Imidazolium
Mostrando 1-12 de 34 artigos, teses e dissertações.
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1. Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture
Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazolium based IL combined with [Br]- and [Tf2N]- anions were used
Mat. Res.. Publicado em: 11/11/2019
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2. Thermal Stability and Kinetic of Decomposition of Mono- and Dicationic Imidazolium-Based Ionic Liquids
Phase transitions, thermal stability, thermokinetics and activation parameters of degradation reaction of the dicationic ionic liquids (ILs), 1,n-bis(3-methylimidazolium-1-yl)alkane ([BisAlk(MIM)2][2Br]) and monocationic ILs, 1-(3-methylimidazolium-1-yl)alkane ([Alk(MIM)][Br]), where Alk = Dec, DoDec, TetDec, (decane, dodecane, tetradecane) were evaluated. T
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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3. Silver Complex of an N-Heterocyclic Carbene Ligand with Bulky Thiocarbamate Groups
The synthesis of a new N-heterocyclic carbene with bulky S-arylthiocarbamate substituents was devised from the condensation between 2-chloromethyl-4-methy-l,6-[3,5-bis(trifluoromethyl)-phenyl]-S-phenyl-N,N-dimethylthiocarbamate and imidazole, resulting in the proligand N,N’-bis[(2-S-(N’’,N’’-dimethylthiocarbamoyl)-5-methyl)phenylmethyl]imidazolium
J. Braz. Chem. Soc.. Publicado em: 2018-08
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4. Unsymmetrically substituted imidazolium salts: synthesis, characterization and antimicrobial activity
ABSTRACT Unsymmetrically substituted imidazolium salts were synthesized and characterized using 1H-NMR and 13C-NMR. The antimicrobial activities of the salts were evaluated using the agar-well diffusion method against 14 bacteria and five yeasts. The minimal inhibitory concentrations (MIC) against seven bacteria and one yeast were also determined. Among the
Braz. J. Pharm. Sci.. Publicado em: 20/04/2017
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5. NANOPARTÍCULAS DE Au EM LÍQUIDO IÔNICO SUPORTADAS EM FILMES BIOPOLIMÉRICOS: UMA AULA PRÁTICA PARA INVESTIGAÇÃO DA ATIVIDADE ANTIMICROBIANA
The synthesis of Au nanoparticles (NPs) in ionic liquid (IL) supported on biopolymers films applied in the investigation of antimicrobial activity was introduced as a new experimental practice for undergraduates in the nanotechnology discipline at the Department of chemistry, at University Federal of Rio Grande- FURG. The Au NPs were synthesized by reduction
Quím. Nova. Publicado em: 2016-09
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6. Oxidative Desulfurization of Gasoline by Ionic Liquids Coupled with Extraction by Organic Solvents
In this work, desulfurization of real fluidized catalytic cracking (FCC) gasoline was investigated in dual steps; first in oxidative desulfurization (ODS) using imidazolium and pyrrolidonium based Brønsted acidic ionic liquids (ILs) as solvent and catalyst and hydrogen peroxide as oxidant. In second step, extractive desulfurization took place using organic
J. Braz. Chem. Soc.. Publicado em: 2016-06
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7. Synthesis and Characterization of 1-Methyl-3-Methoxysilyl Propyl Imidazolium Chloride – Mesoporous Silica Composite as Adsorbent for Dehydration in Industrial Processes
Ionic liquid – mesoporous silica composite was synthesized as a new adsorbent for dehydration in industrial processes. An ionic liquid (IL) with proved dehydration properties has been covalently anchored to mesoporous silica. The parameters of the synthesis were studied to produce a solid and stable composite. The material was then characterized by SEM, BE
Mat. Res.. Publicado em: 08/04/2016
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8. Solid, Solution and Gas Phase Interactions of an Imidazolium-Based Task-Specific Ionic Liquid Derived from Natural Kojic Acid
Um líquido iônico imidazólio de função específica derivado do ácido kójico natural teve suas interações supramoleculares investigadas no estado sólido, em solução e em fase gasosa. Diferentes técnicas como difração de raios X de monocristal, espectroscopia de ressonância magnética nuclear (NMR), espectrofotometria UV-Vis, medidas de conduti
J. Braz. Chem. Soc.. Publicado em: 2014-12
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9. A New Approach to CO2 Capture and Conversion Using Imidazolium Based-Ionic Liquids as Sorbent and Catalyst
Embora tecnologias de captura e armazenamento de carbono (CCS) estejam recebendo grande atenção para a mitigação do efeito estufa, ainda existem muitas desvantagens, tais como o aumento dos custos e gastos de energia associados à sua implementação. No entanto, o uso de CO2 como bloco de construção C1 em síntese orgânica pode ser muito atraente par
J. Braz. Chem. Soc.. Publicado em: 2014-12
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10. Líquidos iônicos como plastificantes em blendas de borracha nitrílica/polianilina
Two imidazolium-based ionic liquids (C4MIMTf2N and C4MIMBF4) were used to verify their influence on polyaniline (PANI) and nitrile rubber (NBR)/PANI blend properties and the vulcanization process. High conductivity values were observed for PANI-C4MIMTf2N samples and no interference was found for the C4MIMBF4 samples. These materials were added to NBR by mech
Quím. Nova. Publicado em: 2014
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11. Solventes verdes para biopolímeros: síntese e aplicação de líquidos iônicos na derivatização de celulose / Green solvents for biopolymers: synthesis of ionic liquids and their use in derivatization of cellulose
The work reported has the target of studying the acylation of cellulose under homogeneous reaction conditions. Imidazolium-based ionic Liquids (ILs) were employed as solvents, and the reaction was assisted by a microwave. These following processes have been studied: Optimization of the synthesis of ILs; ii) Effects of the structure of ILs on the dissolution
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 06/10/2011
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12. Biosensors of laccase based on hydrophobic ionic liquids derived from imidazolium cation
Biossensores contendo lacase (Aspergillus oryzae) e líquidos iônicos derivados do cátion 1-butil-3-metilimidazol (BMI) associados com os ânions hexafluorfosfato (BMI•PF6) ou bis(trifluormetilsulfonil)imida (BMI•Tf2N) foram construídos para determinação de adrenalina. O biossensor baseado no BMI•Tf2N foi selecionado por apresentar maior resposta
Publicado em: 2011