Electron Electron Interactions
Mostrando 1-12 de 702 artigos, teses e dissertações.
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1. Preparation and performance of magnetic zirconium-iron oxide nanoparticles loaded on palygorskite in the adsorption of phosphate from water
Magnetic zirconium-iron oxide nanoparticles loaded on palygorskite as a low-cost adsorbent was produced by one-step co precipitation technique and its properties for phosphate adsorption were overall investigated. The Brunauer Emmett Teller (BET) specific surface area analysis, scanning electron microscopy (SEM), thermo gravimetric analysis (TGA), Fourier tr
Química Nova. Publicado em: 2022
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2. Through-Bond and Through-Space Interactions in [2,2]Cyclophanes
The interpretation of the distortions of the electron distribution in [2,2]cyclophanes (22-CPs) is controversial. Some studies indicate that there is an accumulation of electron density (ρ) outside the cavity of 22-CPs. The nature of through-space (ts) interaction is still under debate. The relative importance of ts and through-bond (tb) is an open question
J. Braz. Chem. Soc.. Publicado em: 2021-07
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3. Nickel-Cerium Layered Double Hydroxide as Electrocatalyst for Glycerol Oxidation
A new nickel based layered double hydroxide nanomaterial, Ni0.8Ce0.2-LDH, constituted by about 3 nm large nanoparticles exhibiting enhanced electrocatalytic properties towards oxidation of glycerol in alkaline media, was prepared by incorporation of 20 wt.% of CeIII ions into α-nickel hydroxide. This can be oxidized to CeIV, as demonstrated by X-ray photoel
J. Braz. Chem. Soc.. Publicado em: 2020-11
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4. COVID-19 and stroke: a thromboembolic hypothesis
A new nickel based layered double hydroxide nanomaterial, Ni0.8Ce0.2-LDH, constituted by about 3 nm large nanoparticles exhibiting enhanced electrocatalytic properties towards oxidation of glycerol in alkaline media, was prepared by incorporation of 20 wt.% of CeIII ions into α-nickel hydroxide. This can be oxidized to CeIV, as demonstrated by X-ray photoel
Rev. Assoc. Med. Bras.. Publicado em: 2020-11
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5. Well Defined Rich Electronic Structure: Facile Approach for Nido-Carborane Fused Azaspirodecaniums in Water Solution
A novel bis-dumbbell shape of a multi cation around a azaspirodecanium combined with nido-carborane was prepared in a single step in good yield starting from pyrrolidine and 1,3-dichloropropane to give one compound and from piperidine and 1,4-dichlorobutane to give the other. This is the first report of an electrolyte azaspirodecanium-boron-cluster structure
J. Braz. Chem. Soc.. Publicado em: 2020-01
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6. UNRAVELING THE SOLVATOCHROMISM OF A TRIARYLMETHANE DYE BY RESONANCE RAMAN SPECTROSCOPY
The effect of the solvent on the electronic properties of the triarylmethane dye rosolic acid (RA) is investigated by means of UV-VIS and resonance Raman (RR) spectroscopies. The comparison of the solvatochromic behavior of both neutral and dianionic species of RA in acetonitrile, dimethylsulfoxide, and methanol illustrates the effect of polarity and hydroge
Quím. Nova. Publicado em: 05/12/2019
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7. Hydrogen production from aqueous glycerol using titanate nanotubes decorated with Au nanoparticles as photocatalysts
Abstract: Protonated titanate nanotubes (HTiNts) were synthesized using the hydrothermal method, followed by proton exchange with acid. Gold nanoparticles decorated titanate nanotubes (AuHTiNts) were obtained by the reduction of AuCl4- under vigorous stirring with an aqueous solution of HTiNts containing 1 wt% of ascorbic acid. To investigate the surface str
An. Acad. Bras. Ciênc.. Publicado em: 28/11/2019
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8. Influence of Composition on Mechanical Properties of Cassava Starch, Sisal Fiber and Carnauba Wax Biocomposites
Concern for sustainable development has provided significant improvements in the development of biodegradable materials. This work aims to evaluate, through a central composite design (CCD), the mechanical properties of cassava starch-based biocomposites manufactured with different compositions of carnauba wax (CW), sisal fiber (SF) and glycerol (G). The bio
Mat. Res.. Publicado em: 24/10/2019
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9. Interplay between Near-Field Properties and Au Nanorod Cluster Structure: Extending Hot Spots for Surface-Enhanced Raman Scattering
Materials science has observed a continuous increase in the use of metal nanoparticles in a wide range of studies, from fundamental physics to technological applications such as photocatalysis and optical communication devices. This broad scope has the same fundamental origin, the localized surface plasmons, whose excitation leads to strong light confinement
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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10. Green synthesis and Characterization of ZnO-CoFe2O4 Semiconductor Photocatalysts Prepared Using Rambutan (Nephelium lappaceum L.) Peel Extract
In this work, the semiconductor of ZnO-CoFe2O4 composites were prepared by green synthesis approach using rambutan peel extract (Nephelium lappaceum L.) as a capping agent. X-ray diffraction patterns of composites showed the main peaks of ZnO at 2θ = 31.8°, 34.5°, and 36.2° corresponding to hexagonal wurtzite structure and weak peak at 2θ = 35.4° for c
Mat. Res.. Publicado em: 30/09/2019
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11. Palladium Nanoparticles Supported on β-cyclodextrin Functionalised Poly(amido amine)s and their Application in Suzuki-Miyaura Cross-Coupling Reactions
Herein, the synthesis, characterization and catalytic application of an organic-inorganic, palladium (Pd)-containing hybrid material, poly(amidoamine)-cyclodextrin (Pd@PAAs-CD), is reported as an efficient catalyst for Suzuki-Miyaura coupling reactions. The structure of Pd@PAAs-CD was confirmed by Fourier transform infrared spectroscopy (FTIR), transmission
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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12. STUDY OF THE CHROMIUM(VI) REMOVAL FROM AQUEOUS SYSTEMS BY COBALT NANOPARTICLES
The cobalt nanoparticles (NPs-Co) were synthesized and applied in the removal of Cr(VI). The obtained nanomaterials presented magnetic properties and were characterized by the techniques of Transmission Electron Microscopy and X-ray diffraction. The NPs-Co, with a diameter of less than 50 nm, had a composition based on metallic cobalt and cobalt oxide. The N
Quím. Nova. Publicado em: 18/07/2019