Complexation Agent
Mostrando 1-12 de 20 artigos, teses e dissertações.
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1. DEVELOPMENT AND OPTIMIZATION OF A SPECTROPHOTOMETRIC METHOD WITH CLOUD POINT EXTRACTION FOR DETERMINATION OF GADOLINIUM
This work describes a simple, sensible, and low-cost analytical method, based on cloud-point extraction (CPE) of the surfactant (1,1,3,3-Tetramethylbutyl)phenyl-polyethylene glycol (Triton X-114), for the efficient extraction and sensible determination of gadolinium after its complexation with 1-(2-pyridylazo)-2-naphthol (PAN) and subsequent determination by
Química Nova. Publicado em: 2022
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2. SELECTIVE SEPARATION OF Mn(II) AND Cd(II) AS WELL AS REGENERATION OF POLYMER VIA SHEAR INDUCED DISSOCIATION COUPLING WITH ULTRAFILTRATION
Abstract The selective separation of Mn(II) and Cd(II) as well as regeneration of the complexing agent were conducted by shear induced dissociation coupling with ultrafiltration (SID-UF), and the copolymer of maleic acid and acrylic acid (PMA) was used as complexing agent. At the optimal complexation conditions, pH 6 and P/M (mass ratio of polymer to metal i
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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3. ELUCIDATION OF THE ELECTRONIC SPECTRUM CHANGES OF KA-Al3+ COMPLEX BY POTENTIOMETRIC TITRATION, FTIR, 13C RMN AND QUANTUM MECHANICS
Kojic acid (KA) is an organic acid widely used in pharmaceutical industry, mainly as a skin lightening agent. Based on the ability of KA to form complexes with ions, we found the most possible kind of complex formed with cation aluminum. KA-Al3+ complex structures were studied using potentiometric and spectrophotometric (UV) titrations, FTIR and 13C NMR. The
Quím. Nova. Publicado em: 2017-08
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4. Speciation of Chromium in Water Samples after Dispersive Liquid-Liquid Microextraction, and Detection by Means of High-Resolution Continuum Source Atomic Absorption Spectrometry
A newly analytical method has been developed to determine total chromium and speciation of this element in water samples through dispersive liquid-liquid microextraction combined with a high-resolution continuum source flame atomic absorption spectrometry. The most significant variables affecting complexation and extraction were optimized by using response s
J. Braz. Chem. Soc.. Publicado em: 2017-02
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5. OBTENÇÃO E CARACTERIZAÇÃO DE MATERIAL HÍBRIDO ENTRE SÍLICA E CICLODEXTRINAS
The obtention of silica and cyclodextrin hybrid materials was accomplished by refluxing them in xylol using citric acid as a binding agent. The materials were characterized by infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, and elemental analysis. Evidence for the docking of cyclodextrins α and γ was subs
Quím. Nova. Publicado em: 2015-09
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6. Fixação de complexo de ferro II em matriz de poli(acrilato de sódio) / Fixing iron complex II in matrix of poly (sodium acrylate)
Neste trabalho estudou-se a complexação do poli(acrilato de sódio), PAS, com aminpentacianoferrato de sódio,APCF. As reações de complexação ocorreram imediatamente com a formação de uma coloração amarela com total solubilização do polímero na solução 0,032 M molar do complexo. As soluções mostraram-se estáveis por 48 h e após esse perío
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/07/2010
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7. SÍNTESE E ARRANJOS SUPRAMOLECULARES DE COMPLEXOS BIS(TRIAZENIDO) MACROCÍCLICOS E TRIAZENIDO 1-ÓXIDO COM OS CÁTIONS Cu2+, Ni2+, Cu+, K+. / SYNTHESIS AND SUPRAMOLECULAR ARRANGEMENTS OF BIS(TRIAZENIDE) MACROCYCLIC AND TRIAZENIDE 1-OXIDE COMPLEXES WITH Cu2+, Ni2+, Cu+, K+ CATIONS.
This work elaborates on the determination of crystal and molecular structures of four pro-ligands, emphasizing bis(triazenes), triazene 1-oxide and a new class of bis(triazenes) macrocyclic, and eight complexes involving Cu+, Cu2 +, Ni2 + and K+. Pro-ligands triazenes 1-oxide are relatively small and simple molecules. When they are deprotonated they presen a
Publicado em: 2010
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8. Pré-concentração por extração em ponto nuvem para determinação de cádmio em amostras de bebidas por espectrometria de absorção atômica como forno tubular na chama e aerossol térmico / Preconcentration and Determination of Cadmium in Beverage Samples by Cloud Point Extraction and Thermospray Flame Furnace Atomic Absorption Spectrometry detection
In this work, it was evaluated extraction/preconcentration cloud point procedure for cadmium determination in soft drinks samples stored in polyethylene terephthalate (PET) packaging and detection by thermospray flame furnace atomic absorption spectrometry (TS -FF-AAS). For the cloud point preconcentration procedure were used Triton X-114 as surfactant, PAN
Publicado em: 2010
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9. Desenvolvimento tecnologico da extração da sericina e preparação de nanoparticulas para aplicação em cosmeticos / Technological development of sericin extraction and preparation of nanoparticles for cosmetic application
This work presents the development of sericin nanoparticles applied to the cosmetic treatment of hair. The nanoparticles were obtained from sericin solutions, previously extracted from cocoons or silk yarn, and formed through electrostatic complexation with guar gum. The surface of the nanoparticles was modified through the incorporation of cationic surfacta
Publicado em: 2008
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10. Extração em fase sólida de níquel em amostras aquosas e determinação por espectroscopia de reflectância difusa / Solid phase extraction of nickel in aqueous samples and determination by diffuse reflectance spectroscopy
This work aimed at the development and adaptation of a new methodology based on solid phase extraction associated with diffuse reflectance spectroscopy for determination of trace levels of nickel in aqueous samples. The proposed extraction technique involves complexation of Ni2+ ions in aqueous solution on the surface of a solid matrix (naphthalene) saturate
Publicado em: 2008
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11. Combinação das técnicas de precipitação ácida e complexação para obtenção de frações enriquecidas de α-lactoalbumina e β-lactoglobulina do isolado protéico de soro de leite / Combination of the techniques of acid precipitation and complexing for obtaining of enriched fractions of α- lactalbumin and β-lactoglobulin from whey protein isolate of milk
In this work it was studied the effects of the combination of two techniques for proteins recovering, in order to obtain an enriched fraction in α-lactalbumin and an enriched one in β-lactoglobulin, from commercial whey protein isolate (WPI) of cheese. The employed techniques were the acid precipitation and the complexation of calcium ion, present
Publicado em: 2008
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12. Caracterização da atividade antitumoral das tiossemicarbazonas derivadas de N(4)-Metil-Toluil-2-acetilpiridina e de 2-piridinoformamida e seus complexos metálicos: avaliação do potencial radiofarmaceutico / CHARACTERIZATION OF THE ANTITUMURAL ACTIVITY OF THE THIOSEMICARBAZONES DERIVED FROM N(4)-METHYL-TOLYL-2- ACETYLPYRIDINE AND 2-PIRIDINOFORMAMIDE AND ITS METAL COMPLEX: EVALUATION OF THE RADIOPHARMACEUTICAL POTENTIAL.
Thiosemicarbazones have attracted great pharmacological interest because of their biological properties, such as cytotoxic activity against multiple strains of human tumors. The most studied compounds are pyridine-based because of their resemblance to pyridoxal metabolites that attach to co-enzyme B6-dependant enzymes. This work aimed the characterization of
Publicado em: 2008