Co Oxidation
Mostrando 25-36 de 954 artigos, teses e dissertações.
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25. CO Tolerance and Stability of Proton Exchange Membrane Fuel Cells with Nafion® and Aquivion® Membranes and Mo-Based Anode Electrocatalysts
This work presents a CO tolerance study of PtMo/C (70:30, Pt:Mo) and Pt/MoO2-C anode catalysts on proton exchange membrane fuel cells (PEMFC) with Nafion® and Aquivion® ionomer membranes. Results denote improved activity for the hydrogen oxidation reaction (HOR) in the presence of CO on both anode catalysts at 85 ºC. Experiments of identical location tran
J. Braz. Chem. Soc.. Publicado em: 2018-05
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26. Activity and Stability of Dispersed Multi Metallic Pt-based Catalysts for CO Tolerance in Proton Exchange Membrane Fuel Cell Anodes
ABSTRACT Studies aiming at improving the activity and stability of dispersed W and Mo containing Pt catalysts for the CO tolerance in proton exchange membrane fuel cell (PEMFC) anodes are revised for the following catalyst systems: (1) a carbon supported PtMo electrocatalyst submitted to heat treatments; (2) Pt and PtMo nanoparticles deposited on carbon-supp
An. Acad. Bras. Ciênc.. Publicado em: 16/04/2018
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27. Catalytic Behaviors of CoII and MnII Compounds Bearing α-Diimine Ligands for Oxidative Polymerization or Drying Oils
The oxidative polymerization of linseed oil was investigated comparing the classical catalysts cobalt(II) 2-ethylhexanoate and manganese(II) 2-ethylhexanoate and their derivatives modified by the presence of chelating nitrogen ligands, i.e., 2,2'-bipyridyl, 2-(acetyl-2,6-diisopropylphenylimine)-pyridine and [N-(2,6-diisopropylphenyl)imine]acenaphthoquinone.
J. Braz. Chem. Soc.. Publicado em: 2018-02
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28. Preparation of Au/TiO2 Catalyst by a Liquid-Phase Reduction Method for Preferential Oxidation of Carbon Monoxide in a Hydrogen Rich-Stream (CO-PROX reaction)
Au nanoparticles supported on TiO2 were prepared by a liquid-phase reduction method using HAuCl4.3H2O as the Au precursor, TiO2 as the support, a solution of ethylene glycol/water as solvent and reducing agent and sodium citrate as reducing agent and stabilizer. The Au/TiO2 catalysts were prepared using different routes and characterized by Energy-dispersive
Mat. Res.. Publicado em: 18/12/2017
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29. Mentha pulegium crude extracts induce thiol oxidation and potentiate hemolysis when associated to t-butyl hydroperoxide in human’s erythrocytes
ABSTRACT Mentha pulegium (Lamiaceae) tea has been used as a traditional medicine; however, the modulatory effect of M. pulegium extracts on damage to human erythrocytes associated to t-butyl hydroperoxide (t-BHP) exposure remains to be investigated. Accordingly, we perform this study in order to test the hypothesis that aqueous and ethanolic extracts of M. p
An. Acad. Bras. Ciênc.. Publicado em: 11/12/2017
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30. Effect of PANI on Thermal, Mechanical and Electromagnetic Properties of HDPE/LLDPE/PANI Composites
In this work, polyaniline (PANI) in emeraldine-base form, synthesized by chemical oxidation polymerization, was protonated with hydrochloric acid (HCl). Composites based on high-density polyethylene (HDPE) and linear-low density polyethylene (LLDPE) blends with PANI were prepared in molten condition using a torque rheometer. The effect of compatibilizer agen
Mat. Res.. Publicado em: 11/12/2017
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31. Development and Validation of a Stability-Indicating Method for Perillyl Alcohol Incorporated in Poly(lactide-co-glycolide) Nanoparticles and Stress Degradation Studies
Perillyl alcohol has been studied in the treatment of cancer disease. However, its high toxicity is a drawback, which can be overcome by its incorporation in nanostructured systems. The aim of this work was to develop and validate a chromatographic method for determination of perillyl alcohol encapsulation efficiency in a polymeric nanoparticles formulation
J. Braz. Chem. Soc.. Publicado em: 2017-12
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32. Cellulose Oxidation and the Use of Carboxyl Cellulose Metal Complexes in Heterogeneous Catalytic Systems to Promote Suzuki-Miyaura Coupling and C-O Bond Formation Reaction
This work shows the modification of microcrystalline cellulose by the selective oxidation of primary hydroxyl groups to carboxylate groups by a 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated system and its application as a heterogeneous ligand by ionic exchange with catalytic metals ions such as palladium, nickel and copper. Afterwards is desc
J. Braz. Chem. Soc.. Publicado em: 2017-11
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33. Synergistic Effect of Adsorption and Enzymatic Conversion in the Bisphenol-A Removal by Laccase Immobilized on Poly(glycidyl methacrylate-co-ethyleneglycol dimethacrylate)
Carriers with different functional groups (epoxy, aldehyde, ethyldiazonium, phenyldiazonium and amino) were tested for immobilization of T. versicolor laccase on GMA-co-EGDMA (glycidyl methacrylate-co-ethyleneglycol dimethacrylate) microspheres. Laccase immobilized on GMA-co-EGDMA containing the phenyldiazonium functional group showed the highest activity (9
J. Braz. Chem. Soc.. Publicado em: 2017-11
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34. Ethylene glycol oxidation on ternary PtRhNi/C electrocatalyst with different metal compositions
ABSTRACT Direct Alcohol Fuel Cells (DAFC’s) are an alternative to fuel cell systems and when is used alkaline medium this has an increase performance. The alkaline direct alcohol fuel cells (ADAFC's) have some advantages such as low-emission, high energy efficiency, improved oxidation kinetics, low crossover and in addition there is a broad range of materi
Matéria (Rio J.). Publicado em: 20/07/2017
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35. Melipona mondury produces a geopropolis with antioxidant, antibacterial and antiproliferative activities
ABSTRACT Geopropolis is a special type of propolis produced by stingless bees. Several pharmacological properties have been described for different types of geopropolis, but there have been no previous studies of the geopropolis from Melipona mondury. In this study, we investigated the antioxidant, antibacterial, and antiproliferative activities of M. mondur
An. Acad. Bras. Ciênc.. Publicado em: 20/07/2017
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36. Ethylene Glycol Electro-Oxidation on Platinum-Free Surfaces: How the Composition of PdRuRh Surfaces Influences the Catalysis
In this work we performed electrochemical (cyclic voltammetry and chronoamperommetry) and spectroelectrochemical studies (in situ Fourier transform infrared (FTIR)) in PdRuRh electrodeposits in acidic media in presence of ethylene glycol (0.5, 1.0 and 2.0 mol L-1). The electrochemical results show that the ethylene glycol oxidation is sensitive to the compos
J. Braz. Chem. Soc.. Publicado em: 2017-06