Methane Reforming
Mostrando 1-12 de 48 artigos, teses e dissertações.
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1. CHARACTERIZATION AND BEHAVIOUR OF PT CATALYSTS SUPPORTED ON BASIC MATERIALS IN DRY REFORMING OF METHANE
ABSTRACT Different basic materials, such as K-L zeolite, K-Al2O3, K-Mg/Al mixed oxide and MgO, were used as supports of Pt-catalysts for the dry reforming of methane (DR) reaction. The effects of the distribution of basic strength in the support on the metal-support properties and catalyst performance were evaluated. The density of strong and the total basic
Braz. J. Chem. Eng.. Publicado em: 15/07/2019
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2. Evaluation of nickel and copper catalysts in biogas reforming for hydrogen production in SOFC
ABSTRACT The solid oxide fuel cells (SOFC) enable the efficient generation of clean energy, fitting the current requirements of the growing demand for electricity and for the environment preservation. When powered with biogas (from digesters of municipal wastes), the SOFCs also contribute to reduce the environmental impact of these wastes. The most suitable
Matéria (Rio J.). Publicado em: 22/05/2017
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3. OXIDATIVE-REFORMING OF METHANE AND PARTIAL OXIDATION OF METHANE REACTIONS OVER NiO/PrO2/ZrO2 CATALYSTS: EFFECT OF NICKEL CONTENT
Abstract In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD), Temperature Programmed Reduction (H2-TPR), Scanning Electron Microscopy (SEM/EDX) and Ads
Braz. J. Chem. Eng.. Publicado em: 2016-09
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4. Nickel-based Catalyst Precursor Prepared Via Microwave-induced Combustion Method: Thermodynamics of Synthesis and Performance in Dry Reforming of CH4
Nickel-based catalyst precursor for dry reforming of methane was successfully prepared by a self-combustion method. Three different amino acids: urea, glycine and citric acid were tested as fuels in the redox reaction with metal nitrates. For each fuel, a thermodynamic modeling of the combustion reaction was performed. The samples were characterized by X-ray
Mat. Res.. Publicado em: 25/08/2015
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5. METHANE DRY REFORMING OVER Ni SUPPORTED ON PINE SAWDUST ACTIVATED CARBON: EFFECTS OF SUPPORT SURFACE PROPERTIES AND METAL LOADING
The influence of metal loading and support surface functional groups (SFG) on methane dry reforming (MDR) over Ni catalysts supported on pine-sawdust derived activated carbon were studied. Using pine sawdust as the catalyst support precursor, the smallest variety and lowest concentration of SFG led to best Ni dispersion and highest catalytic activity, which
Quím. Nova. Publicado em: 2015-05
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6. EVALUATING HYDROGEN PRODUCTION IN BIOGAS REFORMING IN A MEMBRANE REACTOR
Abstract Syngas and hydrogen production by methane reforming of a biogas (CH4/CO2 = 2.85) using carbon dioxide was evaluated in a fixed bed reactor with a Pd-Ag membrane in the presence of a nickel catalyst (Ni 3.31% weight)/γ-Al2O3) at 773 K, 823 K, and 873 K and 1.01×105 Pa. Operation with hydrogen permeation at 873 K increased the methane conversion to
Braz. J. Chem. Eng.. Publicado em: 2015-03
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7. Nickel / Doped Ceria Solid Oxide Fuel Cell Anodes for Dry Reforming of Methane
Neste trabalho, foi estudado o desempenho catalítico de materiais a base de Ni, suportado em cério dopado com Zr, Pr e Nb para serem usados como anodos em células a combustível de óxido sólido (SOFC) alimentadas com combustíveis contendo metano e CO2. Os anodos foram preparados pelo método hidrotérmico, usando um teor de Ni (14% em volume) menor do
J. Braz. Chem. Soc.. Publicado em: 2014-12
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8. Dry reforming of methane at moderate temperatures over modified Co-Al Co-precipitated catalysts
M-Co-Al (M = Ca, La, Li or Mg) materials were synthesised by co-precipitation and investigated for dry reforming of methane. Thermogravimetry, temperature-programmed oxidation, reduction and CO2 desorption, specific area and X-ray diffraction were utilised for characterisation. Activity tests were conducted at atmospheric pressure, temperatures between 400-5
Mat. Res.. Publicado em: 28/07/2014
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9. Estudo de catalisadores de níquel suportados em cinza de casca de arroz na reforma de metano com dióxido de carbono visando a produção de hidrogênio e gás de síntese
Rice husk ash (RHA) is used as a silica source for several purposes, among them to obtain metal catalysts, as was done in this work. The catalysts were characterized by chemisorption, physisorption, thermal analyses (TG, DSC), X-ray diffraction, X-ray fluorescence, temperature-programmed reduction and scanning electron microscopy. The catalysts synthesized w
Quím. Nova. Publicado em: 2014
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10. Desenvolvimento e caracterização de catalisadores de níquel suportados em matrizes CeO2-ZrO2-Al2O3, CeO2-La2O3-Al2O3 e ZrO2-La2O3-Al2O3 avaliados para as reações de reforma do metano / Development and characterization of nickel catalysts supported on CeO2-ZrO2-Al2O3, CeO2-La2O3-Al2O3 and ZrO2-La2O3-Al2O3 evaluated for the reactions of methane reforming
A reforma do metano é um processo de grande interesse industrial para a produção de hidrogênio e de gás de síntese. Entre as reações de reforma do metano, destacam-se as reações de reforma a vapor e a reação com dióxido de carbono. O catalisador comumente utilizado nos processos e Ni/Al2O3. Porém, durante este processo, ocorre uma indesejada fo
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 17/04/2012
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11. Análise termodinâmica de processos de reforma do metano e da síntese Fischer-Tropsch / Thermodynamic analysis of methane reforming processes and Fischer-Tropsch synthesis
The reactions of reforming of light hydrocarbons, especially natural gas, are chemical reactions of great importance and represent key steps for large scale production of hydrogen for use in hydrogenation reactions or fuel cells, or synthesis gas production, for application in the ammonia or methanol production, or to Fischer-Tropsch (FT) synthesis. The Fisc
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 30/03/2012
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12. Ce - promoted catalyst from hydrotalcites for CO2 reforming of methane: calcination temperature effect
Ce-promoted Ni-catalysts from hydrotalcites were obtained. The effect of calcination temperature on the chemical and physical properties of the catalysts was studied. Several techniques were used to determine the chemical and physical characteristics of oxides. The apparent activation energies of reduction were determined. Catalytic experiments at 48 L g-1h-
Química Nova. Publicado em: 2012