Metal Organic Materials
Mostrando 1-12 de 46 artigos, teses e dissertações.
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1. Zinc tungstate: a review on its application as heterogeneous photocatalyst
Abstract ZnWO4 crystallizes in a monoclinic wolframite-like structure, which has been studied for applications in heterogeneous photocatalysis for degradation, oxidation, and reduction of various contaminants. This type of tungstate has proved to be an efficient photocatalyst under both ultraviolet and visible light irradiation and, when ZnWO4 forms a hetero
Cerâmica. Publicado em: 2022
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2. Environmental effects of leachate extracts from reclaimed asphalt pavement: determination of metals, polycyclic aromatic hydrocarbon and acute toxicity to Daphnia magna
RESUMO Reclaimed Asphalt Pavement (RAP) has a variety of organic and inorganic compounds that can interact with the environment and promote deleterious effects on human health. This study investigated the potential toxicity of RAP through metal determination, polycyclic aromatic hydrocarbon (PAH) analysis and acute toxicity tests with Daphnia magna. Leached
Engenharia Sanitaria e Ambiental. Publicado em: 2022
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3. Photoluminescent Investigation of the Doping Site of Eu3+-Doped [Zn3(BTC)2·12H2O] Metal-Organic Framework Prepared by Microwave-Assisted Hydrothermal Synthesis
The [Zn3(BTC)2·12H2O] (BTC = 1,3,5-tricarboxylate) metal-organic framework (MOF) was successfully synthesized using a microwave-assisted hydrothermal synthesis technique, which allowed for significantly decreased reaction time compared to the production of the same compound via conventional heating. In situ doping with Eu3+ ions at concentrations ranging fr
J. Braz. Chem. Soc.. Publicado em: 2020-11
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4. Hydrothermal Synthesis to Water-stable Luminescent Carbon Dots from Acerola Fruit for Photoluminescent Composites Preparation and its Application as Sensors
Carbon dots (C-dots) possess the attractive properties of high stability, low toxicity, good water solubility, simple synthetic routes as well as size and excitation-dependent photoluminescence (PL).The aim of this work was to synthesize photoluminescent C-dots by hydrothermal method using acerola fruit (Malpighiaemarginata) as a row material, since this fru
Mat. Res.. Publicado em: 06/06/2019
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5. Effect of sol-gel processing parameters on structure of zirconia
Abstract The present study reports the experimental results regarding the effect of molar ratio of hydrolysis water used in the sol-gel synthesis upon the structure of zirconia. The ZrO2 materials were synthesized via simple metal-chelate route using zirconium n-propoxide [Zr(OCH2CH2CH3)4], n-propanol, acetic acid, and deionized water. Thermogravimetric anal
Cerâmica. Publicado em: 2019-01
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6. Efectos del uso de electrolitos soportes en ensayos electroquímicos de la aleación Al-4%Mg expuesta a bioetanol combustible
ABSTRACT The growth of world energy demand directly affects the consumption of petroleum-based fuels, increasing the negative impact of the use of these fuels and the decrease of crude oil reserves. This creates an opportunity for the use of fuels that are more efficient, of low environmental impact and, above all, of a renewable nature. Bioethanol is a biof
Matéria (Rio J.). Publicado em: 19/07/2018
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7. First evaluation of semidirect recycling methods for the reclamation of cemented carbides based on a literature survey
ABSTRACT At the moment the industrially applied techniques for cemented carbide reclamation feature several deficiencies. Depending on the process route, obstacles consist in high energy and chemical consumption (indirect recycling methods) or a deterioration of the recycled product in comparison with the primary material (direct recycling approach). Therefo
Matéria (Rio J.). Publicado em: 19/07/2018
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8. AVALIAÇÃO DOS RESÍDUOS GERADOS DURANTE A DESTRUIÇÃO DE PCBS PELO PROCESSO CATALISADO POR BASE
There are many processes capable of decontamination of polychlorinated biphenyls in several matrixes. The set of inputs, materials, operation conditions and efficiencies are wide. The base catalyzed dechlorination process shows application potential in great scale, mainly due mild chemical reaction conditions and low cost raw materials. The KPEG is a familia
Quím. Nova. Publicado em: 2018-06
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9. Reference Values of Soil Quality for the Rio Doce Basin
ABSTRACT: The great geological and soil variation in the state of Minas Gerais, Brazil, indicates the need for regional studies to understand the geochemical background of soils. The Rio Doce Basin became a priority area for geochemical background determination after the rupture of the tailings dam of Fundão in 2015. In this context, the objectives of this
Rev. Bras. Ciênc. Solo. Publicado em: 16/04/2018
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10. Natural Fertility and Metals Contents in Soils of Rio Grande do Sul (Brazil)
ABSTRACT: The parent geological materials and formation factors influence the chemical, physical, and mineralogical properties and composition of the soil. Therefore, the aims of this study were to determine the chemical and some physical and mineralogical properties of the soil useful for agricultural practice; to determine the natural contents of the semit
Rev. Bras. Ciênc. Solo. Publicado em: 01/02/2018
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11. Synthesis and Characterization of Non-Linear Optical Crystal of Manganese Mercury Thiocyanate Glycol Monomethyl Ether
The design and synthesis of organic nonlinear optical (NLO) crystals are a promising area of current research in materials science. Organic materials are found to possess better non linear optical properties when compared to inorganic materials. Recently, there has been a widespread interest in the metal-organic coordination compounds, which are a combinatio
Mat. Res.. Publicado em: 30/11/2017
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12. Modulator Effect of Acetic Acid on the Morphology of Luminescent Mixed Lanthanide-Organic Frameworks
The control of the size and morphology of Metal-Organic Frameworks is a challenge that must be overcome to ensure the use of these materials in advanced applications. Mixed Lanthanide-Organic Frameworks (MLOFs) were synthesized via solvo(hydro)thermal method and then characterized by PXRD, IR, TG/DTA, SEM and PL spectroscopy. The effect of the modulator (ace
Mat. Res.. Publicado em: 30/11/2017