Nephelauxetic Effect
Mostrando 1-2 de 2 artigos, teses e dissertações.
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1. CONTRIBUIÇÃO AO ESTUDO DE CAMPO CRISTALINO E TRANSIÇÕES 4f-4f EM SISTEMAS CONTENDO LANTANÍDEOS. / CONTRIBUTION TO THE STUDY OF CRYSTAL AND FIELD 4F-4F TRANSITIONS IN SYSTEMS CONTAINING LANTHANIDES.
A theoretical study of the interactions between the 4f electrons in lanthanide ions (Ln3 +) with the chemical environment was made using crystal field theory. The main effects were studied: change in position of the berycentre of the energy levels of the free ion, maximum splitting of the J level and contribution to 5D0-7F0 transition of Eu3+ ion. Use of sec
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 18/09/2012
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2. Influence of Side-Chain Substituents on the Position of Cleavage of the Benzene Ring by Pseudomonas fluorescens1
Pseudomonas fluorescens was grown on mineral salts media with phenol, p-hydroxybenzoic acid, p-hydroxy-phenylacetic acid, or p-hydroxy-trans-cinnamic acid as sole carbon and energy source. Each compound was first hydroxylated, ortho to the hydroxyl group on the benzene ring, to give catechol, protocatechuic acid (3,4-dihydroxy-benzoic acid), homoprotocatechu