Kinetic Mechanisms
Mostrando 1-12 de 332 artigos, teses e dissertações.
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1. Kinetic study and thermodynamic equilibrium modeling of the Co(II) and Mn(II) bioadsorption using the Rhodococcus opacus strain
Abstract Microbial biomass is considered a renewable and environmentally friendly resource. Thus, the research conducted a kinetic study and thermodynamic equilibrium modeling of the cobalt (Co) and manganese (Mn) bioadsorption process using the Rhodococcus opacus (RO) strain as a biosorbent. The inactive biomass subjected to 0.1 M NaOH pretreatment was brou
REM - International Engineering Journal. Publicado em: 2022
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2. PEACH PIT CHEMICALLY TREATED BIOMASS AS A BIOSORBENT FOR METFORMIN HYDROCHLORIDE REMOVAL: MODELING AND SORPTION MECHANISMS
ABSTRACT In this work, the potential of peach pit biosorption in the removal of the drug metformin hydrochloride from water is evaluated. Experiments are carried out in a closed batch system to evaluate the effect of the solution pH (2–10), temperature (25, 35 and 45 °C), stirring (100, 150 and 200 rpm) and chemical treatments. During the study, biosorben
Eng. Agríc.. Publicado em: 2021-04
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3. Activated carbon loaded with manganese and iron for glyphosate adsorption: Kinetics, isotherms and thermodynamic studies
Resumo Carvão ativado granular foi impregnado com 1% de ferro e 0,5% de manganês (m/m) para remoção de glifosato em soluções aquosas. O adsorvente foi caracterizado por microscopia eletrônica de varredura, espectroscopia de energia dispersiva, técnicas de adsorção de nitrogênio e análises de potencial zeta. Estudos em batelada foram realizados pa
Rev. Ambient. Água. Publicado em: 25/11/2019
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4. Nanoparticles of Fe2O3 and Co3O4 as Efficient Electrocatalysts for Oxygen Reduction Reaction in Acid Medium
This paper presents a comparative study about the oxygen reduction reaction (ORR) catalyzed by nanoparticles of Fe2O3 and Co3O4 applied on the surface of glassy carbon electrodes (GCE). The nanoparticles were synthesized using the modified polymeric precursor method (Pechini). These two nanomaterials were characterized by Fourier transform infrared spectrosc
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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5. Controlled synthesis of noble metal nanomaterials: motivation, principles, and opportunities in nanocatalysis
ABSTRACT This review describes some principles of the controlled synthesis of metal nanoparticles, focusing on how the fundamental understanding of their synthesis in the solution-phase can be put to tailor size, shape, composition, and architecture. The maneuvering over these parameters not only enable the tuning of properties, but also the maximization and
An. Acad. Bras. Ciênc.. Publicado em: 16/04/2018
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6. Rice Husk Ash as Raw Material for the Synthesis of Silicon and Potassium Slow-Release Fertilizer
Rice husk ash (RHA) is a waste material produced in large quantities in many regions worldwide, and its disposal can be problematic. This work describes a method for using RHA to synthesize silicon and potassium slow-release fertilizer. The extraction of silica from RHA was accomplished by alkaline leaching with KOH. Different KOH concentrations and reaction
J. Braz. Chem. Soc.. Publicado em: 2017-11
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7. The browning kinetics of the non-enzymatic browning reaction in L-ascorbic acid/basic amino acid systems
Abstract Under the conditions of weak basis and the reaction temperature range of 110-150 °C, lysine, arginine and histidine were reacted with L-ascorbic acid at equal amount for 30-150 min, respectively and the formation of browning products was monitored with UV–vis spectrometry. The kinetic characteristics of their non-enzymatic browning reaction were
Food Sci. Technol. Publicado em: 20/07/2017
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8. Introdução à físico-química orgânica utilizando um colorímetro artesanal - uma prática interdisciplinar
Herein, we propose an interdisciplinary experiment for undergraduate course that involves concepts of organic and physical chemistry. Firstly, we propose the synthesis of three nitrophenyl acetates, varying the substituent position. Afterwards, we describe the construction of a homemade colorimeter using inexpensive materials and LED as both emission and det
Quím. Nova. Publicado em: 2017-02
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9. ADVANCED CONTROL OF A COMPLEX CHEMICAL PROCESS
Abstract Three phase catalytic hydrogenation reactors are important reactors with complex behavior due to the interaction among gas, solid and liquid phases with the kinetic, mass and heat transfer mechanisms. A nonlinear distributed parameter model was developed based on mass and energy conservation principles. It consists of balance equations for the gas a
Braz. J. Chem. Eng.. Publicado em: 2016-03
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10. Dielectric Behavior of Alginate-Based Hydrogel Containing Neomycin-Loaded Lipid Nanovesicles under Influence of Electrical Potentials
Dielectric characterization has been applied as a convenient tool for evaluation of transport and polarization mechanisms in soft materials. In this work, we have explored the study of charge transport mechanisms in alginate hydrogel containing neomycin-loaded liposomes. For comparison, drug release kinetic was evaluated by using UV-Vis spectrophotometry and
J. Braz. Chem. Soc.. Publicado em: 2016-01
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11. Multicenter trial of motion analysis for injury risk prediction: lessons learned from prospective longitudinal large cohort combined biomechanical - epidemiological studies
ABSTRACTOur biodynamics laboratory group has conducted large cohort biomechanical-epidemiological studies targeted at identifying the complex interactions among biomechanical, biological, hormonal, and psychosocial factors that lead to increased risk of anterior cruciate ligament (ACL) injuries. The findings from our studies have revealed highly sensitive an
Braz. J. Phys. Ther.. Publicado em: 06/10/2015
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12. Kinetic Parameters of Soot Oxidation Catalyzed by Nanosized ZnO-CeO2 Solids
Catalytic combustion of soot was performed over ZnO:CeO2 catalysts obtained via a non‑alkoxide sol-gel route. Different kinetics parameters were calculated through thermal analyses, thus, enabling the correlation between the experimental data and the decomposition mechanisms probably associated with the soot decomposition in each case.
J. Braz. Chem. Soc.. Publicado em: 2015-07