Mesoporous Silica
Mostrando 13-24 de 75 artigos, teses e dissertações.
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13. Synthesis of ordered mesoporous silica MCM-41 with controlled morphology for potential application in controlled drug delivery systems
Resumo O MCM-41 é uma das cerâmicas mesoporosas mais estudadas para sistemas de liberação controlada de fármacos. Sua elevada área superficial específica e mesoporosidade permitem alta capacidade de adsorção. Apesar dos inúmeros trabalhos publicados na área biomédica, até o presente momento não há relatos de aplicações comerciais do MCM-41.
Cerâmica. Publicado em: 06/06/2019
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14. Catalytic Dehydration of 1-Propanol Over Silica Containing Sulfonic Acid Groups
Mesoporous silica with strongly acid sulfonic sites were synthesized and used as catalytic supports for catalytic dehydration of 1-propanol. This porous material with a large surface area and high porosity were prepared by a simplified sol-gel in an acidic medium and impregnated easily by -SO3H groups. The experimental results indicate that the very strong a
Mat. Res.. Publicado em: 28/03/2019
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15. Importance of the Order of Addition of the Alumina Precursor and its Type Into Al-SBA-15 Mesoporous Materials for Use as Water Adsorbents
In the present report, Al-SBA mesoporous materials were investigated for use as water adsorbents. Different precursors for aluminum were investigated: aluminum sulfate and nitrate, boehmite, and aluminum tri-sec-butoxide. Furthermore, three different procedures for addition of the silica and alumina sources were tested. Samples were characterized by nitrogen
Mat. Res.. Publicado em: 10/12/2018
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16. Síntesis de sílice mesoestructurada: determinación de las condiciones óptimas de extracción del templato
ABSTRACT Ordered mesoporous silica was synthesized by the sol-gel process using tetraethoxysilane (TEOS) as silica source and hexadecyltrimethyl ammonium bromide (CTAB) as structure directing agent. Post-synthesis surfactant removal was conducted by two techniques: calcination, with progressive increases in temperature up to 550 ºC and solvent extraction us
Matéria (Rio J.). Publicado em: 19/07/2018
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17. Ordered Silica Particles Made by Nonionic Surfactant for VOCs Sorption
Adsorption of light organic compounds such acetone, 1-propanol and carbon dioxide was tested by using mesoporous silica materials made from non ionic surfactant with long chain and silica sources as tetraethylorthosilicate TEOS and modified Na-X and Li-A Zeolites. X-ray powder diffraction (XRD), nitrogen adsorption-desorption analysis and scanning electron m
Mat. Res.. Publicado em: 26/06/2017
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18. Gallium-Containing Mesoporous Silica: Supported Catalysts with High Catalytic Activity for Oxidation of Benzene, Toluene and o-Xylene
Benzene, toluene and xylene (BTX) are a particular class of volatile organic compounds, which are highly toxic pollutants. In this study, samples of gallium-containing mesoporous silica (MS-Ga7% and MS-Ga11%) were synthesized and their catalytic activity in the oxidation of BTX was investigated. The physicochemical characterization shows that the inclusion o
J. Braz. Chem. Soc.. Publicado em: 2017-01
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19. A Mesoporous SiO2/γ-Fe2O3/KI Heterogeneous Magnetic Catalyst for the Green Synthesis of Biodiesel
A magnetic catalyst (sample MCat) consisting of KI supported on a mixture of silica and maghemite (γ-Fe2O3) was prepared and used in the transesterification reaction for the synthesis of biodiesel. The energy dispersive X-ray spectrum of the catalyst showed signals due to Si, Fe, K, and I. Powder X-ray diffraction data revealed the amorphous nature of the S
J. Braz. Chem. Soc.. Publicado em: 2016-12
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20. SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES
An efficient acidic functionalization of mesoporous silica LUS-1 (Laval University Silica) and its application as a recyclable heterogeneous catalyst in the synthesis of 2,4-diamino pyrimidine-5-carbonitriles via condensation reaction of aromatic aldehydes, malononitrile and guanidine carbonate in solvent-free condition has been reported. This green method o
Quím. Nova. Publicado em: 2016-09
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21. POLYMERIZATION OF ANILINE IN DIFFERENT SBA-16 SILICA HOSTS
Polyaniline-silica composites made with mesoporous silica have been reported to improve the mechanical properties of the free polymer. However, there are not many studies about the effect of the chemical and physical properties of the inorganic material used as hosts over the final properties of polyaniline and the composites. Here, polyaniline-silica compos
Quím. Nova. Publicado em: 2016-08
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22. The novel mesoporous silica aerogel modified with protic ionic liquid for lipase immobilization
Mesoporous silica supports (aerogels) were used to immobilize Burkholderia cepacia lipase (BC) by encapsulation (EN or ENIL), physical adsorption (ADS or ADSIL) and covalent binding (CB or CBIL) into or onto the aerogel modified with protic ionic liquid (PIL). Yield immobilization (Ya) and operational stability were determined by the hydrolytic reaction of o
Quím. Nova. Publicado em: 2016-05
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23. Synthesis and Characterization of 1-Methyl-3-Methoxysilyl Propyl Imidazolium Chloride – Mesoporous Silica Composite as Adsorbent for Dehydration in Industrial Processes
Ionic liquid – mesoporous silica composite was synthesized as a new adsorbent for dehydration in industrial processes. An ionic liquid (IL) with proved dehydration properties has been covalently anchored to mesoporous silica. The parameters of the synthesis were studied to produce a solid and stable composite. The material was then characterized by SEM, BE
Mat. Res.. Publicado em: 08/04/2016
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24. Removal of Lead(II), Copper(II) and Zinc(II) Ions from Aqueous Solutions Using Magnetic Amine-Functionalized Mesoporous Silica Nanocomposites
In this work, a batch adsorption study was conducted to investigate the removal efficiency of lead, copper and zinc ions from aqueous solutions. Magnetic amine-functionalized mesoporous silica nanoparticles were synthesized by grafting amine groups within the channels of magnetic mesoporous silica nanocomposites. Morphological and structural characterization
J. Braz. Chem. Soc.. Publicado em: 2015-11