Intercalation Reaction
Mostrando 1-12 de 25 artigos, teses e dissertações.
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1. Synthesis of New 1,2,3-Triazolo-naphthalimide/phthalimide Conjugates via ‘Click' Reaction: DNA Intercalation and Cytotoxic Studies
Cancer is a complex disease which involves abnormalities of multiple cellular pathways. Current chemotherapeutic drugs are mainly designed to target the DNA and cell division. Therefore, in the present study, we have synthesized a new series of 1,2,3-triazolo-naphthalimide/phthalimide conjugates and evaluated their in vitro cytotoxicity against selected huma
J. Braz. Chem. Soc.. Publicado em: 2019-03
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2. Investigation on Structural, Morphological and Relaxometric Properties of Lamellar Zrp Modified with Long Chain Amine
In order to search nanofiller for controlling release of drugs lamellar α-zirconium phosphate (α-ZrP) was modified with ether-amine oligomer (E-A). Synthesis and chemical modification followed specific reaction conditions and different EA:ZrP ratios. Infrared spectra showed strong interaction between P-OH and NH2 groups. Thermogravimetric curves showed tha
Mat. Res.. Publicado em: 17/01/2019
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3. Effects of the Structure and Composition of Montmorillonite on the Dimerization of Unsaturated Fatty Acids
The effects of structure and composition of different montmorillonites on their catalytic performance in the dimerization of unsaturated fatty acids were investigated. The dimerization reaction was performed at 240 ºC for 3 h, with montmorillonite as catalyst, and LiCl as the co-catalyst. The results showed that the specific surface areas of the different m
J. Braz. Chem. Soc.. Publicado em: 2018-07
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4. Improved Method for Preparation of Methoxy-Modified Kaolinite
A hydrated kaolinite-methanol intercalation compound (Kaol-MeOH (hydrated)) was synthesized by utilizing kaolinite/dimethyl sulfoxide intercalation compound (Kaol-DMSO) as an intermediary, and further displacement intercalation with butyl trimethylammonium chloride (BTAC) was also carried out. The obtained samples were characterized by X-ray diffraction (XRD
J. Braz. Chem. Soc.. Publicado em: 2018-01
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5. Intercalation of Molybdate Ions into Ni/Zn Layered Double Hydroxide Salts: Synthesis, Characterization, and Preliminary Catalytic Activity in Methyl Transesterification of Soybean Oil
This study reports the synthesis and characterization of a Ni/Zn layered double hydroxide salt intercalated with acetate ions and the subsequent replacement of the acetate ions with molybdate ions via an ion exchange reaction, conducted at two different pH values. Regardless of the pH employed during the synthesis, the basal spacing in the Ni/Zn layered doub
J. Braz. Chem. Soc.. Publicado em: 2017-07
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6. Oclusão de pares iônicos em espaços interlamelares como ferramenta para formação de híbridos luminescentes baseados em V IND. 2 O IND. 5 e MoO IND. 3 / Interlayer occlusion of ion pairs as tool for the production of V2O5 and MoO3-based luminescent materials
In the first part of this work, novel hybrid materials were developed by insertion of poly(diallymethylammonium chloride) PDDA and poly(allylamine hydrochloride) PAH polyelectrolytes into V2O5 and MoO3 interlayer spaces using hydrothermal treatment. A systematic study of the synthesis of hybrids materials by direct in situ reaction of PDDA and PAH polycation
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 24/02/2010
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7. Benzothiadiazoles: synthesis, photophysical and biological properties and palladacycles = Synthèse, propriétés photophysiques et biologiques de benzothiadiazoles et de dérivés cyclopalladés / Synthèse, propriétés photophysiques et biologiques de benzothiadiazoles et de dérivés cyclopalladés
Le travail présenté dans ce memoire a été realisé au Laboratory of Molecular Catalysis (Chapitre 1, 2 et 3) de l'Universidade Federal do Rio Grande do Sul, sous la direction du Prof. Jaïrton Dupont, et au Laboratoire de Synthèse Métallo Induites (Chapitre 4) de l'Université de Strasbourg, sous la direction du Dr. Michel Pfeffer, entre le mois d'Aoü
Publicado em: 2010
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8. Intercalação de íons lantanídeos e de poli(óxido de etileno) assistida por tensoativo na matriz hospedeira VOPO4.2H2O / Intercalation of ions Lanthanides and Poly (ethylene oxide) assisted by surfactant in host matrix of VOPO4.2H2O
Vanadium compounds are intensively studied due to their electrochemical, catalytic, magnetic and biological properties. In this work, our goal was to investigate the VOPO4.2H2O (vanadyl phosphate), which has a lamellar structure formed by VOPO4 sheets interconnected by weak interactions. Taking advantage of this structure, it is possible to synthesize severa
Publicado em: 2008
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9. Preparação e caracterização de pentóxido de vanádio mesoporoso e reações de intercalação / Synthesis and characterization of mesoporous vanadium pentoxide and intercalation reaction
Synthesis, characterization of vanadium pentoxide mesoporous and studies of properties of hybrids compound based on vanadium oxide xerogel and vanadium pentoxide mesoporous, intercalated with guest species have been the main of this thesis. The interest in those materials, that present a considerable structural and chemical modification, is due to the possib
Publicado em: 2007
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10. Nanotubos e nanobastões de oxidos e sulfetos de metais de transição obtidos via sistemas bidimensionais (lamelares) : preparação, caracterização e propriedades / Nanotubes and nanorods of transition metal oxides and sulfides obtained from bidimensional systems (layered compunds) : preparation, characteization and properties
This Thesis reports the preparation, characterization and properties of nanotubes and nanorods of transition metal oxides and sulfides obtained from bidimensional (Iamellar) structures. From the structural point view, nanotubes could be formed from bidimensional compounds by rolling its layers generating scroll-like nanotubes, or by the elimination of dangli
Publicado em: 2006
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11. Síntese e caracterização de um composto VOPO4-DMA
A layered matrix, alpha-VOPO4.2H2O was used as host species to produce a VOPO4.dimethylacetamide intercalation compound. The oxovanadium matrix and the synthesized hybrid were characterized by elemental analysis, infrared spectroscopy, thermogravimetry, X-ray diffractometry and SEM microscopy. The X-ray diffraction patterns show that the VOPO4.dimethylacetam
Química Nova. Publicado em: 2003-08
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12. Obtenção, caracterização e avaliação do desempenho catalitico de [alfa]-fosfatos de zirconio (IV) intercalados com Cu(II) ou Pt(II) na reação de HTS
The a-zirconium (IV) hydrogenphosphate, usually refereed as a-ZrP, is one of the most extensively studied members of the group 4 layered metal phosphates. This compound has received great attention in the last years due to it s intercalation, ionic condutivity, ion exchange and catalytic properties. From the catalytic point of view, the a-ZrP is particularly
Publicado em: 2001