Electrochemical Model
Mostrando 1-12 de 99 artigos, teses e dissertações.
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1. Synergy between Experimental and Theoretical Investigations Reveals the Anti‑Corrosion Efficiency of Imine-Chalcones
The inhibitory action of three imine-chalcones on carbon steel corrosion in HCl was investigated by theoretical and experimental methods. Quantum descriptors were calculated at the conductor-like polarizable continuum model (CPCM)-Becke-3 Parameter-Lee-Yang-Parr (B3LYP)-D3/def2-TZVPP level allowing the prediction of efficiency inhibition ranking. Electrochem
J. Braz. Chem. Soc.. Publicado em: 2021-08
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2. Desenvolvimento de software e interface para o controle por retroalimentação atrasada em sistemas eletroquímicos
In this paper, we show the development of a LabVIEW algorithm able to apply the delayed feedback control on oscillatory electrochemical reactions. The coupling of the control and the experiments was carried out by a real-time apparatus, measuring the faradaic current and, in sequence, applying a calculated circuit voltage as an analog output. The setup was u
Quím. Nova. Publicado em: 2021-06
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3. Voltammetric Generation and Kinetic Stability of Nitro Anion Radical from Nitrofurazone in Ionic Liquids
The nitrofurazone (NF) electrochemical reduction has been studied by cyclic voltammetry (CV) and square wave voltammetry (SWV) in non-aqueous medium using three different ionic liquids (IL): BMImTf2N, BMImBF4 and BMMImTf2N, having a carbon fiber microelectrode as working electrode. In all of them, two reversible cathodic peaks were recorded for NF. Under hig
J. Braz. Chem. Soc.. Publicado em: 2021-04
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4. ANALYTICAL EXPRESSIONS FOR THE CONCENTRATION AND CURRENT IN THE REDUCTION OF HYDROGEN PEROXIDE AT A METAL-DISPERSED CONDUCTING POLYMER FILM
A mathematical model describing the reduction of Hydrogen peroxide (H2O2) to water in a metal dispersed conducting polymer film is discussed. The model is based on a system of reaction-diffusion equations containing a non-linear term related to Michaelis-Menten kinetics of the enzymatic reaction. The approximate analytical expressions corresponding to the co
Quím. Nova. Publicado em: 2020-01
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5. Reduction of Aqueous Ag+ Steered by Electrochemical Plasma: Connecting the Bulk pH Variation with the Reaction Pathways for Hydrated Electrons
Reduction of silver cations followed by nanoparticle (Ag-NPs) synthesis is a model process to understand the reduction mechanism induced by a discharge over an aqueous surface, termed electrochemical plasma. This work aims at studying the silver reduction reaction steered by electrochemical plasma in the presence of other chemically active plasma-related int
J. Braz. Chem. Soc.. Publicado em: 23/05/2019
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6. Estudo de recobrimentos de silicato e aluminato obtidos por oxidação por plasma eletrolítico em liga de alumínio
RESUMO As ligas de Alumínio são utilizadas para diversas finalidades e para a maioria dos casos a superfície desses materiais precisa ser modificada a fim de se melhorar propriedades como resistência ao desgaste e corrosão. Neste cenário, o processo de oxidação por plasma eletrolítico (PEO) surge como uma alternativa viável para produção de recob
Matéria (Rio J.). Publicado em: 20/05/2019
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7. Continuous electrochemical reactor improved by the addition of Moringa oleífera lam extract: optimization of operational conditions for Blue 5G dye removal
Resumo Os efluentes das indústrias têxteis são conhecidos pela dificuldade de tratamento, constituindo um campo de aplicação de tecnologias alternativas para o tratamento. Neste contexto, um sistema de tratamento híbrido, composto por eletrocoagulação associada à adição de coagulante natural (extrato de sementes de Moringa oleífera lam), visa uti
Rev. Ambient. Água. Publicado em: 09/05/2019
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8. Anticorrosive Effect of PVP 40000 Against AISI 1020 Carbon Steel in HCl
Polymers have received considerable attention for replacing synthetic inorganic and organic anti-corrosion inhibitors since they are not as toxic for the environment, besides being cheaper. Polyvinylpyrrolidone (PVP) has been studied due to its applicability, solubility, very low toxicity, cost and efficiency in corrosion inhibition against metals, such as z
Mat. Res.. Publicado em: 29/10/2018
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9. AVALIAÇÃO DA ADSORÇÃO E ESTUDO ELETROQUÍMICO DE CÉLULAS SOLARES PRODUZIDAS COM TiO2 E CORANTE EXTRAÍDO DO HIBISCUS
Dye-sensitized solar cells using natural dyes have lower cost when compared to ruthenium-based dyes. This paper aims to evaluate, electrochemically, solar cells composed of TiO2 with dye extracted from the Hibiscus(var. Sabdariffa) and propose an adsorption model capable of predicting the adsorption mechanism of the dye on the semiconductor surface. The char
Quím. Nova. Publicado em: 2018-05
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10. Simultaneous Determination of Different Phenolic Compounds Using Electrochemical Biosensor and Multivariate Calibration
Phenolic compounds are important environmental contaminants due to their high toxicity and persistence in the environment. The use of enzyme-based electrochemical biosensors is a simple, sensitive and low-cost alternative for the determination of these pollutants in contaminated waters. However, in most cases, it is impossible to detect specific compounds in
J. Braz. Chem. Soc.. Publicado em: 2018-03
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11. FOTOELETROCATÁLISE EM SEMICONDUTORES: DOS PRINCÍPIOS BÁSICOS ATÉ SUA CONFORMAÇÃO À NANOESCALA
The science of semiconductors, essential in electronics, is pivotal also for the most active research fields of environmental science and engineering today - the development of solar energy conversions and advanced oxidation processes, exemplified by the harvesting of sun daylight to produce electric energy, environmentally friendly fuels and to clean up wat
Quím. Nova. Publicado em: 2018-03
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12. Mechanisms of Ion Detection for FET-Sensors Using FTO: Role of Cleaning Process, pH Sequence and Electrical Resistivity
The use of FTO samples as an extended gate field effect transistor biosensor is presented. The FTO samples were produced by spray pyrolysis technique. The cleaning process is shown to have a fundamental importance for the final sensitivity of the samples when multiple re-usage is adopted. The role of electrical resistivity and morphology of the films are inv
Mat. Res.. Publicado em: 31/07/2017