, and NiPi) on the WO3/BiVO4 heterojunction and their activity in water oxidation. The OECs were deposited by cycles of (i) open-circuit potential (OCP) and (ii) applying a potential positive enough to oxidize the
Journal of the Brazilian Chemical Society. Publicado em: 2022
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4. Heterogeneous Fenton-like catalytic degradation of phenazine dye over CeO2 (CP-2) nanoscale powder
Abstract A heterogeneous Fenton-like process was explored for oxidation of phenazine dye using ceria polishing material (CP-2). XRD, SEM, FTIR, UV-vis DRS, and pHPZC techniques were applied to characterize the catalyst features. The performance of the heterogeneous Fenton-like process was investigated under various parameters (reaction time, pH, H2O2 concent
Cerâmica. Publicado em: 2022
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5. The Influence of the Platinum Weight Percentage in the Catalyst Formulation on the Performance of a High Temperature Ethanol Electroreformer Based on H3PO4 Doped Polybenzimidazole for Green Hydrogen Production
A vapor-fed high temperature proton exchange ethanol electroreformer has been developed based on the use of a H3PO4-doped polybenzimidazole membrane to produce green hydrogen. As a key parameter, this article describes the influence of platinum weight percent (wt.%) in the catalyst formulation from different commercial catalysts (20, 40, 60, 80 wt.% Pt/C and
Journal of the Brazilian Chemical Society. Publicado em: 2022
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6. Iron Cobaltite (FeCo2O4) Nanocatalysts for Water-Oxidation: Effects of Annealing Temperature on Catalytic Properties
The development of efficient, stable, and non-precious metal water oxidation catalysts (WOCs) is a matter of importance for sustainable energy research. In this work, iron cobaltite (FeCo2O4) nanoparticles were prepared by the coprecipitation method, and we present the effect of heat treatment (250, 350, 450, 650 and 900 °C) on the catalytic properties. Cat
Journal of the Brazilian Chemical Society. Publicado em: 2022
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7. A Simple, Rapid, and Reliable Titrimetric Method for the Determination of Glycerol at Low Concentration
Glycerol can be determined in several products by various analytical techniques. Titrimetric ones have stood out for their low cost, being recommended as standards. However, reliable, simple, fast, and green methods with low quantification limits are still needed. Titration of glycerol is based on its oxidation by periodate (Malaprade reaction) producing for
Journal of the Brazilian Chemical Society. Publicado em: 2022
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8. Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables
Conductive polymers are versatile materials that can be applied in many different technology fields, especially green energy. They have several advantages, such as easy synthesis, low density, and cost. However, its electric conduction property is also related to material aging with great loss of their characteristics, limiting their applicability. The in-de
Journal of the Brazilian Chemical Society. Publicado em: 2022
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9. ADDITION OF NATURAL EXTRACTS WITH ANTIOXIDANT PROPERTIES IN BIODIESEL: ANALYSIS BY NEURAL NETWORKS OF THE MULTILAYER PERCEPTRON TYPE
Biodiesel is capable of replacing diesel because it has similar physicochemical properties, but this biofuel is susceptible to oxidation, which makes the application of antioxidant substances necessary. For this study, alcoholic extracts of senna leaves, hibiscus flowers, and blackberry were used. Biodiesel samples were submitted to physicochemical analysis
Química Nova. Publicado em: 2022
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10. Zinc tungstate: a review on its application as heterogeneous photocatalyst
Abstract ZnWO4 crystallizes in a monoclinic wolframite-like structure, which has been studied for applications in heterogeneous photocatalysis for degradation, oxidation, and reduction of various contaminants. This type of tungstate has proved to be an efficient photocatalyst under both ultraviolet and visible light irradiation and, when ZnWO4 forms a hetero
Cerâmica. Publicado em: 2022
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11. The combined effect of lifestyle intervention and antioxidant therapy on sperm DNA fragmentation and seminal oxidative stress in IVF patients: a pilot study
ABSTRACT Purpose: Sperm DNA fragmentation (SDF) and seminal oxidative stress are emerging measurable factors in male factor infertility, which interventions could potentially reduce. We evaluated (i) the impact of lifestyle changes combined with oral antioxidant intake on sperm DNA fragmentation index (DFI) and static oxidation-reduction potential (sORP), a
International braz j urol. Publicado em: 2022
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12. Erratum
Abstract The aim of this work was to determine and compare the mineral composition and physico-chemical parameters of formulations of cookies developed by hand based on Lablab purpureus (L.) Sweet (mangalo—BFM), Vigna unguiculata (L.) Walp. (cowpea beans—BFC) and Cajanus cajan (L.) Huth (pigeon pea—BFP) flours. The results indicate that the cookies hav
Food Sci. Technol. Publicado em: 2021-09