Cleanup Methods
Mostrando 1-12 de 29 artigos, teses e dissertações.
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1. A Selective Gas Chromatography-Selected Ion Monitoring Mass Spectrometry (GC-MS/SIM) Method to Determine Polychlorinated Biphenyls in Fuller’s Earth
Polychlorinated biphenyls (PCBs) are carcinogenic to humans and can be found in Fuller’s earth used for the regeneration of used transformer oil. This work describes a highly selective gas chromatographic-selected ion monitoring mass spectrometric method (GC-MS/SIM) for the simultaneous determination of three Aroclor PCB congener mixtures (1242, 1254, and
J. Braz. Chem. Soc.. Publicado em: 2020-03
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2. Determination of Antibiotics Residues in Milk Using a QuEChERS Method Using Full Factorial Design and Liquid Chromatography-Tandem Mass Spectrometry
This study evaluated different methods of extraction based on quick, easy, cheap, effective, rugged and safe (QuEChERS) method for analysis of the antibiotics ceftiofur, cloxacillin and enrofloxacin in milk using ultra-performance liquid chromatography-tandem mass spectrometry. The QuEChERS acetate method has been shown to be inefficient for extracting such
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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3. Green Chemistry Method Based on PARAFAC EEM Data Modeling for Benzo[a]pyrene Quantitation in Distilled Spirit
Benzo[a]pyrene (BaP) is often used as a marker of polycyclic aromatic hydrocarbons (PAHs) in beverages. This marker is often quantified by chromatographic methods, which require sample preparations involving the use of reagents, solvents, extraction, pre-concentration, and/or cleanup steps. In this study, a new method for quantification of BaP in cachaças (
J. Braz. Chem. Soc.. Publicado em: 2019-02
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4. Identification and quantification of genipin and geniposide from Genipa americana L. by HPLC-DAD using a fused-core column
Abstract In this work, it was developed a fast, simple and selective method for quantification of genipin and geniposide from unripe fruits of genipap, which are known as natural colorants, blue and yellow, respectively. The compounds separation was performed in a fused-core C18 column using as mobile phase water (A) and acetonitrile (B) both acidified with
Food Sci. Technol. Publicado em: 19/03/2018
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5. Aplicação da radiação ultravioleta como forma de contribuição para a química verde e construção de um reator fotoquímico alternativo e de baixo custo, para pré-tratamento de amostras
Ultraviolet radiation corresponds to a fraction of electromagnetic radiation, covering wavelengths between 1 and 400 nm. Methods based on UV irradiation have become popular because it is possible to treat samples simply by applying energy, avoiding procedures that require the use of toxic substances, thus contributing to the development of Green Chemistry. T
Quím. Nova. Publicado em: 2014-04
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6. Comparison of High Performance Liquid Chromatography with Fluorescence Detector and with Tandem Mass Spectrometry methods for detection and quantification of Ochratoxin A in green and roasted coffee beans
Two analytical methods for the determination and confirmation of ochratoxin A (OTA) in green and roasted coffee samples were compared. Sample extraction and clean-up were based on liquid-liquid phase extraction and immunoaffinity column. The detection of OTA was carried out with the high performance liquid chromatography (HPLC) combined either with fluoresce
Braz. arch. biol. technol.. Publicado em: 2013-12
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7. Desenvolvimento e aplicação de técnicas miniaturizadas de preparo de amostra na determinação de fármacos no ambiente / Development and application of microextraction sample preparation techniques to determine pharmaceutical drugs in the environment
The occurrence of pharmaceutical drugs in the environment is a worldwide problem caused by the genotoxicity and ecotoxicity activities of those compounds. Water is one of most used natural resource in human activities which explain the presence of emerging contaminants. Those compounds affect not only humans but also aquatic animals that spend the whole life
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/08/2012
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8. Métodos de análise da rosiglitazona e pioglitazona e de seus principais metabólitos: aplicações em estudos de metabolismo in vitro / Methods for the analysis of rosiglitazone and pioglitazone and their metabolites: application to in vitro metabolism studies
Estudos de metabolismo in vitro possuem o intuito de caracterizar e quantificar possíveis metabólitos, elucidar as vias metabólicas e sugerir modelos a serem seguidos para a realização de estudos in vivo. Com o intuito de estudar o metabolismo in vitro não estereosseletivo da rosiglitazona (RSG) empregando fração microssomal de fígado de ratos,foi d
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 02/04/2012
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9. MÉTODOS INDIVIDUAL E MULTIRRESIDUAL PARA DETERMINAÇÃO DE PESTICIDAS EM GRÃOS E DERIVADOS POR GC-PFPD, GC-ITD-MS E LC-MS/MS / SINGLE AND MULTI-RESIDUE METHODS FOR PESTICIDE ANALYSIS IN GRAINS AND DERIVATES BY GC-PFPD, GC-ITD-MS AND LC-MS/MS
Due to the complexity of grains like soybean, corn and rice, and the very low pesticide concentration expected for these samples, it is really necessary to develop efficient and reliable analytical methods to identify and quantify their residues. The possibility to perform the determination of a large number of pesticides in just a single chromatographic ana
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 29/08/2011
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10. ESTUDO COMPARATIVO ENTRE EXTRAÇÃO SOXHLET E ULTRASOM PARA DETERMINAÇÃO DE HIDROCARBONETOS POLICÍCLICOS AROMÁTICOS EM SEDIMENTOS DO ESTUÁRIO DO RIO SERGIPE POR CROMATOGRAFIA A GÁS ACOPLADA A ESPECTROMETRIA DE MASSAS. / COMPARATIVE STUDY OF EXTRACTION SOXHLET AND ULTRASOUND DETERMINATION FOR OIL POLYCYCLIC AROMATIC SEDIMENTS SERGIPE RIVER ESTUARY BY GAS CHROMATOGRAPHY MASS SPECTROMETRY ATTACHED.
Polycyclic aromatic hydrocarbons (PAHs) are compounds that can be found in environmental compartments such as atmosphere, soil, sediment and water. Throughout bioaccumulation, they can also be incorporated into vegetables and animals tissues. They are mainly originated from anthropogenic sources such as fossil fuels and biomass burnings. Due they potential t
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 26/08/2011
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11. Avaliação sistemática do efeito de matriz em ensaios bioanalíticos por LC-MS/MS para a análise de rifampicina em fluidos biológicos / Systematic evaluation of the matrix effect in bioanalytical assays for rifampicin analysis in biological fluids by LC-MS/MS
Bioanalytical assays by LC-MS/MS were conducted in order to investigate the matrix effect (ME) in the analysis of rifampicin (RIF) in biological matrices, human plasma or microsomal fractions, which were submitted to different sample pretreatment procedures: 1) off-line solid phase extraction (SPE), protein precipitation using acetonitrila (PP(ACN)) or metha
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2011
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12. OPTIMIZATION AND VALIDATION OF METHODS USING MSPD, QuEChERS, LC-ESI-MS/MS FOR THE DETERMINATION OF PESTICIDE IN ONION / OTIMIZAÇÃO E VALIDAÇÃO DE METÓDOS EMPREGANDO MSPD, QuEChERS MODIFICADO E LC-ESI-MS/MS PARA DETERMINAÇÃO DE AGROTÓXICOS EM CEBOLA
A cebola (Allium Cepa L) tem grande importância social e econômica. É considerada um alimento funcional devido à presença de compostos bioativos em sua composição. O sistema de plantio empregado é a agricultura familiar. No Brasil a cebola é plantada do sul ao nordeste do país, e os estados de Santa Catarina (SC), Rio Grande do Sul (RS) e Paraná (
Publicado em: 2010