Chemistry Kinetic
Mostrando 1-12 de 53 artigos, teses e dissertações.
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1. ONE-POT DIASTEREOSELECTIVE SYNTHESIS OF CHIRAL TRICYCLIC L-CYSTEINE AND D-PENICILLAMINE DERIVATIVES: A LABORATORY EXPERIMENT
A one-pot diastereoselective synthesis of thiazolidine-ring fused systems derived from enantiomerically pure amino acids, L-cysteine or D-penicillamine, and achiral succindialdehyde is described as an experiment to be carried out by upper-division undergraduate students in a laboratory classroom. Reactions were performed under mild conditions, the products w
Quím. Nova. Publicado em: 2020-01
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2. Films Formed on Carbon Steel in Sweet Environments - A Review
Corrosion of carbon steel pipelines in sweet environments has been extensively researched on oil and natural gas exploration and production in order to obtain efficient corrosion mitigation methods. Although the consequences of corrosion are known, the cause and mechanism by which a certain phenomenon occurs are still not well understood. Sweet corrosion is
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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3. Equipartition of energy, Avogadro law and ratio of specific heats
Abstract The equipartition of energy in its simplest form, which is related to the translational motion of the molecules of a gas, was announced independently by Waterston in 1845 and by Clausius in 1857. In its more general form, it was formulated by Maxwell in 1860. Together with the relation between pressure and translational motion, given by the kinetic
Rev. Bras. Ensino Fís.. Publicado em: 18/02/2019
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4. Flow Analysis: Looking Back and Forward
Flow analysis changed significantly the way of performing chemical analysis by (i) mechanization of analytical procedures in a continuous flowing stream with minimal sample intercontamination; (ii) analytical measurements without attaining chemical equilibria, thus increasing the applicability of kinetic methods and allowing the exploitation of non-quantitat
J. Braz. Chem. Soc.. Publicado em: 2018-05
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5. Introdução à físico-química orgânica utilizando um colorímetro artesanal - uma prática interdisciplinar
Herein, we propose an interdisciplinary experiment for undergraduate course that involves concepts of organic and physical chemistry. Firstly, we propose the synthesis of three nitrophenyl acetates, varying the substituent position. Afterwards, we describe the construction of a homemade colorimeter using inexpensive materials and LED as both emission and det
Quím. Nova. Publicado em: 2017-02
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6. Sawdust Derivative for Environmental Application: Chemistry, Functionalization and Removal of textile dye from aqueous solution
ABSTRACT The adsorption of Violet Remazol 5R (VR 5) on wood sawdust modified with succinic anhydride (SSA) as a function of contact time, pH, and initial dye concentrations was investigated using a batch technique under ambient conditions. The SSA obtained was confirmed by IR spectroscopy, thermogravimetry and 13C NMR, and degrees of substitution (DS) were c
An. Acad. Bras. Ciênc.. Publicado em: 25/08/2016
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7. Determinação de parâmetros cinéticos em fluxo com câmara de gradiente e deteção espectrofotométrica: aplicação à reação entre o violeta de cristal e o ião hidróxido
A didactic experiment is proposed aimed to extend the Flow Injection Analysis (FIA) based methodology to the area of physical chemistry/chemical reactors for undergraduate labs. Our prime objective was to describe the use of a gradient chamber for determination of the rate constant for the reaction between crystal violet and the hydroxide ion. The study was
Quím. Nova. Publicado em: 2013
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8. Ammonium Perchlorate and Ammonium Perchlorate-Hydroxyl Terminated Polybutadiene Simulated Combustion
Abstract: The combustion simulation of ammonium perchlorate was carried out with the software Chemkin, in two steps: the burning behavior of pure ammonium perchlorate and the one of formulated ammonium perchlorate with hydroxyl terminated polybutadiene binder. In both cases, the room pressure varied in order to verify its influence in the system. The burning
J. Aerosp. Technol. Manag.. Publicado em: 2012-03
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9. Planejamento de inibidores da enzima diidroorotato desidrogenase de Trypanosoma cruzi por biocalorimetria / Biocalorimetry as a tool for Trypanosoma cruzi dihydroorotate dehydrogenase inhibitors discovery
A doença de Chagas, causada pelo protozoário flagelado Trypanosoma cruzi, é uma doença tropical que enseja morte/morbidade de milhões de pessoas na América Latina. Por processos migratórios, vem-se estendendo ao sul dos Estados Unidos, Canadá, Europa, Austrália e Japão. Essa doença tem sido considerada super-negligenciada pela indústria farmacêu
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 04/03/2011
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10. Solução via LES de chamas difusivas de metano, metanol e etanol
This work presents a model for a jet diffusion flame, for low Mach and high Damköhler numbers. The model is based on the solution of the flamelet equations for the chemistry and on the mixture fraction for the flow. This model describes well the behavior of diffusion flames, except at the flame tip, where instabilities can often occur. Numerical results are
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2011
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11. Editorial
OH LIF-thermometry was applied to premixed ethanol flames at atmospheric pressure in a burner for three flame conditions. Flame temperatures were simulated from energy equation with PREMIX code of CHEMKIN software package for comparison. A kinetic modeling based on a model validated through chemiluminescence measurements and on a set of reactions for nitroge
Química Nova. Publicado em: 2009
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12. Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular
This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxid
Química Nova. Publicado em: 2009