Methane Reforming
Mostrando 13-24 de 48 artigos, teses e dissertações.
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13. Catalisadores à base de platina frente a correntes de H2 contendo acetaldeído geradas via reforma do etanol / Platinum-based catalystic in the face of current H2 containing acthaldehyde generated via reforming of ethanol
Due to the greenhouse effect, hydrogen production from bioethanol reforming is a very important subject in heterogeneous catalysis research. Pt based catalysts are employed in H2 purification processes and also as electrocatalysts of PEM (Proton Exchange Membrane) fuel cells. Hydrogen obtained from ethanol reforming may contain acetaldehyde and small amounts
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 23/05/2011
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14. Conversão de biogás em gás de síntese via reações de reforma do metano com CO2 e a vapor sobre catalisadores de Ni-Y-Al / Biogas conversion to synthesis gas via methane reforming reactions with CO2 and steam on Ni-Y-Al catalysts
Devido a crescente busca por fontes de energia que utilizem combustíveis renováveis, a utilização do biogás (mistura de gases produzida durante a digestão de matéria orgânica) proveniente do tratamento anaeróbio de águas residuárias e esgotos, surge como um processo promissor para a produção de gás de síntese (mistura de H2 e CO), contribuindo
Publicado em: 2010
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15. Estudo da reação de oxidação preferencial do co sobre o sistema CuO/CeO2-TiO2
Cu catalysts supported on CeO2, TiO2 and CeO2/TiO2 were prepared by precipitation method and used for preferential oxidation of carbon monoxide contained in a hydrogen flow generated by methane steam reforming. The samples were characterized by XRD, BET and TPR techniques. The catalytic properties were studied in the 50-330ºC range by using a quartz micro-r
Química Nova. Publicado em: 2010
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16. Exergy and thermoeconomic evaluation of a petroleum refinery hydrogem production unit. / Produção de hidrogênio em refinarias de petróleo: avaliação exergética e custo de produção.
Pure hydrogen (H2) is an useful gas in chemical and petrochemical industries because it reacts easily with several other elements. On refineries, hydrogen is used to sequestrate sulphur from diesel and gasoline. Emission restrictions regard to fossil fuels are rising the world hydrogen demands. In spite of its abundance, hydrogen is normally found associated
Publicado em: 2010
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17. Síntese e caracterização de nanocatalisadores de platina suportados aplicados à reação de reforma do metano
Nanopartículas coloidais de platina (NPs-Pt) foram obtidas por meio da redução do ácido hexacloroplatínico por etilenoglicol na presença de polivinilpirrolidona (PVP) como agente protetor das partículas. Dois métodos de síntese foram realizados os quais se diferiram pela razão PVP/Pt empregada. As sínteses das NPs-Pt foram acompanhadas por medidas
Publicado em: 2010
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18. PD/AL2O3 catalysts modified with la: preparation, characterization and catalytic properties in the steam and autothermal reforming of methane reactions. / Catalisadores de Pd/Al2O3 modificados com La: preparação, caracterização e propriedades catalíticas nas reações de reforma a vapor e autotérmica do metano
Os catalisadores de Pd foram preparados por impregnação dos suportes utilizando-se uma solução aquosa de nitrato de paládio. Os suportes (x)La2O3-Al2O3, com x = 0 a 20 % em peso, foram obtidos pelos métodos de impregnação úmida e sol gel. Os suportes e catalisadores foram caracterizados por fisissorção de N2, difração de raios X, termogravimetri
Publicado em: 2010
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19. Hydrogen from biomass gas steam reforming for low temperature fuel cell: energy and exergy analysis
This work presents a method to analyze hydrogen production by biomass gasification, as well as electric power generation in small scale fuel cells. The proposed methodology is the thermodynamic modeling of a reaction system for the conversion of methane and carbon monoxide (steam reforming), as well as the energy balance of gaseous flow purification in PSA (
Brazilian Journal of Chemical Engineering. Publicado em: 2009-03
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20. Análise termodinâmica das reações de reforma do metano e do GLP para a produção de hidrogênio
The chemical equilibrium compositions of steam and dry methane reforming reactions, (SMR) and (DMR), respectively, are calculated by two distinct methods: (1) evaluation of the equilibrium constants; (2) Lagrange multipliers. The chemical equilibrium compositions of LPG steam reforming reaction are calculated by the method of evaluation of equilibrium consta
Publicado em: 2009
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21. Análise termodinâmica das reformas do metano (oxidativa e autotérmica), do etanol e da nafta
Catalytic reforming of hydrocarbons or other organic species is a technology usually employed in either improving traditional energy sources or producing alternative energy sources. Amongst the technologies employed in improving traditional energy sources, one can include catalytic reforming of petrochemical naphtha. Although being also employed to produce h
Publicado em: 2009
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22. Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet impregnation on γ- Al2O3 (Alfa Aesar) with 10% by weight of oxides of cerium, zirconium, lanthanum, ceria-zirconia, ceria-lanthanum an
Publicado em: 2009
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23. Catalisadores de Pt suportados, obtidos pelo método solgel : efeito do cério na atividade e estabilidade nas reações de reforma do metano
The effect of Ce as a structural and electronic promoter on the activity and stability of Pt catalysts supported on Al2O3 for methane reforming reactions were investigated to elucidate the metal-support interaction. Pt/Al2O3 and Pt/CeO2-Al2O3 catalysts were prepared by conventional method of wet impregnation on commercial supports and on CeO2- Al2O3 mixed ox
Publicado em: 2009
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24. Desenvolvimento experimental e validaÃÃes do processo catalÃtico (Ni/γ-Al2O3/CeO2-Al2O3) de reforma metano-diÃxido de carbono em reator de leito fluidizado
Carbon dioxide of methane reforming into syngas over Ni/γ-Al2O3 and Ni/CeO2-Al2O3 catalysts was investigated. The Nikel catalysts presented high activity and stability although of the potential of coke formation on its active sites. The development of the dry methane reform for process, main component of natural gÃs (GN), was studied in a fluidized bed
Publicado em: 2009