Elemental Analysis
Mostrando 1-12 de 380 artigos, teses e dissertações.
-
1. Catalytic Effects of Ruthenocene Bimetallic Compounds Derived from Fused Aromatic Ring Ligands on the Main Oxidizing Agent for Solid Rocket Motor
We report the catalytic effect of three ruthenocene bimetallic compounds derived from fused aromatic rings of general formula [{Cp*Ru}2L], with Cp*: pentamethylcyclopentadiene and L = pentalene (1), 2,6-diethyl-4,8-dimethyl-s-indacene (2), and 2,7-diethyl-as-indacene (3), on the thermal decomposition of ammonium perchlorate (AP). The new compound 3 was chara
Journal of the Brazilian Chemical Society. Publicado em: 2022
-
2. Assessment of Urban Contamination by Sewage in Sediments from Ipojuca River in Caruaru City, Pernambuco, Brazil
The Ipojuca River is considered the third most polluted river in Brazil due to the intense anthropogenic activities in the surrounding urban areas. The most important effluent is sewage discharge, which is responsible for considerable contamination. Traditional analyses (infrared spectroscopy, organic matter (OM), elemental analysis and granulometry) and adv
Journal of the Brazilian Chemical Society. Publicado em: 2022
-
3. Agro-Industrial Waste Valorization: Transformation of Starch from Mango Kernel into Biocompatible, Thermoresponsive and High Swelling Nanogels
Mango industry processing disposes 40-60% of this fruit as residues, such as peels and kernels. The exploration of bioproducts from these industrial rejects can reduce environmental impact besides of producing high value-added materials. In this scenario, carboxymethyl starch nanoparticles were produced from mango (Mangifera indica L.) kernel starch. These n
J. Braz. Chem. Soc.. Publicado em: 2021-08
-
4. Comparison between barley malt protein quantification methods
Abstract Brazil imports about 60% of all the malt used by the brewing industry which is spread throughout the country. Even though it is an agricultural country, only a small portion of the barley production has the characteristics to produce barley malt for brewing. Seeking supply to the ever-growing demand and reducing the dependency on other countries and
Food Sci. Technol. Publicado em: 2021-06
-
5. Synthesis, Hypoglycemic Effect, Antimicrobial and Molecular Docking Studies of Organotin(IV) Complexes Derived From N-Phthalimido β-Amino Acid Derivatives
N-Phthalimido β-amino acid derivatives, 3-phthalimido-3(2-hydroxyphenyl) propanoic acid (P2HPA) and 3-phthalimido-3(2-nitrophenyl) propanoic acid (P2NPA) with new series of di- and triorganotin(IV) complexes (1-12) have been designed and synthesized. All the ligands and organotin(IV) complexes were characterized by elemental analysis, Fourier transform infr
J. Braz. Chem. Soc.. Publicado em: 2021-05
-
6. MODIFICAÇÃO QUÍMICA DO POLIPROPILENO ATRAVÉS DA INTRODUÇÃO DE GRUPOS SULFÔNICOS PARA APLICAÇÃO COMO CATALISADOR EM REAÇÕES DE ESTERIFICAÇÃO
In this work, the chemical modification of pristine polypropylene was carried out through sulfonation reactions with concentrated sulfuric acid (PPS1) and fuming sulfuric acid (PPS2), for production of heterogeneous catalysts used in esterification reactions. Fourier transform infrared spectroscopy, elemental analysis, degree of substitution and ion exchange
Quím. Nova. Publicado em: 2021-04
-
7. EVALUATION OF THE CHEMICAL COMPOSITION AND STRUCTURE OF ASPHALTENES FROM THREE OFFSHORE BRAZILIAN BIODEGRADED HEAVY OILS
Asphaltenes fractions were extracted and purified from three heavy Brazilian oils. Their mass compositions of C, H, N, Ni and V were obtained from elemental analysis and S and O atomic percentages from EDS. The H/C ratios showed high degree of unsaturation, while the O atomic percentages indicated more pronounced biodegradation effects on two samples. Quanti
Quím. Nova. Publicado em: 2021-04
-
8. SYNTHESIS, CHARACTERIZATION, DFT MODELING AND IN VITRO ANTIMYCOBACTERIAL ACTIVITY ASSAYS OF A SILVER(I)-ISONIAZID COMPLEX
In the present work, a silver(I) complex with the antimycobacterial drug isoniazid (inh) is described. Elemental and thermogravimetric analyses confirmed a 1:1 metal:ligand ratio for the silver-isoniazid (Ag-inh) complex with molecular composition AgC6H7N3O·NO3. Infrared (IR) analysis suggests a bidentate coordination of isoniazid to silver by the nitrogen
Quím. Nova. Publicado em: 2021-03
-
9. A Calix[4]arene-Functionalized Perylene Imide and Its Luminescence Properties
In this study, new perylene-derived molecules were synthesized as perylene-3,4,9,10-tetracarboxylic acid monoanhydride monopotassium carboxylate 1; N-(3-propanol)perylene-3,4,9,10-tetracarboxylic-3,4-(monoimide)anhydride-9,10-acid potassium carboxylate 2; 5,11,17,23-tetra(tert-butyl)-25,27-bis(3’-bromopropoxy)-26,28-(dihydroxy)calix[4]arene 3; 5,11,17,23-t
J. Braz. Chem. Soc.. Publicado em: 2020-11
-
10. Synthesis, Characterization, Absorption and Fastness Properties of Novel Monoazo Dyes Derived from 1-Phenyl-3-amino-4-(2-thiazolilazo)pyrazol-5-one
Monosubstitute thiazolyl amines were diazotized in acetic acid, coupled to 1-phenyl-3-aminopyrazol-5-one (1a-1c) and acetylated to obtain the 2a-2c dyes. The dyes were characterized by elemental analysis and spectroscopic (Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), ultraviolet (UV)) methods. The effects on the visible absorption spe
J. Braz. Chem. Soc.. Publicado em: 2020-09
-
11. New Magnetic Fe Oxide-Carbon Based Acid Catalyst Prepared from Bio-Oil for Esterification Reactions
In this work, bio-oil (an organic matrix rich in oxygen functionalities) was used to efficiently dissolve and disperse Fe3+ which upon thermal treatment produced a carbon containing dispersed and encapsulated Fe oxide magnetic nanoparticles. These materials were prepared by dissolution of 8, 16 and 24 wt.% Fe3+ salt in bio-oil followed by treatment at 400, 4
J. Braz. Chem. Soc.. Publicado em: 2020-08
-
12. Should kidney transplants during the COVID-19 pandemic be canceled or maintained?
The preparation, characterization, theoretical calculations and biological application of four RuII complexes with 2-picolinate (pic), 2,2’-bipyridine (bipy) and P-P as ligands [P-P = 1,1-bis(diphenylphosphino)methane (dppm-1), 1,2-bis(diphenylphosphino)ethane (dppe-2), 1,3-bis(diphenylphosphino)propane (dppp-3) or 1,1’-bis(diphenylphosphino)ferrocene (d
Rev. Assoc. Med. Bras.. Publicado em: 2020-07