Methanol Conversion
Mostrando 1-12 de 76 artigos, teses e dissertações.
-
1. Catalysts Derived from Thermal Treatments of Hydrocalumite-Type Compounds: Synthesis and Application in Transesterification Reactions
Catalyst performance is a relevant factor in biodiesel production because it can affect the efficiency of the process. This work provides a study of the performance of heterogeneous catalysts for biodiesel production derived from thermal-treated hydrocalumite-type compounds. This work aimed to synthesize and characterize hydrocalumite-type compounds intercal
Journal of the Brazilian Chemical Society. Publicado em: 2023
-
2. K2O SUPORTADO EM ZEÓLITA NATURAL: SÍNTESE, CARACTERIZAÇÃO E APLICAÇÃO PRODUÇÃO DE BIODIESEL A PARTIR DO ÓLEO DE GIRASSOL
Biodiesel is a renewable fuel, a substitute for fossil diesel, which is important for reducing GHG in Brazil. Therefore, this work aims to synthesize and characterize the catalyst using the support of natural zeolite impregnated with K2O and apply it in the production of biodiesel through the transesterification reaction. Through the analysis of characteriza
Química Nova. Publicado em: 2022
-
3. MODIFICAÇÃO QUÍMICA DO POLIPROPILENO ATRAVÉS DA INTRODUÇÃO DE GRUPOS SULFÔNICOS PARA APLICAÇÃO COMO CATALISADOR EM REAÇÕES DE ESTERIFICAÇÃO
In this work, the chemical modification of pristine polypropylene was carried out through sulfonation reactions with concentrated sulfuric acid (PPS1) and fuming sulfuric acid (PPS2), for production of heterogeneous catalysts used in esterification reactions. Fourier transform infrared spectroscopy, elemental analysis, degree of substitution and ion exchange
Quím. Nova. Publicado em: 2021-04
-
4. HSCCC Separations of Rutin Esters Obtained by Enzymatic Reaction Catalyzed by Lipase
The flavonoid rutin presents several pharmacological effects, despite this, its application in the pharmaceutical industry can be significantly limited by its low bioavailability. The development of lipophilic derivatives by esterification of hydroxyl groups with fatty acid chains may be an effective strategy to change their physicochemical properties. This
J. Braz. Chem. Soc.. Publicado em: 2021-03
-
5. New Magnetic Fe Oxide-Carbon Based Acid Catalyst Prepared from Bio-Oil for Esterification Reactions
In this work, bio-oil (an organic matrix rich in oxygen functionalities) was used to efficiently dissolve and disperse Fe3+ which upon thermal treatment produced a carbon containing dispersed and encapsulated Fe oxide magnetic nanoparticles. These materials were prepared by dissolution of 8, 16 and 24 wt.% Fe3+ salt in bio-oil followed by treatment at 400, 4
J. Braz. Chem. Soc.. Publicado em: 2020-08
-
6. CONVERSÃO FOTOELETROCATALÍTICA DE CO2 E BIOGÁS EM PRODUTOS DE INTERESSE ENERGÉTICO UTILIZANDO SEMICONDUTORES NANOESTRUTURADOS DE Ti/TiO2 MODIFICADOS COM ÓXIDO DE COBRE
This work describes the superficial modification of Ti/TiO2 nanotubes by copper oxide electrochemical deposition, in different temperatures (25 and 65 ºC), and its application on the photoelectrocatalytic conversion of CO2 and biogas in products of energy interest. The different temperatures deposition resulted in the formation of different geometric forms
Quím. Nova. Publicado em: 2020-02
-
7. PRODUCTION OF METHYL ESTERS BY ENZYMATIC HYDROESTERIFICATION OF CHICKEN FAT INDUSTRIAL RESIDUE
Abstract The feedstock cost can comprise more than 75% of the overall biodiesel cost, and then economic issues are the main limitations of biodiesel production. This research focused on the use of alternative feedstock and production processes. The production of fatty acid esters from residues becomes an interesting alternative route since it is possible to
Braz. J. Chem. Eng.. Publicado em: 30/09/2019
-
8. Simple Niobium Catalysts Applied in Reflux and Ultrasound-Assisted Systems for Biofuel Synthesis
Using niobium compounds as heterogeneous catalysts in biodiesel production is a promising methodology from economic and environmental viewpoints. However, the application of niobium catalysts still is a challenge due to the high temperatures and pressures for moderate biofuel yields. Therefore, easily handled and applied materials have been developed to opti
J. Braz. Chem. Soc.. Publicado em: 16/09/2019
-
9. Esterificação do ácido oleico utilizando aluminossilicato mesoporoso modificado com óxido de zircônio
RESUMO Os desafios decorrentes do aumento populacional, do uso extensivo e degradação dos recursos naturais e da dependência dos recursos fósseis, tem despertado o interesse pelo desenvolvimento de tecnologias para a produção de combustíveis renováveis. Dentro deste contexto tecnologias para a produção de biodiesel tem sido bastante estudadas de fo
Matéria (Rio J.). Publicado em: 20/05/2019
-
10. Comparative Study on Catalytic Dehydration of Glycerol with Alcohols
A comparative study of glycerol dehydration with alcohols (methanol, ethanol, tert-butyl alcohol) over ion exchange resin Amberlyst-35 was performed. The effect of catalyst amounts (1-15 wt.% to glycerol), reaction temperature (50-100 ºC), reaction time (5-10 h), and the molar ratio of alcohols to glycerol (3:1-8:1) were carried out in 50 mL stainless steel
J. Braz. Chem. Soc.. Publicado em: 2019-04
-
11. Methyl Esters Production by Heterogeneous Catalyst Mixtures of CaO/Nb2O5 with Simulation of Analysis of Environmental Impacts
The conventional biodiesel process, although it reaches high conversion yields and productivity, faces problems related to the use of homogeneous catalysts. This work aims to study mixtures of calcium oxide (CaO) and niobium oxide (Nb2O5) as the heterogeneous catalyst. It was used a full 23 factorial design with four central points to analyze how the mass pe
J. Braz. Chem. Soc.. Publicado em: 2019-03
-
12. Appliance of a high pressure semi-batch reactor: supercritical transesterification of soybean oil using methanol
Abstract This work presents the results of a supercritical transesterification process of soybean oil using methanol, performed in a laboratory high pressure semi-batch reactor. A full description of the equipment and a standard operating procedure are also provided. Since fossil fuels are not renewable, biofuels such biodiesel, have gained attention over t
Food Sci. Technol. Publicado em: 31/01/2019