Catalytic Reforming
Mostrando 13-24 de 36 artigos, teses e dissertações.
-
13. Lumping procedure for a kinetic model of catalytic naphtha reforming
A lumping procedure is developed for obtaining kinetic and thermodynamic parameters of catalytic naphtha reforming. All kinetic and deactivation parameters are estimated from industrial data and thermodynamic parameters are calculated from derived mathematical expressions. The proposed model contains 17 lumps that include the C6 to C8+ hydrocarbon range and
Brazilian Journal of Chemical Engineering. Publicado em: 2009-12
-
14. Studies on mixed metal oxides solid solutions as heterogeneous catalysts
In this work, a series of perovskite-type mixed oxide LaMo xV1-xO3+δ powder catalysts (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, and 1.0, with 0.5 < δ < 1.5), prepared by the sol-gel process and calcined at 750ºC, provide an attractive and effective alternative means of synthesizing materials with better control of morphology. Structures of resins obtained during t
Brazilian Journal of Chemical Engineering. Publicado em: 2009-03
-
15. Análise termodinâmica das reformas do metano (oxidativa e autotérmica), do etanol e da nafta
Catalytic reforming of hydrocarbons or other organic species is a technology usually employed in either improving traditional energy sources or producing alternative energy sources. Amongst the technologies employed in improving traditional energy sources, one can include catalytic reforming of petrochemical naphtha. Although being also employed to produce h
Publicado em: 2009
-
16. Desenvolvimento de catalisadores para reforma e oxidação combinadas do metano
In this work, we studied the effects of the promoters of support (ZrO2, La2O3, CeO2, CeO2-ZrO2, CeO2-ZrO2-La2O3 and La2O3) in the nickel catalysts supported on γ-Al2O3 were studied. The supports were prepared by wet impregnation on γ- Al2O3 (Alfa Aesar) with 10% by weight of oxides of cerium, zirconium, lanthanum, ceria-zirconia, ceria-lanthanum an
Publicado em: 2009
-
17. Contribuição ao estudo da reforma a vapor do glicerol em catalisadores Pt/c - efeito do tamanho da partícula de Pt e do Ph da solução de alimentação
Com o aumento da produção de biodiesel, espera-se que grandes quantidades de glicerol estejam disponíveis no mercado a preços razoáveis. Logo, é relevante e promissor a busca de processos que levem o glicerol a produtos de valor agregado. Além disso, o glicerol é considerado uma das 12 moléculas-chaves mais promissoras a serem usadas em futuras bio-
Publicado em: 2009
-
18. Study of nickel catalysts supported on modified ZrO2 applied in reforming reactions / Estudo de catalisadores de níquel suportados em ZrO2 modificados aplicados em reações de reforma
Zirconium dioxide is a material with physics and chemical characteristics that can be applied in many fields, as academic as industrial. In the catalysis, the interest in systems based on zirconia (ZrO2) are growing- up quickly, as a catalyst as a support, considering that ZrO2 properties can be changed by the addition of different cations. The objective of
Publicado em: 2008
-
19. Efeito da concentração de irídio sobre as propriedades de catalisadores do tipo Pt-Ge-Ir/Al2O3. / Effect of concentration of iridium on the properties of type catalysts Pt-Ge-Ir/Al2O3.
The effect of iridium content on the activity, selectivity and stability of platinum, germanium and iridium supported in alumina catalysts for oil naphta catalytic reforming was studied in this work. Samples were prepared by the impregnation of the metallic salts (hexachloroplatinic acid, hexachoroiridic acid and germanium chloride) over g-alumina in order t
Publicado em: 2008
-
20. Produção de hidrogênio a partir da reforma a vapor de etanol utilizando catalisadores Cu/Ni/gama-Al2o3
Cu/Ni/gamma-Al2O3 catalysts were prepared by an impregnation method with 2.5 or 5% wt of copper and 5 or 15% wt of nickel and applied in ethanol steam reforming. The catalysts were characterized by atomic absorption spectrophotometry, X-ray diffraction, temperature programmed reduction with hydrogen and nitrogen adsorption. The samples showed low crystallini
Química Nova. Publicado em: 2007-04
-
21. "Aplicação de catalisadores de níquel e cobalto preparados via precursores do tipo hidrotalcita nas reações de reforma a vapor, oxidação parcial e reforma oxidativa do metano" / "Application of nickel and cobalt catalysts prepared via hydrotalcite-type precursors in the reactions of steam reforming, partial oxidation and oxidative reforming of methane"
One of the most important applications of methane is the syngas production, a mixture of H2 and CO. Three processes can lead to syngas formation from methane: steam reforming, CO2 reforming and partial oxidation. Various non-noble metal catalysts were studied in these processes, although the carbon deposition or the metal sinterization is always observed. Ca
Publicado em: 2007
-
22. Nanopartículas de Co suportadas em SiO2 : síntese, caracterização e propriedades catalíticas para a reforma a vapor do etanol.
Colloidal Co Nanoparticles (Co-NPs) were used to prepare supported Co catalysts. The Co- NPs were obtained by thermal decomposition of the precursor Co2(CO)8 in the presence of oleic acid and trioctylphosphine oxide (TOPO), in an inert atmosphere (Ar). The Co- NPs/SiO2 were obtained by impregnation of a colloidal suspension of nanoparticles on the support no
Publicado em: 2007
-
23. ProduÃÃo de gÃs de sÃntese por tri-reforma do metano em reator de leito fixo
The ever increasing availability of natural gas (NG), and the abundant carbonic gas production, via fermentation of most prepared from sugar cane products (sugar cane juice, and molasses), thermoelectric generators, and refineries have enhanced the research interest of these commodities. The indirect NG conversion processes to synthesis gas (CO and H2), the
Publicado em: 2007
-
24. Reforma autotÃrmica do metano em catalisadores de Ni/CeZrO2/Al2O3 para a produÃÃo de hidrogÃnio
In this work, nickel catalysts supported on CeO2/Al2O3 and CeZrO2/Al2O3 were investigated in reforming autothermal of methane, aiming hydrogen production. Two types of aluminas with different areas were used (Al2O3-D and Al2O3-C). Therefore, two catalysts series were prepared: one was supported on Al2O3-D, and another series supported on Al2O3-C. The charact
Publicado em: 2007