Metallic Clusters
Mostrando 13-16 de 16 artigos, teses e dissertações.
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13. Nanotubos e nanobastões de oxidos e sulfetos de metais de transição obtidos via sistemas bidimensionais (lamelares) : preparação, caracterização e propriedades / Nanotubes and nanorods of transition metal oxides and sulfides obtained from bidimensional systems (layered compunds) : preparation, characteization and properties
This Thesis reports the preparation, characterization and properties of nanotubes and nanorods of transition metal oxides and sulfides obtained from bidimensional (Iamellar) structures. From the structural point view, nanotubes could be formed from bidimensional compounds by rolling its layers generating scroll-like nanotubes, or by the elimination of dangli
Publicado em: 2006
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14. Síntese e caracterização de alfa-fosfato de zircônio(IV) contendo agregados de cobre metálico
The alpha-zirconium (IV) hydrogenphosphate (alpha-ZrP) has received great attention in the last years due to its properties like ion exchange, intercalation, ionic conductivity and catalytic activity. This work reports a method to produce metallic copper clusters on alpha-ZrP to be used as catalysts in petrochemical processes. It was found that the solids we
Química Nova. Publicado em: 2005-02
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15. Desenvolvimento de sistemas polinucleares baseados em clusters trinucleares e complexos poliimínicos de rutênio: unidades de montagem em química supramolecular / Development of polynuclear systems based on trinuclear cluster and polyimines ruthenium compounds: building blocks in supramoleular chemistry
The aim of the work reported is to develop polynuclear structures based on trinuclear ruthenium clusters. All the oligomers are seen as interesting options to the future development of supramolecular devices, due to their photophysical and electrochemical properties. A series of mixed dimers and one trimer were obtained by the combination of the [Ru3O(CH3COO
Publicado em: 2002
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16. Magic numbers for metallic clusters and the principle of maximum hardness.
It is shown that for relatively more stable metallic clusters (those with magic number of atoms) the chemical hardness (I-A) too is relatively larger. Thus the occurrence of magic numbers for metal clusters whose stability is determined by their electronic shell structure can be understood as a manifestation of the principle of maximum hardness. This may als