Epichlorohydrin
Mostrando 1-12 de 34 artigos, teses e dissertações.
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1. Synthesis of Eugenol-Fluorinated Triazole Derivatives and Evaluation of Their Fungicidal Activity
Eugenol (C10H12O2, 4-allyl-2-methoxyphenol) is a phenolic natural product that has several biological activities and possibilities of applications. It is herein described the synthesis of eugenol-fluorinated triazole derivatives and evaluation of their fungicidal activity. The reaction of eugenol with epichlorohydrin resulted in the preparation of (±)-2-((4
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. IMPROVING THE CATALYTIC FEATURES OF THE LIPASE FROM Rhizomucor miehei IMMOBILIZED ON CHITOSAN-BASED HYBRID MATRICES BY ALTERING THE CHEMICAL ACTIVATION CONDITIONS
The lipase from Rhizomucor miehei (RML) has been immobilized on chitosan-based hybrid (sodium alginate or carrageenan) matrices activated with glycidol (GLY), epichlorohydrin (EPI) or glutaraldehyde (GLU) groups. Then, the properties of the different biocatalysts have been evaluated and compared with the soluble RML. Thermal stability (at pH 7.0 and 60 °C)
Quím. Nova. Publicado em: 2020-09
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3. SYNTHESIS OF MESOPOROUS γ-ALUMINA AND ITS CATALYTIC PERFORMANCE IN DICHLOROPROPANOL CYCLIZATION
This paper discusses the synthesis and resulting catalytic performance of mesoporous alumina using aluminum isopropoxide as the aluminum source, and synthesized organosiloxane KH560-540 as template. The effects of the hydrothermal conditions, as well as the amount of templating agent at pH values of 5-9 on the structure of the synthesized mesoporous alumina
Quím. Nova. Publicado em: 21/10/2019
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4. Agarose Based Magnetic Solid-Phase Extraction-Magnetic Field Agitation for Determination of Trace Amounts of Molybdenum in Beans
A magnetic solid-phase extraction method based on agarose coated magnetic nanoparticles (ACMNPs) coupled to a magnetic field agitation (MFA) device was developed and used for the preconcentration and graphite furnace atomic absorption spectrometric determination of trace amounts of MoVI in beans. The formation of the nanoparticles and their encapsulation in
J. Braz. Chem. Soc.. Publicado em: 2016-04
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5. Studies on the Thermal, Mechanical and Chemical Resistance Properties of Natural Resource Derived Polymers
Cardanol-based epoxidized resole resins (ERCF) were synthesized by reacting resole type phenolic resin (RCF) and epichlorohydrin in basic medium, at 120 °C. Resole type phenolic resins were synthesized by reacting cardanol (C) and formaldehyde (F) in the presence of sodium hydroxide, as catalyst, at five different temperatures ranging between 60-80 °C with
Mat. Res.. Publicado em: 03/11/2015
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6. Triagem de suportes orgânicos e protocolos de ativação na imobilização e estabilização de lipase de Thermomyces lanuginosus
Lipase from Thermomyces lanuginosus was covalently immobilized on activated poly-hydroxybutyrate, sugarcane bagasse and the chemically modified hybrid hydrogel chitosan-alginate prepared by different strategies. Among the tested supports, chitosan-alginate chemically modified with 2,4,6-trinitrobenzenesulfonic acid rendered derivatives with the highest hydro
Quím. Nova. Publicado em: 2013
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7. Water Influence in Poly(epichlorohydrin) Synthesis: An Intermediate to Energetic Propellants
Abstract: Poly(epichlorohydrin) was synthesized using anhydrous and hydrate stannic chloride, separately, as initiator. Reactions were conducted in the presence of a diolat 70°C. Polymers were characterized by Fourier Transform Infrared I Spectroscopy (FT-IR), differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and hydroxyl value d
J. Aerosp. Technol. Manag.. Publicado em: 2012-03
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8. Evaluation of Caesalpinia pulcherrima endospermic gum as affinity matrices for galactose-binding lectins interaction
Lectins are proteins or glycoproteins able to bind, specifically and reversibly carbohydrates and glycoconjugates. Considering this ability, the utilization of Caesalpinia pulcherrima seeds polysaccharides as an affinity matrix was tested. The endospermic gum were solubilized in distinct concentrations of NaOH and treated with different amounts of epichloroh
Brazilian Archives of Biology and Technology. Publicado em: 2011-04
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9. Avaliação da sorção de Cu (II) e Hg (II) pela Sargassum sp modificado com epicloridrina / Evaluation of the sorption of Cu (II) and Hg (II) by sargassum sp modifiers with epichlorohydrin
É crescente o aumento da preocupação do homem com a contaminação de ambientes aquáticos uma vez que da subsistência dos mesmos depende o bem estar de todos. Ao mesmo tempo em que cresce a preocupação tem aumentado a quantidade de pesquisas em busca de tecnologias alternativas ao tratamento e remediação de efluentes aquosos contaminados pelas mais
Publicado em: 2011
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10. Dynamic adsorption of chromium ions onto natural and crosslinked chitosan membranes for wastewater treatment
Water pollution with heavy metals is a matter of major concern for public health and also for natural resource management. The present study investigated the effect of chemical modifications on biopolymeric adsorbents (based on chitosan membranes) for chromium removal using fixed-bed dynamic adsorption technique. Parameters such as flow rate, initial concent
Materials Research. Publicado em: 2010-03
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11. Production of chemically modified chitosan microspheres by a spraying and coagulation method
Chitosan microspheres can be used in several applications, as biomaterials, in biotechnology processes and as adsorbents. The control of particle size in microsphere production is important to make these applications viable. This study focuses on the production and morphological characterization of chitosan microspheres. Microspheres were prepared by a spray
Materials Research. Publicado em: 2007-12
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12. Mechanical and barrier properties, solubility and microstructure of amaranth flour films crosslinked with epicholorohydrin or blended with poly (vinyl alcohol). / Propriedades mecanicas e de barreira, solubilidade e microestrutura de filmes de farinha de amaranto modificada com epicloridrina ou misturada com poli (vinil alcool).
O amaranto apresenta-se como uma matéria prima interessante para a elaboração de filmes biodegradáveis por seu conteúdo em amido, proteína e lipídeos. Embora o amaranto não seja nativo do Brasil, seu cultivo está sendo desenvolvido nos solos dos cerrados brasileiros com bons resultados. Isto incentiva o desenvolvimento de alternativas para o uso com
Publicado em: 2007