Hydrogenation
Mostrando 13-24 de 214 artigos, teses e dissertações.
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13. Estudio y caracterización del efecto de compuestos con titanio sobre el sistema hidruro Li-B-Mg-H con alta capacidad de almacenamiento de hidrógeno
ABSTRACT One of the main constraints for the implementation of hydrogen as energy carrier is the lack of an efficient and safe hydrogen storage system. Hydrogen storage in solid state through hydride compounds formation is a potential alternative to address this problem. In this work, it is studied the effect of different titanium based compounds (TiB2, LixT
Matéria (Rio J.). Publicado em: 19/07/2018
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14. Carbon Nanotube-Supported Copper-Cobalt Catalyst for the Production of Higher Carbon Number Alcohols through Carbon Monoxide Hydrogenation
A series of carbon nanotube (CNTs)-supported copper-cobalt catalysts were prepared and investigated in a slurry reactor for their ability to selectively convert syngas into higher carbon number alcohols. The 7.5Cu7.5Co/CNTs catalyst achieved superior selectivity towards the formation of ethanol (30.1%) and C2+ alcohols (57.7%), while the 10Co5Cu/CNTs catalys
J. Braz. Chem. Soc.. Publicado em: 2018-07
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15. Screening and Binding Analysis of Flavonoids with Alpha-Amylase Inhibitory Activity from Lotus Leaf
Lotus leaf is gaining growing popularity due to its various benefits and widely usage. In this paper, ten flavonoids in lotus leaf extract were analyzed by high performance liquid chromatography (HPLC). Centrifugal ultrafiltration combined liquid chromatography was used to screen alpha-amylase inhibitors from ten flavonoids mixture and the binding degrees ra
J. Braz. Chem. Soc.. Publicado em: 2018-03
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16. MORE ACTIVE AND SULFUR RESISTANT BIMETALLIC Pd-Ni CATALYSTS
The influence of the kind of metal precursor and the sequence of impregnation on the properties of Pd-Ni catalysts was evaluated during the test reaction of selective hydrogenation of styrene to ethylbenzene by means of physicochemical characterization. The focus was put on the final hydrogenating activity and the resistance to deactivation by sulfided compo
Quím. Nova. Publicado em: 2018-02
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17. Investigation of Electrocatalysts for Selective Reduction of CO2 to CO: Monitoring the Reaction Products by on line Mass Spectrometry and Gas Chromatography
The carbon dioxide electrocatalytic reduction is central for the development of regenerative cycles of electrochemical energy conversion and storage. Herein, the gaseous products of the CO2 electroreduction were monitored by using an electrochemical cell on line coupled to a differential electrochemical mass spectrometer (DEMS), aiming at searching for elect
J. Braz. Chem. Soc.. Publicado em: 2017-09
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18. NOVOS HÍBRIDOS BASEADOS EM OXIHIDRÓXIDO DE FERRO(III) E NANOPARTÍCULAS DE OURO (AuNPs/FeOOH) COMO CATALISADORES PARA A REDUÇÃO DE POLUENTES ORGÂNICOS AMBIENTAIS
A new δ-FeOOH supported nano-Au catalyst was prepared by a facile method using HAuCl4 as the gold source and NaBH4 as the reducing agent. The samples (denoted as AuNPs/FeOOH) were characterized by means of X-ray diffraction (XRD), UV-vis and infrared spectroscopies and scanning electron microscope (SEM). The obtained characterization data confirmed the form
Quím. Nova. Publicado em: 2017-06
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19. MODELING STYRENE HYDROGENATION KINETICS USING PALLADIUM CATALYSTS
Abstract The high octane number of pyrolysis gasoline (PYGAS) explains its insertion in the gasoline pool. However, its use is troublesome due to the presence of gum-forming chemicals which, in turn, can be removed via hydrogenation. The use of Langmuir-Hinshelwood kinetic models was evaluated for hydrogenation of styrene, a typical gum monomer, using Pd/9%N
Braz. J. Chem. Eng.. Publicado em: 2016-09
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20. Influence of Hydrogenation on Residual Stresses of Pipeline Steel Welded Joints
Hydrogen embrittlement is a phenomenon that affects the performance of steel used for oil and gas pipelines. This paper presents a study of the effect of hydrogenation on the residual stresses of an API 5L X65 steel pipe. Residual stresses were analyzed by X-ray diffraction technique using the sin2Ψ method. The hydrogenation of base metal and welded joint s
Mat. Res.. Publicado em: 15/08/2016
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21. Identification and Synthesis of the Male-Produced Sex Pheromone of the Soldier Beetle Chauliognathus fallax (Coleoptera: Cantharidae)
Chauliognathus fallax Germar 1824 (Coleoptera: Cantharidae) occurs in North and South America and Australia. Gas chromatographic (GC) analyses of volatiles released by adults showed the presence of a male specific compound. GC coupled with electroantennographic detection (GC-EAD) showed that this compound is exclusively bioactive on female antennae, suggesti
J. Braz. Chem. Soc.. Publicado em: 2016-08
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22. Effect of Metal Dispersion on the Hydrogenation of 2-Amyl Anthraquinone over Pd/Al2O3 Catalyst
A series of highly dispersed Pd/Al2O3 catalysts were prepared via the polyol method. The catalysts were characterized by nitrogen adsorption, X-ray diffraction (XRD), UV-Vis spectrophotometry, temperature programmed reduction (TPR) and transmission electron microscopy (TEM). The influence of Pd particle size on the hydrogenation of 2-amyl anthraquinone (AAQ)
J. Braz. Chem. Soc.. Publicado em: 2016-06
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23. THE WILKINSON COMPLEX AS A HETEROGENEOUS CATALYST IN THE PARTIAL HYDROGENATION OF 1-HEPTYNE. REGENERATION OF THE COMPLEX
The Wilkinson complex was tested as a catalyst in the partial hydrogenation of 1-heptyne, a medium chain alkyne, at a temperature of T = 303 K and hydrogen pressure PH2 = 150 kPa. The tests were performed in homogeneous system as well as heterogeneous system, supporting the complex on i) γ-Al2O3 and ii) a commercial carbonaceous material, RX3. Characterizat
Quím. Nova. Publicado em: 2016-06
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24. ADVANCED CONTROL OF A COMPLEX CHEMICAL PROCESS
Abstract Three phase catalytic hydrogenation reactors are important reactors with complex behavior due to the interaction among gas, solid and liquid phases with the kinetic, mass and heat transfer mechanisms. A nonlinear distributed parameter model was developed based on mass and energy conservation principles. It consists of balance equations for the gas a
Braz. J. Chem. Eng.. Publicado em: 2016-03