Degradation Of Chlorophenols
Mostrando 1-12 de 20 artigos, teses e dissertações.
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1. Treatment of wastewater containing chlorophenols by photo-Fenton advanced oxidation process. / Tratamento de efluentes aquosos contendo clorofenóis por meio de processo oxidativo avançado foto-Fenton.
In recent years, advanced oxidation processes (AOP) have emerged as potentially powerful methods to transforming organic pollutants into harmless substances. The present work aims to study the degradation of chlorophenols (2,4-dichlorophenol and pentachlorophenol) in aqueous solution by the photo-Fenton process. The experiments were conducted in a batch recy
Publicado em: 2009
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2. Preparation, characterization and aplication of anodes of nominal composition Ti/RuyTi(1-y-x)SnxO2 in the degradation electrochemical of chlorophenols / Preparação, caracterização e aplicação de ânodos de composição nominal Ti/RuyTi(1-y-x)SnxO2 na degradação eletroquímica de clorofenóis
In this work oxides electrodes of nominal composition Ti/RuyTi(1-y-x)SnxO2 were prepared by thermal decomposition (400 °C) by three different routes: Traditional Method using inorganic precursors dissolved in either Isopropanol (MT/ISO) or a solution of HCl 1:1 (v/v) (MT/HCl) and the Polymeric Precursors Method (MPP).Oxides coatings were characterized by Sc
Publicado em: 2007
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3. Degradation of chlorophenols by a defined mixed microbial community.
Synthetic sewage containing phenol, acetone, and alkanols plus 4-chlorophenol or a mixture of isomeric chlorophenols is completely degraded by a defined mixed culture with Pseudomonas sp. strain B13 as a chlorocatechol-dissimilating member of the community. Total degradation of the organic carbon was indicated by release of stoichiometric amounts of chloride
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4. Degradation and O-methylation of chlorinated phenolic compounds by Rhodococcus and Mycobacterium strains.
Three polychlorophenol-degrading Rhodococcus and Mycobacterium strains were isolated independently from soil contaminated with chlorophenol wood preservative and from sludge of a wastewater treatment facility of a kraft pulp bleaching plant. Rhodococcus sp. strain CG-1 and Mycobacterium sp. strain CG-2, isolated from tetrachloroguaiacol enrichment, and Rhodo
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5. Anaerobic Degradation of Chloroaromatic Compounds in Aquatic Sediments under a Variety of Enrichment Conditions †
Anaerobic degradation of monochlorophenols and monochlorobenzoates in a variety of aquatic sediments was compared under four enrichment conditions. A broader range of compounds was degraded in enrichments inoculated with sediment exposed to industrial effluents. Degradation of chloroaromatic compounds was observed most often in methanogenic enrichments and i
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6. Chlorophenol degradation coupled to sulfate reduction.
We studied chlorophenol degradation under sulfate-reducing conditions with an estuarine sediment inoculum. These cultures degraded 0.1 mM 2-, 3-, and 4-chlorophenol and 2,4-dichlorophenol within 120 to 220 days, but after refeeding with chlorophenols degradation took place in 40 days or less. Further refeeding greatly enhanced the rate of degradation. Sulfat
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7. Limited degradation of chlorophenols by anaerobic sludge granules.
To better understand the fate of chlorophenols treated in upflow anaerobic sludge bed reactors, we examined the ability of sludge granules from such bioreactors to degrade two trichlorophenols and one dichlorophenol in batch incubations under controlled conditions. Biodegradation was primarily limited to two distinct activities, reductive dehalogenation of o
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8. Purification and characterization of chlorophenol 4-monooxygenase from Burkholderia cepacia AC1100.
Burkholderia (formerly Pseudomonas) cepacia AC1100 mineralizes the herbicide 2,4,5-trichlorophenoxyacetate (2,4,5-T), and the first intermediate of 2,4,5-T degradation is 2,4,5-trichlorophenol. Chlorophenol 4-monooxygenase activity responsible for 2,4,5-trichlorophenol degradation was detected in the cell extract. The enzyme consisted of two components separ
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9. Improved Degradation of Monochlorophenols by a Constructed Strain
Pseudomonas sp. strain B13, a strain able to degrade 3-chlorobenzoate and, after prolonged adaptation (40 days), 4-chlorophenol, could transfer the ability to degrade chlorocatechols to a recipient, Alcaligenes sp. strain A7, which is able to grow with benzoate and phenol. Representative transconjugants, such as Alcaligenes sp. strain A7-2, were able to util
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10. Isolation of Pseudomonas pickettii strains that degrade 2,4,6-trichlorophenol and their dechlorination of chlorophenols.
Three strains of Pseudomonas pickettii that can grow with 2,4,6-trichlorophenol (2,4,6-TCP) as the sole source of carbon and energy were isolated from different mixed cultures of soil bacterial populations that had been acclimatized to 2,4,6-TCP. These strains released 3 mol of chloride ion from 1 mol of 2,4,6-TCP during the complete degradation of the TCP.
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11. O-Methylation of Chlorinated para-Hydroquinones by Rhodococcus chlorophenolicus
Rhodococcus chlorophenolicus PCP-I, a degrader of polychlorinated phenols, guaiacols (2-methoxyphenols), and syringols (2,6-dimethoxyphenols), was shown to O-methylate the degradation intermediate, a chlorinated para-hydroquinone, into 4-methoxyphenol. O-methylation was constitutively expressed, whereas the degradation of chlorophenols and chlorohydroquinone
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12. 31P nuclear magnetic resonance studies of effects of some chlorophenols on Escherichia coli and a pentachlorophenol-degrading bacterium.
A Flavobacterium sp. that mineralizes pentachlorophenol degrades some, but not all, of the other chlorinated phenols. Whole-cell 31P nuclear magnetic resonance was used to compare and observe transmembrane pH gradients and nucleotide pools in the Flavobacterium sp. and Escherichia coli after pentachlorophenol and 3,4,5-trichlorophenol were added to the cell