Mesopores Materials
Mostrando 1-12 de 12 artigos, teses e dissertações.
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1. Obtenção de hydrochar a partir de carbonização hidrotérmica de cascas do fruto de Magonia pubescens A. St. Hil. Sapindaceae: Caracterização e avaliação em processo de adsorção
RESUMO A Carbonização hidrotermal (HTC) de cascas do fruto de Magonia pubescens A. St. Hil. Sapindaceae (Tingui do cerrado) é apresentada como uma proposta inédita na produção de hydrochars a partir de precursores de espécies do Cerrado Brasileiro, onde se verificou a influência da temperatura nas propriedades dos materiais obtidos. Os hyrochar obtid
Matéria (Rio J.). Publicado em: 10/06/2019
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2. Generación de mesoporosidad en zeolitas ZSM-11, BETA e Y por tratamiento alcalino
ABSTRACT Zeolites, Y, ZSM-11 and BETA, widely used in refineries and petrochemical processes, fine chemistry and environmental processes were subjected to an alkaline treatment of desilication, in order to generate mesoporosity in the structure. The process used consisted of treating samples with an aqueous solution of NaOH at 65 ° C for 30 minutes. An exch
Matéria (Rio J.). Publicado em: 19/07/2018
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3. Catálise básica usando sílica mesoporosa estabilizada por acrilatos encapsulados
The synthesis of new type of silicas, with structures akin to that of MCM-41, containing polyacrylate-encapsulated micelles in their mesopores is reported. Initially, the monomers were inserted in the aqueous micelles of cetyltrimethylammonium cations. MCM-41 was then prepared in this microemulsion. Finally, the polymerization of the acrylates was initiated
Quím. Nova. Publicado em: 2014-06
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4. Synthesis and characterization of novel ZrO2-SiO2 mixed oxides
In this study the mixed oxides ZrO2-SiO2, were synthesized by the sol-gel method with a molar ratio of 95:5 (Si/metal) and characterized by X-ray diffraction, absorption-desorption of N2, Fourier transform infrared spectroscopy, thermal gravimetric analysis, temperature-programmed desorption of ammonia, and acidity test by titration. The synthesized material
Mat. Res.. Publicado em: 15/04/2014
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5. Síntese, caracterizaçao e propriedades catalicas da peneira molecular nanoestruturada modificada com lantanio
A peneira molecular nanoestruturada SBA-15 foi sintetizada pelo método hidrotérmico, e modificada com lantânio com razões molares Si/La de 25, 50, 75 e 100. Os materiais obtidos foram avaliados como catalisador para a reação modelo de craqueamento de n-hexano. Os materiais mesoporosos tipo SBA-15 e LaSBA-15 foram sintetizados utilizando tetraetilortosi
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 06/08/2009
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6. Materials hierarchically structuralized with mesoporosa cubical phase: synthesis, characterization and use as support in the immobilization of enzyme HRP / Materiais hierarquicamente estruturados com fase cúbica mesoporosa: síntese, caracterização e uso como suporte na imobilização da enzima HRP
Hierarchical silica porous materials have been successfully synthesized using polystyrene nanospheres as macropore template, triblock copolymer Pluronic F127 as mesopore template, tetramethyl orthosilicate as silica source and ethanol as cosurfactant. The obtained materials were characterized by XRD, TG-DTA, N2 adsorption, Hg porosimetry, SEM, HRSEM, TEM and
Publicado em: 2009
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7. Síntese e caracterização de peneiras moleculares mesoporosas do tipo MCM-41 e AlMCM-41 a partir de fontes alternativas de sílica e de alumínio
The mesoporous molecular sieves of MCM-41 and AlMCM-41 type are considered as promising support for metal in the refining processes of petroleum-based materials as catalysts and adsorbents for environmental protection. In this work the molecular sieves MCM-41 and AlMCM-41 were synthesized by replacing the source of silica conventionally used, for quartz, an
Publicado em: 2009
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8. RemoÃÃo de Ãcidos naftÃnicos presentes na mistura modelo de querosene de aviaÃÃo utilizando adsorventes tipo perovsquitas modificadas
In this work were prepared adsorbents of type perovsquitas La1-xMgxNiO3, where x = 0, 0.25, 0.5, 0.75, 1.0. The addition of magnesium resulted in increased basicity of the material and consequently the affinity of the acids. The adsorbents prepared materials were characterized by atomic absorption espectrofometria (AA), X-ray diffraction (XRD) measurement of
Publicado em: 2009
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9. Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano / Formação de mesoporos na síntese de zeólitas ZSM-5 via nanomoldagem avaliação no craqueamento de n-decano
The use of zeolites in the cracking of hydrocarbons is limited because the molecules higher than 0.74 nm do not diffuse in their micropores. In the other hand, molecular sieves as MCM-41, MCM-48 ou SBA-15, whose diameters are up 10 nm for the two formers and up to 30 nm for the last, have low hydrothermal stability and catalytic activity. To overcome those l
Publicado em: 2008
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10. Síntese e caracterização de nanocompósitos de sílica mesoporosa com partículas magnéticas para dispositivos de liberação controlada de fármacos
Ordered mesoporous materials like SBA-15 posses a network of channels and pores of well-defined size in the nanoscale range. This particular pore architecture makes them suitable for hosting a broad variety of compounds into the silica matrix, resulting in very promising material for a broad range of applications, including magnetic carriers for drug deliver
Publicado em: 2007
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11. Materiais mesoporosos ordenados aplicados como sistemas para liberação controlada de drogas / Ordered mesoporous materials applied as drug delivery systems
In the last decade, progress in the development of nanosized hybrid therapeutics and drug delivery systems has been remarkable. Mesoporous materials such as SBA-15 and MCM-41 have been considered very promising materials for hosting and further delivery of biological agents within silica samples and for controlling their release kinetics from the matrix due
Publicado em: 2006
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12. Structural studies of niquel oxide xerogels. / Estudos estruturais de xerogéis de óxido de níquel.
Structural properties of several xerogels obtained by the sol-gel procedure and heat treated at different temperatures between 150 and 900ºC were studied. The initial systems were dry gels prepared from liquid solutions composed of nickel chloride, buthanol, water and acetic acid. During the different isothermal treatments, volatile species leave the inicia
Publicado em: 2000