Copper Catalysts
Mostrando 1-12 de 44 artigos, teses e dissertações.
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1. Synthesis of delafossite CuCrO2 via solution combustion method and its acid functionalization for biodiesel production
Abstract CuCrO2 was synthesized by solution combustion synthesis (SCS) and applied as a heterogeneous catalyst to produce soybean biodiesel. The combustion reaction was carried out using urea as a fuel, and copper (II) and chromium (III) nitrates as precursors. After the powders’ obtention, these were calcined and functionalized in an acidic medium. The po
Cerâmica. Publicado em: 2023
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2. Effects of Polycyclic Aromatic Hydrocarbon Pendant-Armed Ligands on the Catecholase Activity of Dinuclear Copper(II) Complexes
Herein, we present three new binuclear copper(II) complexes containing different polycyclic aromatic hydrocarbons, able to catalyze the oxidation of 3,5-di-tert-butylcathecol, a model substrate for catechol oxidase. The ligands and complexes were successful characterized in solid and solution states. The structure of C1 was determined by X-ray crystallograph
J. Braz. Chem. Soc.. Publicado em: 2021-05
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3. Study of the structural and morphological properties of copper catalysts supported on Al2O3 and TiO2 synthesized by the impregnation method
ABSTRACT Aluminum oxide and titanium oxide are widely used as catalytic support. Due to their characteristics and properties, they have several applications such as chemical processes, photocatalysis and pollution control. In this work, the catalytic supports of Al2O3 and TiO2 were impregnated with 2% of copper oxide by the method of impregnation. The cataly
Matéria (Rio J.). Publicado em: 20/05/2019
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4. Carbon Nanotube-Supported Copper-Cobalt Catalyst for the Production of Higher Carbon Number Alcohols through Carbon Monoxide Hydrogenation
A series of carbon nanotube (CNTs)-supported copper-cobalt catalysts were prepared and investigated in a slurry reactor for their ability to selectively convert syngas into higher carbon number alcohols. The 7.5Cu7.5Co/CNTs catalyst achieved superior selectivity towards the formation of ethanol (30.1%) and C2+ alcohols (57.7%), while the 10Co5Cu/CNTs catalys
J. Braz. Chem. Soc.. Publicado em: 2018-07
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5. Electrocatalytic Oxidation Removal of Phenol from Aqueous Solution with Metal Oxides Doped Carbon Aerogel
Metal oxides (manganese oxide, MnO, manganese dioxide, MnO2, copper oxide, CuO, zinc oxide, ZnO and nickel oxide, NiO) doped carbon aerogel (CA) were prepared and used as catalysts in heterogeneous oxidation of phenol from aqueous solution in a three-dimensional (3D) electrode reactor. Textural characterization of metal oxides doped CA showed that the metal
J. Braz. Chem. Soc.. Publicado em: 2018-04
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6. Evaluation of nickel and copper catalysts in biogas reforming for hydrogen production in SOFC
ABSTRACT The solid oxide fuel cells (SOFC) enable the efficient generation of clean energy, fitting the current requirements of the growing demand for electricity and for the environment preservation. When powered with biogas (from digesters of municipal wastes), the SOFCs also contribute to reduce the environmental impact of these wastes. The most suitable
Matéria (Rio J.). Publicado em: 22/05/2017
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7. SELECTIVE HYDROGENOLYSIS OF GLYCEROL TO PROPYLENE GLYCOL IN A CONTINUOUS FLOW TRICKLE BED REACTOR USING COPPER CHROMITE AND Cu/Al2O3 CATALYSTS
The glycerol hydrogenolysis reaction was performed in a continuous flow trickle bed reactor using a water glycerol feed and both copper chromite and Cu/Al2O3 catalysts. The commercial copper chromite had a higher activity than the laboratory prepared Cu/Al2O3 and was used for most of the tests. Propylene glycol was the main product with both catalysts, aceto
Quím. Nova. Publicado em: 2017-05
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8. Gas-Phase Conversion of Glycerol to Acetol: Influence of Support Acidity on the Catalytic Stability and Copper Surface Properties on the Activity
Mesoporous mixed copper-aluminum oxides and copper-silicon oxides were synthesized with polymeric precursors route in order to evaluate the effect of the support acidity on the catalytic stability due to the carbon deposit and the copper surface characteristics on the catalytic activity for the gas-phase conversion of glycerol to acetol. The samples were cha
J. Braz. Chem. Soc.. Publicado em: 2016-12
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9. NON-CRYSTALLINE COPPER OXIDE HIGHLY DISPERSED ON MESOPOROUS ALUMINA: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN GLYCEROL CONVERSION TO ACETOL
Polymeric precursor method and wet impregnation route were applied to synthesize copper and aluminium-based catalysts in order to obtain a material with interesting properties in catalytic reactions. The changes in the structural, morphological and textural properties due to the choice of preparation method were characterized by different techniques, such as
Quím. Nova. Publicado em: 2016-07
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10. OXIDATION OF PHENOL IN AQUEOUS SOLUTION WITH COPPER OXIDE CATALYSTS SUPPORTED ON γ-Al2O3, PILLARED CLAY AND TiO2: COMPARISON OF THE PERFORMANCE AND COSTS ASSOCIATED WITH EACH CATALYST
Abstract The Catalytic Wet Air Oxidation (CWAO) of phenol using copper oxide catalysts supported by γ-Al2O3, TiO2, and pillared clay was evaluated to identify which of these catalysts was the most appropriate for this reaction. The CuO/PILC, CuO/γ-Al2O3 and CuO/TiO2 catalysts were the most successful at removing phenol and resulted in more than 96% convers
Braz. J. Chem. Eng.. Publicado em: 2015-12
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11. Síntese, caracterização e atividade fotocatalítica de catalisadores nanoestruturados de TiO2 dopados com metais
Titanium dioxide nanostructured catalysts (nanotubes) doped with different metals (silver, gold, copper, palladium and zinc) were synthesized by the hydrothermal method in order to promote an increase in their photocatalytic activity under visible light. The catalysts were characterized by X-ray diffraction, diffuse reflectance spectroscopy, transmission ele
Quím. Nova. Publicado em: 2013
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12. Reação de deslocamento de gás d Água sobre catalisadores de cobre e níquel suportados em alumina e nanofibra de carbono / Water gas shift reaction over copper and nickel catalysts supported on alumina and carbon nanofibers
A reação de deslocamento de gás d água, também conhecida como water gas shift reaction (WGSR), é muito utilizada na produção de hidrogênio, por meio da conversão do monóxido de carbono em CO2 e da água em H2. No presente trabalho, catalisadores de cobre e níquel suportados em alumina ou nanofibras de carbono (NFC) foram utilizados para estudo da
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 13/08/2012