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1. Experimental study of living free radical polymerization mediated nitroxide (NMRP) / Estudo experimental da polimerização via radical livre controlada em presença de radicais nitroxido (NMRP)
NMRP process (Nitroxide Mediated Radical Polymerization) has received increasing attention as a technique for production polymers with highly controlled structures, narrow molecular weight distribution (MWD) and polydispersity index dose to 1.0. In this work 2,2,6,6-tetramethyl-l-piperidinoxyl (TEMPO) is used as the stable radical to reversibly terminate the
Publicado em: 2006