Iminociclitois
Mostrando 1-1 de 1 artigos, teses e dissertações.
-
1. Heck arylation reaction with arenediazonium salts : applications in the total synthesis of polyhydroxylated prolines and pyrrolidines, rolipram and baclofen analogues, and in the formal synthesis of prepolycitrin A and polycitrin A / Reação de arilação de Heck com sais de arenodiazonio : aplicações nas sinteses totais de prolinas e pirrolidinas poliidroxiladas, rolipram e analogos do baclofeno, e na sintese formal de prepolicitrina A e policitrina A
The Heck-Matsuda arylation reaction is a valuable and extremely versatile synthetic procedure for carbon-carbon bond formation, based on the coupling of an olefin with an arenediazonium salt in the presence of a zerovalent palladium organometallic specie. Recently, the use of this reaction has been gaining space in total syntheses, demonstrating its viabilit
Publicado em: 2008