Chemical And Phase Equilibrium
Mostrando 1-12 de 64 artigos, teses e dissertações.
-
1. LABORATORY INVESTIGATION OF X-RAY PHOTOLYSIS OF METHANOL ICE AND ITS IMPLICATION ON ASTROPHYSICAL ENVIRONMENTS
Methanol (CH3OH) is one of the most abundant organic molecules in astrophysical environments. It has been found in cold regions such as surfaces of comets, ices near young stellar objects and protoplanetary disks, as well as in the gas phase in different regions in space. In this work, we experimentally simulate the methanol ice and its behavior when irradia
Quím. Nova. Publicado em: 2020-05
-
2. DEEP EUTECTIC SOLVENTS BASED ON BETAINE AND PROPYLENE GLYCOL AS POTENTIAL DENITRIFICATION AGENTS: A LIQUID-LIQUID EQUILIBRIUM STUDY
Abstract Two deep eutectic solvents (DES) based on betaine (B) and propylene glycol (PG) in molar ratios of 1:4 and 1:5 were prepared and their physico-chemical properties were determined. Liquid-liquid equilibria at 298.15 K and atmospheric pressure were determined for 13 quasi-three-component systems with a hydrocarbon (n-hexane, n-heptane, i-octane or tol
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
-
3. Liquid-liquid equilibria in aqueous two-phase ethanol/salt systems at different temperatures and their application to anthocyanins extraction
Abstract Aqueous two-phase systems (ATPS) are formed by mixtures of chemical species that, under certain conditions, separate into two immiscible phases, with water as the major component in global terms and, at lower concentrations, polymers, salts, ionic liquids and alcohols, depending on the system type. Different parameters influence ATPS equilibrium suc
Food Sci. Technol. Publicado em: 16/05/2019
-
4. Discharge of Non-Reactive Fluids from Vessels
Abstract This paper presents simulations of discharges from pressure vessels that consistently account for non-ideal fluid behavior in all the required thermodynamic properties and individually considers all the chemical components present. The underlying assumption is that phase equilibrium occurs instantaneously inside the vessel and, thus, the dynamics of
Braz. J. Chem. Eng.. Publicado em: 2017-10
-
5. Solubility measurement and solid-liquid equilibrium model for the ternary system MgBr2 + MgSO4 + H2O at 288.15 K
The solubility of magnesium minerals and the refractive index of the ternary system MgBr2 + MgSO4 + H2O at 288.15 K were investigated using an isothermal dissolution method. It was found that there are two invariant points in the phase diagram and the solubility isotherm of this ternary system consists of three branches, corresponding to equilibrium crystall
Braz. J. Chem. Eng.. Publicado em: 2014-06
-
6. Ab. initio study of the structural, elastic, electronic and optical properties of Cu3N
Electronic, optical, elastic, properties of Copper nitride (Cu3N) in cubic anti- ReO3 phase have been studied using the full-potential augmented plane waves (FP-LAPW) within density functional theory (DFT) framework. Generalized gradient approximation (GGA), local density approximation (LDA), Perdew - Burke - Ernzerhof generalized parameterization of gradien
Mat. Res.. Publicado em: 01/04/2014
-
7. Removal of Cadmium(II) and Lead(II) ions from aqueous phase on sodic bentonite
This paper describes the adsorption of Cd2+and Pb2+ions using sodic bentonite clay type Fluidgel modified. The Fluidgelbefore and after chemical modification and thermal activation was characterized by different techniques including X-ray diffraction, thermal analysis, Fourier transform infrared, surface area, helium pycnometry, cation exchange capacity and
Mat. Res.. Publicado em: 28/01/2013
-
8. Adsorção de o-xileno em argila fluidgel organofílica em fase gasosa / Adsorption of o-xylene onto organoclay fluidgel in gas phase
The industrial growth allied to use of petroleum products generate numerous volatile organic compounds (VOC) that are continuously emitted to the atmosphere, degrading air quality and causing serious problems to human health and environment. Among the VOC, the so-called BTEX (benzene, toluene, ethyl benzene, and xylene), are the most important in terms of to
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/07/2012
-
9. Método da minimização da energia de Gibbs para a modelagem do equilíbrio químico e de fases no processo reacional do biodiesel / Method of minimization of Gibbs energy for the modeling of simultaneous chemical and phase equilibrium in reaction system for biodiesel production process
O presente trabalho tem como objetivo o estudo e aplicação da metodologia da minimização da energia de Gibbs no sistema para o cálculo do equilíbrio de fases, com e sem reação química, para o sistema reacional do biodiesel, utilizando técnicas de otimização global aliadas ao software GAMS, ferramenta computacional utilizada nesta pesquisa. Desse
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 23/03/2012
-
10. Modelagem de equilíbrio líquido-líquido, líquido-vapor e líquido-líquido-vapor para sistemas binários, ternários, quaternários e pseudo-quaternários, envolvendo a produção de biodiesel / Modeling of liquid-liquid, liquid-vapor and liquid-liquid-vapor equilibria for binary, ternary, quarternay and pseudo-quaternary systems involving biodiesel production
The worldwide energy demand increases every year. This demand will reach levels that cannot be supplied by current conventional fossil fuel resources. In this context, biofuels arise as a growing primary source of energy, raising research opportunities and encouraging technology development. An important technical issue related to biofuels development is the
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/01/2012
-
11. Dynamics of gas bubble growth in oil-refrigerant mixtures under isothermal depressurization
This paper proposes a numerical model to predict the growth of gaseous refrigerant bubbles in oil-refrigerant mixtures with high contents of oil subjected to isothermal depressurization. The model considers an Elementary Cell (EC) in which a spherical bubble is surrounded by a concentric and spherical liquid layer containing a finite amount of dissolved liqu
Journal of the Brazilian Society of Mechanical Sciences and Engineering. Publicado em: 2012-06
-
12. Modelagem termodinâmica por extração por solvente de metais divalentes em meio sulfato usando D2EHPA
The extraction of divalent metals (Mn2+, Ni2+, Co2+ and Cu2+) in the system MSO4 - H2SO4 - H2O - D2EHPA in isoparaffin (17/21) was studied by a thermodynamic model based on chemical equilibria with mass and charge balance equations. The activity coefficients of all solutes in the aqueous phase were calculated by Davies equation. By applying this model, the e
Química Nova. Publicado em: 2012