Cracking Catalytic
Mostrando 1-12 de 63 artigos, teses e dissertações.
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1. PREPARATION AND SIMULATION OF THE ON-LINE SiO2/S COATING FOR COKING INHIBITION IN THE INDUSTRIAL CRACKING FURNACE
Abstract Coke formation inside radiant coils is one of the main problems during thermal cracking of hydrocarbons. The on-line preparation of the coating for coking inhibition is a promising technology because it provides more flexibility to the operators on site. The SiO2/S coating was prepared on the inner surface of coils in an 8-year-served GK-VI industri
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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2. Catalytic Cracking of Soybean Oil for Biofuel over γ-Al2O3/CaO Composite Catalyst
In this paper, we report the catalytic cracking of soybean oil for biofuel over γ-Al2O3/CaO composite catalysts. The influence of catalysts, cracking temperature and weight hourly space velocity (WHSV) on the products distribution were investigated. The maximum yield (70.0 wt.%) of biofuel with low acid value (6.7 mg KOH g-1) and oxygen content (5.6%), as w
J. Braz. Chem. Soc.. Publicado em: 2019-02
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3. Electroremediation of deactivated catalysts from fluidised catalytic cracking for vanadium removal - the effect of a dual cathode chamber reactor
Abstract The aim of this study was to evaluate the quantity of vanadium removed through electrokinetic remediation applied to catalyst waste used in a fluid catalytic cracking process. In excess, vanadium affects process efficiency by reducing the catalyst’s activity, causing deactivation and reducing its useful life in petroleum cracking during refining.
Braz. J. Chem. Eng.. Publicado em: 2018-01
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4. Oxidative Desulfurization of Gasoline by Ionic Liquids Coupled with Extraction by Organic Solvents
In this work, desulfurization of real fluidized catalytic cracking (FCC) gasoline was investigated in dual steps; first in oxidative desulfurization (ODS) using imidazolium and pyrrolidonium based Brønsted acidic ionic liquids (ILs) as solvent and catalyst and hydrogen peroxide as oxidant. In second step, extractive desulfurization took place using organic
J. Braz. Chem. Soc.. Publicado em: 2016-06
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5. ACIDIC REMOVAL OF METALS FROM FLUIDIZED CATALYTIC CRACKING CATALYST WASTE ASSISTED BY ELECTROKINETIC TREATMENT
AbstractOne of the main uses of catalysts in the oil industry is in the fluidized catalytic cracking process, which generates large quantities of waste material after use and regeneration cycles and that can be treated by the electrokinetic remediation technique, in which the contaminant metals are transported by migration. In this study, deactivated FCC cat
Braz. J. Chem. Eng.. Publicado em: 2015-06
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6. Comparing Thermal-Cracking and Catalytic Hydrocracking in the Presence of Rh and Ru Catalysts to Produce Liquid Hydrocarbons from Vegetable Oils
Neste trabalho descrevemos a obtenção de hidrocarbonetos líquidos por meio do hidrocraqueamento catalítico de óleo de soja, dendê e mamona, na presença e ausência de catalisadores nanoparticulados de rutênio e ródio. A reação realizada a 200 ºC leva somente à hidrogenação de ligações duplas C=C. No entanto, a 400 ºC, foi observada a decomp
J. Braz. Chem. Soc.. Publicado em: 2014-12
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7. Kaolin and commercial fcc catalysts in the cracking of loads of polypropylene under refinary conditions
The efficiency of Commercial FCC catalysts (low, medium and high activities) was evaluated by the catalytic cracking process of combined feeds of polypropylene (PP) and vaseline, using a microactivity test unit (M.A.T.) for the production of fuel fractions (gasoline, diesel and residue). The PP/vaseline loads, at 2.0% and 4.0% wt, were processed under refine
Braz. J. Chem. Eng.. Publicado em: 2013-12
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8. Metodologia para aplicar LES ao craqueamento catalítico fluido em um reator riser industrial / Large eddy simulation application methodology to a fluid catalytic cracking industry reactor
The main objective of this thesis is to propose a methodology in how to apply Large Eddy Simulation (LES) on a unit of catalytic cracking. In order to achieve this, it was proposed an alternative way of constructing the computational mesh, by using quasi-uniform meshes. The proposed meshes were implemented to minimize the computational effort and procedure f
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 14/09/2012
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9. Simulação de Reações de craqueamento catalítico e térmico em riser industrial / Simulation catalytic and thermal cracking reactions at industrial riser
The dynamic behavior of a FCC (Fluidized Catalytic Cracking) industrial reactor was simulated employing 3D gas-solid ow models and applying the ten-lumps kinetic model developed by JACOB et al.(1976). The uid-dynamic and the chemical reactions predicted were validated with a set of plant data publicated in literature. Besides, there were added thermal cracki
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/01/2012
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10. Estudo computacional da dinâmica do escoamento reativo em risers industriais de FCC / Computational study of the dynamics of the reactive flow in FCC industrial risers
O craqueamento catalítico fluido (FCC) é um dos processos de maior importância da indústria do refino de petróleo, já que converte as frações pesadas de baixo valor comercial provenientes de outros processos de refino, em produtos comercialmente mais importantes, como gasolina, GLP e diesel. Atualmente, com o aumento da demanda por combustíveis fós
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/01/2012
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11. Yield of aromatics from naphthenics upon catalytic cracking
Cis- e trans decalina foram submetidas à reação com catalisadores de craqueamento, para estudar a formação de aromáticos numa fração particular de produtos líquidos do processo de craqueamento catalítico fluido (FCC). Um reator batelada em leito fluidizado, CREC, foi usado a 673 e 723 K com tempos de contato entre 3 e 15 s. Cis-decalina foi muito m
Journal of the Brazilian Chemical Society. Publicado em: 2012-07
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12. Dynamic optimization of a FCC converter unit: numerical analysis
Fluidized-bed Catalytic Cracking (FCC) is a process subject to frequent variations in the operating conditions (including feed quality and feed rate). The production objectives usually are the maximization of LPG and gasoline production. This fact makes the FCC converter unit an excellent opportunity for real-time optimization. The present work aims to apply
Brazilian Journal of Chemical Engineering. Publicado em: 2011-03