Liquid Liquid Equilibrium
Mostrando 25-36 de 310 artigos, teses e dissertações.
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25. Adsorption Mechanism of Lignosulfonate at the Air/Liquid Interface
Lignosulfonate is a type of natural polymer surfactant. Its capability to reduce the surface tension of aqueous solution depends on its adsorption configuration at the air/liquid interface. The dynamic surface tension, the air/liquid interfacial film properties of lignosulfonate at different solution concentrations, pH values and ionic strengths had been mea
J. Braz. Chem. Soc.. Publicado em: 2015-03
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26. MODELING AND SIMULATION OF A BENZENE RECOVERY PROCESS BY EXTRACTIVE DISTILLATION
Abstract Extractive distillation processes with N-formylmorpholine (NFM) are used industrially to separate benzene from six carbon non-aromatics. In the process studied in this work, the stream of interest consists of nearly 20 different hydrocarbons. A new set of NRTL parameters was correlated based on literature experimental data. Both vapor-liquid equilib
Braz. J. Chem. Eng.. Publicado em: 2015-03
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27. APARATO ELETROQUÍMICO PARA SISTEMA DE AQUISIÇÃO DE DADOS MULTICANAL COM RESOLUÇÃO ESPAÇO-TEMPORAL
Spatiotemporal pattern formation in reaction-transport systems takes place spontaneously when the system is kept far from thermodynamic equilibrium. Targets, reaction fronts, waves, spirals, spots and stripes are some typical examples of selforganized structuring. In electrochemical systems, monitoring spatiotemporal patterns of potential in the solid/liquid
Quím. Nova. Publicado em: 2015-01
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28. Wet oxidation of glycerol into fine organic acids: catalyst selection and kinetic evaluation
The liquid phase oxidation of glycerol was performed producing fine organic acids. Catalysts based on Pt, Pd and Bi supported on activated carbon were employed to perform the conversion of glycerol into organic acids at 313 K, 323 K and 333 K, under atmospheric pressure (1.0 bar), in a mechanically agitated slurry reactor (MASR). The experimental results ind
Braz. J. Chem. Eng.. Publicado em: 2014-12
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29. Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
Isobaric vapor-liquid equilibrium (VLE) data for the cyclopentane and tetrahydrofuran (THF) system were measured at 101.3 kPa by using an equilibrium still. Thermodynamic consistency of the experimental data was confirmed by means of the Herington method. The experimental data were correlated and calculated by the Margules, Van Laar and Wilson activity-coeff
Braz. J. Chem. Eng.. Publicado em: 2014-09
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30. A study of parameters affecting the solvent extraction of lactic acid from fermentation broth
Lactic acid has recently been drawing much interest as a raw material for biodegradable polymer. One of the promising technologies for recovery of lactic acid from fermentation broth is reactive liquid - liquid extraction. Equilibrium studies on the reactive extraction of lactic acid with trioctylamine (TOA) in various organic phases and its re-extraction in
Braz. J. Chem. Eng.. Publicado em: 2014-09
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31. Adsorção de alfa-lactalbumina do soro de leite em hidroxiapatita: efeito do pH e da temperatura e análise termodinâmica
The nutritional and functional benefits offered by whey protein α-lactalbumin justify the great interest in its manufacture in large quantities at a high purity level. Hydroxyapatite is a calcium phosphate material able to adsorb proteins and can be synthesized at low production cost. Therefore, this work evaluated the adsorption of α-lactalbumin on hydrox
Quím. Nova. Publicado em: 2014-07
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32. Solubility measurement and solid-liquid equilibrium model for the ternary system MgBr2 + MgSO4 + H2O at 288.15 K
The solubility of magnesium minerals and the refractive index of the ternary system MgBr2 + MgSO4 + H2O at 288.15 K were investigated using an isothermal dissolution method. It was found that there are two invariant points in the phase diagram and the solubility isotherm of this ternary system consists of three branches, corresponding to equilibrium crystall
Braz. J. Chem. Eng.. Publicado em: 2014-06
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33. Resgatando um método eficiente para determinação do ponto de ebulição de substâncias orgânicas: percolador versus Siwoloboff
The aim of this paper was to revive the accurate determination of the boiling point of organic compounds using the percolator technique developed in the 1960s. Although this method is simple, fast and efficient it is omitted from current textbooks. This method has several advantages over Siwoloboff such as high reproducibility and direct measurement of the b
Quím. Nova. Publicado em: 2014-06
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34. Batch removal of manganese from acid mine drainage using bone char
The present study investigated batch kinetics and the batch equilibrium of manganese removal from acid mine drainage (AMD) using bone char as an adsorbent. Equilibrium tests revealed that the Langmuir-based maximum manganese uptake capacity was 22 mg g-1 for AMD effluents and 20 mg g-1 for laboratory solutions at a pH ranging from 5.5 to 5.7. The pseudo-seco
Braz. J. Chem. Eng.. Publicado em: 2014-03
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35. Solid-liquid stable phase equilibria of the ternary systems MgCl2 + MgB6O10+ H2O AND MgSO4 + MgB6O10 + H2O at 308.15 K
The solubilities and the relevant physicochemical properties of the ternary systems MgCl2 + MgB6O10 + H2O and MgSO4 + MgB6O10 + H2O at 308.15 K were investigated using an isothermal dissolution method. It was found that there is one invariant point, two univariant curves, and two crystallization regions of the systems. The systems belong to a simple co-satur
Braz. J. Chem. Eng.. Publicado em: 2014-03
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36. Determinação do coeficiente de atividade na diluição infinita em sistemas etanol-água-sal por microextração em fase sólida-gc-fid
A new method using the headspace solid phase microextraction (HS-SPME) technique was used to evaluate the infinite dilute activity coefficient (γ1∞) in an alcohol/water/salt system. The studied systems were ethanol and water with NaCl and NH4Cl at salt concentrations of 5, 10, 15, and 30% m/v and temperatures of 303.15 and 313.15 K. The method was used to
Quím. Nova. Publicado em: 2014