Catalytic Conversions
Mostrando 1-12 de 35 artigos, teses e dissertações.
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1. Magnetic Materials Enriched with Strontium: a Study of the use as Catalysts in the Transesterification Reaction of Babassu Oil
This work described a new magnetic material enriched with strontium as catalyst to produce babassu biodiesel. The use of magnetic materials has attracted attention due to easy and fast separation from reaction medium. Moreover, they are ecologically correct, due to they generate less discards to the environment. Techniques of analysis and characterization we
Mat. Res.. Publicado em: 30/09/2019
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2. NI-MO SUPPORTED NANOPOROUS GRAPHENE AS A NOVEL CATALYST FOR HDS AND HDN OF HEAVY NAPHTHA
ABSTRACT Reducing sulfur and nitrogen compounds is essential in producing clean fuels for providing a green environment. In this regard, a novel nanocatalyst has been proposed for Hydrodesulfurization (HDS) and Hydrodenitrogenation (HDN) of heavy naphtha. To this end, Ni-Mo was loaded on nanoporous graphene (Ni-Mo/NG) through the incipient wetness impregnati
Braz. J. Chem. Eng.. Publicado em: 15/07/2019
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3. Avaliação do tratamento térmico no catalisador magnético Ni0,5Zn0,5Fe2O4 e sua atividade catalítica na produção de biodiesel por transesterificação e esterificação simultânea do óleo de fritura
Resumo O objetivo deste trabalho foi avaliar o efeito do tratamento térmico na síntese do catalisador Ni0,5Zn0,5Fe2O4 e o desempenho catalítico em reações de transesterificação e esterificação simultânea (TES) do óleo de fritura. Os catalisadores foram sintetizados por reação de combustão sem e com tratamento térmico sequencial a 800 °C com t
Cerâmica. Publicado em: 2019-01
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4. Investigation of Low-Temperature Selective Catalytic Reduction of NOx with Ammonia over Mn-Modified Fe2O3/AC Catalysts
A series of iron-based catalysts supported on activated carbon (AC) and manganese-modified Fe2O3/AC catalysts with various Fe:Mn ratios were prepared for selective catalytic reduction (SCR) of NO by ammonia at low temperature. It was found that the addition of a small amount of MnOx into the Fe2O3/AC catalyst contributed to an improvement of the NO conversio
J. Braz. Chem. Soc.. Publicado em: 2018-01
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5. Intercalation of Molybdate Ions into Ni/Zn Layered Double Hydroxide Salts: Synthesis, Characterization, and Preliminary Catalytic Activity in Methyl Transesterification of Soybean Oil
This study reports the synthesis and characterization of a Ni/Zn layered double hydroxide salt intercalated with acetate ions and the subsequent replacement of the acetate ions with molybdate ions via an ion exchange reaction, conducted at two different pH values. Regardless of the pH employed during the synthesis, the basal spacing in the Ni/Zn layered doub
J. Braz. Chem. Soc.. Publicado em: 2017-07
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6. Isopropyl Octanoate Synthesis Catalyzed by Layered Zinc n-Octanoate
Isopropyl octanoate is an ester used in the formulation of cosmetics, foods, medicines, and other products. The peculiar thermodynamic and kinetic factors, allied with the demand for the applications mentioned above, justify the development of an optimized process for its synthesis. In the present article, the esterification of octanoic acid with isopropanol
J. Braz. Chem. Soc.. Publicado em: 2017-06
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7. PROPRIEDADES E AVALIAÇÃO CATALÍTICA DA ZEÓLITA X NANOMÉTRICA CONTENDO CÁTIONS METILAMÔNIO
The reduction of zeolite particle is one of the main features currently searched; it is due to the catalytic gains that these materials come in some reactions. In this work two faujasite zeolites of type X were evaluated, a micrometer and nanometric. Zeolites in sodium form were exchanged ionically with methylammonium cations. These materials were evaluated
Quím. Nova. Publicado em: 2016-07
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8. MICROWAVE ACTIVATION OF IMMOBILIZED LIPASE FOR TRANSESTERIFICATION OF VEGETABLE OILS
This work investigated the effect of microwave irradiation (MW) on the ethanolysis rate of soybean and sunflower oils catalyzed by supported Novozyme 435 (Candida antarctica). The effects of tert-butanol, water addition and oil:ethanol molar ratio on transesterification were evaluated under conventional heating (CH), and under optimum reaction conditions (wi
Quím. Nova. Publicado em: 2015-03
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9. Evaluation of calcined hydrocalumite-type materials as supports of CoMo and NiMo for thiophene hydrodesulfuration reaction
A hydrocalumite-type material (HC) was synthesized by the co-precipitation method, mixing Ca and Al nitrate solutions in a NaOH solution (pH ≅ 11). This solid was characterized by using different physico-chemical techniques such as: Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), temperature programmed reduction (TPR) and BET surf
Mat. Res.. Publicado em: 13/06/2014
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10. Impregnação do ácido 12-tungstofosfórico em sílica - parte II: efeito de diferentes solventes na impregnação e atividade catalítica na esterificação metílica de ácido esteárico
Materials obtained by the immobilization of 12-tungstophosphoric acid (PTA) on silica using the method of impregnation with excess solution in distinct solvents (aqueous HCl, methanol:H2O, and acetonitrile) were evaluated for use as catalysts in the methyl esterification of stearic acid. Optimum conditions were established for the impregnation of 0.5 g (w/w)
Quím. Nova. Publicado em: 2014-04
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11. Produção de biodiesel via transesterificação etílica com zeólitas básicas
Soybean oil transesterification with ethanol was carried out in a batch reactor using USY zeolites modified with barium and strontium (15 wt.%) as catalysts. A series of three catalytic cycles were performed for each zeolite without any loss of activity. The biodiesel product was analyzed by HPLC and FT-Raman, and the catalysts by pyridine and CO2 adsorption
Química Nova. Publicado em: 2012
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12. Alkaline earth layered benzoates as reusable heterogeneous catalysts for the methyl esterification of benzoic acid
This paper describes the synthesis and characterization of layered barium, calcium and strontium benzoates and evaluates the potential of these materials as catalysts in the synthesis of methyl benzoate. The methyl esterification of benzoic acid was investigated, where the effects of temperature, alcohol:acid molar ratio and amount of catalyst were evaluated
Quím. Nova. Publicado em: 2012