Copper Complex
Mostrando 1-12 de 219 artigos, teses e dissertações.
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1. Study of the CuII Affinity by Three Chelating Agents of Biological Interest: TPEN, TRIEN and Et2DTC
Copper is an important micronutrient, and it is present in some protein structures, as well as participate in several important biological processes. Due to its importance, some ligands are used and studied like carriers of copper in the biological systems. This work has investigated the affinity of CuII by three ligands of biological interest: N, N, N, N’
J. Braz. Chem. Soc.. Publicado em: 2021-04
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2. Synergistic Supramolecular Effect on the Electro-Oxidation of Biological Relevant Molecules: A Novel Sensor for Simultaneous Determination of Epinephrine and Uric Acid in Human Urine Using MWCNT and a Copper(II) Complex
In this paper a novel supramolecular strategy to improve the efficiency of a voltammetric sensor to determine two biologically relevant molecules (epinephrine (EP) and uric acid (UA)) is presented. The strategy is based on the use of a glassy carbon electrode modified with a copper(II) complex ([Cu(H2dimpy)Cl]PF6) adsorbed on multi-walled carbon nanotubes (M
J. Braz. Chem. Soc.. Publicado em: 2020-11
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3. Tópicos Emergentes em Insuficiência Cardíaca: Terapias Intervencionistas na Insuficiência Cardíaca
In this paper a novel supramolecular strategy to improve the efficiency of a voltammetric sensor to determine two biologically relevant molecules (epinephrine (EP) and uric acid (UA)) is presented. The strategy is based on the use of a glassy carbon electrode modified with a copper(II) complex ([Cu(H2dimpy)Cl]PF6) adsorbed on multi-walled carbon nanotubes (M
Arq. Bras. Cardiol.. Publicado em: 2020-11
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4. SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY OF NEW Cu (II), Co (II) AND Sn (II) COMPLEXES WITH THE SODIUM HYDROTRIS(2-MERCAPTOTHIAZOLYL)BORATE LIGAND
The emergence of antibiotic resistance among microbial pathogens is a serious public health problem, resulting in a constant need of discovering new antibiotics. For this purpose, we synthetized and determined the antimicrobial activity of copper (Cu), cobalt (Co), and tin (Sn) complexes coordinated with scorpionate ligand in a tridentate mode against microo
Quím. Nova. Publicado em: 2020-05
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5. Evaluation of a Graphite-Polyurethane Composite Electrode Modified with Copper Nanoparticles as an Amperometric Flow Detector in a Wall-Jet System for the Determination of Cysteine
A graphite-polyurethane composite electrode (GPUE) was modified by electrodeposition of copper nanoparticles (CuNP) followed by electrochemical treatment in NaOH (GPUE-CuNP), in order to prepare an amperometric sensor for the determination of cysteine (Cys). Cyclic votammograms of Cys solutions at GPUE-CuNP allowed the description of a sequence of electroche
J. Braz. Chem. Soc.. Publicado em: 2020-02
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6. New Metal-Organic Systems with a Functionalized Oxamate-Type Ligand and MnII, FeII, CuII and ZnII
Four new complexes of formula [Fe(H2pcpa)2(H2O)2] (1), {[Mn(Hpcpa)(H2O)3]•1/2H2O}n (2), {[Zn(Hpcpa)(H2O)3]•1/2H2O}n (3) and [Cu2(Hpcpa)2(bipy)2]•8H2O (4) [H3pcpa = N-(4-carboxyphenyl)oxamic acid; bipy = 2,2¢-bipyridine] have been synthesized and their structures determined by X-ray diffraction. The structure of 1 consists of mononuclear iron(II) units
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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7. Direct sequencing of blocks in stochastic models with multi-mines and multi-destinations
Abstract Mining Scheduling is the one that maximizes profit from mining over time. By means of computational methods, the deposit is discretized in blocks and algorithms are used to consummate this objective. The methods that are widely known nowadays for mining scheduling optimization of a discrete block model were based on graph theory, and among those mos
REM, Int. Eng. J.. Publicado em: 16/09/2019
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8. Chemosensor Development of Cu2+ Recognition Using 1,5-Diphenylthiocarbazone: Optimization, COSMO-RS and DFT Studies
The sensitive and selective chemosensor for copper(II) ions (Cu2+) was successfully optimized using the 1,5-diphenylthiocarbazone (DPT) compound. The result showed that dimethyl sulfoxide (DMSO) in a 9:1 (DMSO:water) ratio at a pH of 3 was the optimum medium for DPT to act as chemosensor of Cu2+ recognition. The DPT chemosensor did not encounter any interfer
J. Braz. Chem. Soc.. Publicado em: 16/09/2019
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9. Potential of hydrogen (pH) differentially modulates cadmium stress response in abscisic acid-deficient sitiens tomato mutant
ABSTRACT Uptake of nutrients and cadmium (Cd) are dependent upon many factors, including plant species, ions concentration and pH. Tolerance to Cd-induced oxidative stress can be modulated by phytohormones such as abscisic acid (ABA), which induce the production of reactive oxygen species, activating proteins and enzymes involved in stress response and possi
Bragantia. Publicado em: 05/08/2019
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10. Effect of cold-working process on cyclic deformation of electrolytic copper
Abstract Cyclic softening and hardening processes are expressed by the change in the stress amplitude necessary to cause a given strain amplitude. Understanding the cyclic stress-strain behavior of materials is an important step in the complex study of their fatigue behavior. The potential differences between the defect structures of cold-formed materials ma
REM, Int. Eng. J.. Publicado em: 19/06/2019
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11. Performance and Surface Integrity of Wire Electrical Discharge Machining of Thin Ti6al4v Plate Using Coated and Uncoated Wires
Wire Electrical Discharge Machining (WEDM) is one of the most important production technologies to manufacture very accurate small components and tools on any electrical conductive material. Titanium and its alloys have been widely used in automobile and aerospace industry as well as in medical engineering field. Small components and tools with complex geome
Mat. Res.. Publicado em: 03/06/2019
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12. Linking gemology and spectral geology: a case study of elbaites from Seridó Pegmatite Province, Northeastern Brazil
Abstract reflectance spectroscopy is a fast tool for mineral identification and classification. We conducted spectral characterization of elbaite samples (n = 30) from Seridó Pegmatite Province, Borborema Province, NE Brazil, using a FieldSpec portable instrument and geochemical data from electron probe microanalysis. Visual interpretation of reflectance sp
Braz. J. Geol.. Publicado em: 13/05/2019