Cobalt Catalysts
Mostrando 1-12 de 40 artigos, teses e dissertações.
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1. Metal-Supported Niobium Catalysts Investigation for Conversion of Bio-Renewable Glycerol to Organic Compounds
The glycerol oxidative dehydration to organic compounds, especially acrolein and acrylic acid, was studied over vanadium, molybdenum, and cobalt oxides supported on niobium oxide and niobium phosphate catalysts. At 300 °C, the glycerol conversion was 100% over all catalysts tested, and acrolein was the main product observed, without significant deactivation
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Iron Cobaltite (FeCo2O4) Nanocatalysts for Water-Oxidation: Effects of Annealing Temperature on Catalytic Properties
The development of efficient, stable, and non-precious metal water oxidation catalysts (WOCs) is a matter of importance for sustainable energy research. In this work, iron cobaltite (FeCo2O4) nanoparticles were prepared by the coprecipitation method, and we present the effect of heat treatment (250, 350, 450, 650 and 900 °C) on the catalytic properties. Cat
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. Performance of Water Oxidation by 3D Printed Electrodes Modified by Prussian Blue Analogues
The water oxidation is the limiting step in the water-splitting process. Given this scenario, the development of new catalysts is essential in this field. The emergent demand is the use of Earth-abundant elements and catalysts with high performance under mild conditions. Because of this, catalysts such as Prussian Blue analogues (PBA) have been receiving a l
J. Braz. Chem. Soc.. Publicado em: 2020-11
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4. CATALYST PREPARATION METHODS TO REDUCE CONTAMINANTS IN A HIGH-YIELD PURIFICATION PROCESS OF MULTIWALLED CARBON NANOTUBES
Abstract CoMo/MgO catalysts with low loading of cobalt and molybdenum were prepared by incipient wetness impregnation and the sol-gel method for high yield production of carbon nanotubes (CNT). A detailed characterization of the catalysts, as-produced CNT and purified CNT, indicated a relationship between carbon nanotube properties, synthesis and purificatio
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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5. Síntese de CoFe2O4 sobre os suportes MgAl2O4 e ZSM-5 para uso na degradação de poluente orgânico pelo processo foto-Fenton heterogêneo sob irradiação visível e solar
RESUMO Neste trabalho, ferrita de cobalto (CoFe2O4) foi sintetizada sobre aluminato de magnésio (MgAl2O4) e zeólita ZSM-5 e a atividade catalítica desses materiais na reação foto-Fenton visando a decomposição de um poluente orgânico em solução aquosa foi avaliada. Ferrita de cobalto foi sintetizada sobre os suportes pela rota solvotérmica. Os mate
Matéria (Rio J.). Publicado em: 25/11/2019
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6. Catalytic Removal of Toluene from Air Streams by Cobalt Oxide Supported on Sepiolite
Removal of toluene using cobalt oxide supported on sepiolite catalysts was investigated. Deposition precipitation method was used to prepare the catalysts. The catalysts were characterized using X-ray diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis (TGA) and Brunauer-Emmet-Teller meth
J. Braz. Chem. Soc.. Publicado em: 16/09/2019
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7. Carbon Nanotube-Supported Copper-Cobalt Catalyst for the Production of Higher Carbon Number Alcohols through Carbon Monoxide Hydrogenation
A series of carbon nanotube (CNTs)-supported copper-cobalt catalysts were prepared and investigated in a slurry reactor for their ability to selectively convert syngas into higher carbon number alcohols. The 7.5Cu7.5Co/CNTs catalyst achieved superior selectivity towards the formation of ethanol (30.1%) and C2+ alcohols (57.7%), while the 10Co5Cu/CNTs catalys
J. Braz. Chem. Soc.. Publicado em: 2018-07
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8. Catalytic Behaviors of CoII and MnII Compounds Bearing α-Diimine Ligands for Oxidative Polymerization or Drying Oils
The oxidative polymerization of linseed oil was investigated comparing the classical catalysts cobalt(II) 2-ethylhexanoate and manganese(II) 2-ethylhexanoate and their derivatives modified by the presence of chelating nitrogen ligands, i.e., 2,2'-bipyridyl, 2-(acetyl-2,6-diisopropylphenylimine)-pyridine and [N-(2,6-diisopropylphenyl)imine]acenaphthoquinone.
J. Braz. Chem. Soc.. Publicado em: 2018-02
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9. ON THE SYNTHESIS OF MOLYBDENUM CARBIDE WITH COBALT ADDITION VIA GAS-SOLID REACTIONS IN A CH4/H2 ATMOSPHERE
Abstract Due to ever more severe environmental regulations regarding SOx, NOx and other pollutants' emissions, there has been an interest in developing new and improved catalysts for hydroprocessing reactions. Mo2C has been reported to display good selectivity and activity for those reactions, especially for HDS. Addition of another metal to the carbide stru
Braz. J. Chem. Eng.. Publicado em: 2016-09
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10. Catalytic oxidation of volatile organic compounds (n-hexane, benzene, toluene, o-xylene) promoted by cobalt catalysts supported on γ-Al2O3-CeO2
Cobalt catalysts supported on γ-alumina, ceria and γ-alumina-ceria, with 10 or 20%wt of cobalt load, prepared by the wet impregnation method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), field emission transmission electron microscopy (FETEM), N2 adsorption-desorption isotherms (BET/BJH methods), energy-dispersive X-ray
Braz. J. Chem. Eng.. Publicado em: 2014-09
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11. Evaluation of calcined hydrocalumite-type materials as supports of CoMo and NiMo for thiophene hydrodesulfuration reaction
A hydrocalumite-type material (HC) was synthesized by the co-precipitation method, mixing Ca and Al nitrate solutions in a NaOH solution (pH ≅ 11). This solid was characterized by using different physico-chemical techniques such as: Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), temperature programmed reduction (TPR) and BET surf
Mat. Res.. Publicado em: 13/06/2014
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12. Conversão química de no e co sobre catalisadores à base de óxidos de cobalto ou de ferro
Cobalt or iron oxides supported or not on zeolite Hbeta were prepared and evaluated in the reduction reaction of NO by CO in presence of O2, SO2 or H2O. XRD results evidenced the Hbeta structure and the formation of Co3O4 and Fe2O3. TPR-H2 analysis showed complete reduction of cobalt oxide at lower temperatures than for iron oxide. The catalysts are quite ac
Quím. Nova. Publicado em: 2014-04