Equilibria
Mostrando 13-24 de 336 artigos, teses e dissertações.
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13. Phase Diagram Study for the PbO-ZnO-CaO-SiO2-"Fe2O3" System in Air with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 Weight Ratios
An experimental study on the phase equilibrium and the liquidus isotherms for the PbO-ZnO-CaO-SiO2-"Fe2O3" system with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 weight ratios, respectively, was carried out in the temperature range 1100-1300ºC (1373-1573 K). High temperature phases were determined by the equilibrium-quenching method. Results are presented in
Mat. Res.. Publicado em: 05/06/2017
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14. Evolution of Microstructure in Al-Si-Cu System Modified with a Transition Element Addition and its Effect on Hardness
The effect of Ni 1-2 wt.% addition on the microstructure and hardness of the aged A319 alloy were studied. Characterization analyses by x-ray diffraction, optical microscopy and scanning electron microscopy suggest clearly that Ni addition forms Al-Ni-Cu-Fe, Al-Cu-Ni and Al-Ni intermetallic compounds that correlates well with equilibria conditions. Analyses
Mat. Res.. Publicado em: 18/08/2016
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15. Thermodynamic Study on the Acid-Base Properties of Antioxidant Compound Ascorbic Acid in Different NaClO4 Aqueous Ethanol Solutions
The proton dissociation equilibria of ascorbic acid were investigated using a combination of spectrophotometric/potentiometric techniques at constant temperature 25.0 ± 0.1 °C. The study was carried out over a wide range of ionic strengths of 0.1-3.0 mol dm-3 NaClO4 in ethanol-water mixture (1:1). The Gran's method was used for glass electrode calibration
J. Braz. Chem. Soc.. Publicado em: 2016-05
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16. Thermobarometry and electron-microprobe Th-U-Pb monazite dating in garnet metapelites from the Capelinha Formation, Araçuaí Orogen, Brazil
Abstract The Capelinha Formation (Macaúbas Group) consists of a lower quartzitic unit with metamafic intercalations and an upper metapelitic sequence. It occurs in a complex tectono-metamorphic sector of the Araçuaí orogen, where post-collisional collapse-related structures superimposed collisional structures. The garnet-bearing assemblages started crysta
Rem: Rev. Esc. Minas. Publicado em: 2016-03
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17. Modeling Chemical Reactivity in Ionic Detergent Micelles: a Review of Fundamentals
Ionic detergent micelles have the capacity to solubilize organic substrates, interact selectively with counterions, repel coions, exhibit partial "dissociation" of the counterions, grow in size with added salt, affect the position of chemical equilibria, accelerate or inhibit the rates of chemical reactions, modulate photochemical reactivity and determine th
J. Braz. Chem. Soc.. Publicado em: 2016-02
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18. PHASE EQUILIBRIA FOR BINARY SYSTEMS CONTAINING IONIC LIQUID WITH WATER OR HYDROCARBONS
Abstract In this work, the mutual solubilities of sets of ionic liquids ([CnMIM] [TF2N] (n = 4, 8, 12), [C4PY] [TF2N], [C8MIM] [OTF]) and organic compounds (heptane, o-xylene, toluene, or water) are investigated. The experimental data measured for these systems were used to adjust the binary interaction parameters between their components for the Non-Random
Braz. J. Chem. Eng.. Publicado em: 2015-12
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19. LIQUID-LIQUID EQUILIBRIUM FOR TERNARY SYSTEMS CONTAINING ETHYLIC BIODIESEL + ANHYDROUS ETHANOL + REFINED VEGETABLE OIL (SUNFLOWER OIL, CANOLA OIL AND PALM OIL): EXPERIMENTAL DATA AND THERMODYNAMIC MODELING
Abstract Phase equilibria of the reaction components are essential data for the design and process operations of biodiesel production. Despite their importance for the production of ethylic biodiesel, the reaction mixture, reactant (oil and ethanol) and the product (fatty acid ethyl esters) up to now have received less attention than the corresponding system
Braz. J. Chem. Eng.. Publicado em: 2015-09
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20. Adsorption of Transition Metal Chlorides by Silica with Grafted 1-n-Propyl-3-Methylimidazolium Chloride
Silica with grafted 1-n-propyl-3-methylimidazolium chloride was investigated as adsorbent for the removal of cobalt(II), copper(II), zinc(II), cadmium(II) and mercury(II) chlorides from alcoholic and aqueous solutions. The adsorption proceeds via the formation of metal-chloride anionic complexes detained near the grafted organic cations as counterions. This
J. Braz. Chem. Soc.. Publicado em: 2015-06
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21. Solubility measurement and solid-liquid equilibrium model for the ternary system MgBr2 + MgSO4 + H2O at 288.15 K
The solubility of magnesium minerals and the refractive index of the ternary system MgBr2 + MgSO4 + H2O at 288.15 K were investigated using an isothermal dissolution method. It was found that there are two invariant points in the phase diagram and the solubility isotherm of this ternary system consists of three branches, corresponding to equilibrium crystall
Braz. J. Chem. Eng.. Publicado em: 2014-06
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22. Solid-liquid stable phase equilibria of the ternary systems MgCl2 + MgB6O10+ H2O AND MgSO4 + MgB6O10 + H2O at 308.15 K
The solubilities and the relevant physicochemical properties of the ternary systems MgCl2 + MgB6O10 + H2O and MgSO4 + MgB6O10 + H2O at 308.15 K were investigated using an isothermal dissolution method. It was found that there is one invariant point, two univariant curves, and two crystallization regions of the systems. The systems belong to a simple co-satur
Braz. J. Chem. Eng.. Publicado em: 2014-03
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23. Collaborative dominance: when doing unto others as you would have them do unto you is reasonable
In this article, we analyze how reasonable it is to play according to some Nash equilibria if players have a preference for one of their opponents' strategies. To formalize our argument, we propose the concepts of collaborative dominance and collaborative equilibrium studying some of its properties. First, we prove that if the collaborative equilibrium exist
Pesqui. Oper.. Publicado em: 25/10/2013
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24. Isothermal section of the Ti-Si-B system at 1250 ° C in the Ti-TiSi2-TiB2 region
A partial isothermal section (Ti-TiSi2-TiB2 region) of the ternary Ti-Si-B system at 1250 ° C was determined from heat-treated alloys prepared via arc melting. Microstructural characterization has been carried out through scanning electron microscopy (SEM), x-ray diffraction (xRD) and wavelength dispersive spectrometry (WDS). The results have shown the stab
Mat. Res.. Publicado em: 22/10/2013