Boron Doped
Mostrando 1-12 de 87 artigos, teses e dissertações.
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1. Microstructure and diametral fracture strength of spark plasma sintered WC-6Co-0.2B and WC-6Co-0.5B ceramic composites from nanosized and metastable WC powders
Abstract The present work aimed at evaluating the microstructures and mechanical properties of spark plasma sintered WC-6 wt% Co ceramic composites doped with boron (0.2 and 0.5 wt%). W-50 at% C (W-6.13 wt% C) powders produced under different milling times (20, 60, 180, and 600 min) were used as starting materials and subsequently mixed with Co (6 wt%) and B
Cerâmica. Publicado em: 2022
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2. ELECTROCHEMICAL DETERMINATION OF 2-NAPHTHYLAMINE IN PERFUME SAMPLES USING BORONDOPED DIAMOND ELECTRODE
This work presents a simple electrochemical method for 2-naphthylamine (2NAP) determination in perfume by differential-pulse voltammetry (DPV) employing a boron-doped diamond (BDD) electrode cathodically treated. Simple dilution of sample in supporting electrolyte was performed before electrochemical analysis. A borate buffer solution of pH 10.0 containing 2
Quím. Nova. Publicado em: 2020-03
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3. ELECTROCHEMICAL INCINERATION OF SHORT-CHAIN CARBOXYLIC ACIDS WITH NB‑SUPPORTED BORON DOPED DIAMOND ANODE: SUPPORTING ELECTROLYTE EFFECT INTO THE ELECTROGENERATED OXIDANT SPECIES (HYDROXYL RADICALS, HYDROGEN PEROXIDE AND PERSULFATE)
This work describes the electrochemical oxidation study of three short chain carboxylic acids (acetic, oxalic and formic 0.18 mol L-1) using different electrolysis conditions (electrolyte composition and current density) in an electrochemical reactor fitted with niobiumsupported/BDD electrode (Nb/BBD) as anode and titanium plate as cathode. The experiments w
Quím. Nova. Publicado em: 2020-03
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4. Hydrogen Peroxide Electrogeneration by Gas Diffusion Electrode Modified With Tungsten Oxide Nanoparticles for Degradation of Orange II and Sunset Yellow FCF Azo Dyes
In this work, the gas diffusion electrode (GDE) cathode of Vulcan XC72 carbon modified with nanoparticles of WO2.72 (WO2.72 / Vulcan XC72) was used for H2O2 electrogeneration and degradation of 350 mL of Orange II (OII) and Sunset Yellow FCF (SY) azo dyes by electro-Fenton (EF) and photoelectro-Fenton (PEF) processes with different Fe2+ initial content (1.00
J. Braz. Chem. Soc.. Publicado em: 16/09/2019
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5. BDD-Electrolysis of Oxalic Acid in Diluted Acidic Solutions
Boron doped diamond films (BDD) are the most studied electrocatalytic materials and their efficiency for removing organic compounds is attributed to their ability to produce a large amount of hydroxyl radicals by the electrolysis of water. However, some organic compounds are easy to degrade than others, as well as they also interact with BDD surface. Thus, i
J. Braz. Chem. Soc.. Publicado em: 04/07/2019
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6. DETERMINAÇÃO RÁPIDA E SIMULTÂNEA DE PROPIFENAZONA, PARACETAMOL E CAFEÍNA UTILIZANDO ANÁLISE POR INJEÇÃO EM BATELADA COM DETECÇÃO AMPEROMÉTRICA
A fast and simple procedure for simultaneous determination of propyphenazone (PRO), paracetamol (PAR) and caffeine (CAF) was performed using batch injection analysis with multiple pulse amperometric detection (BIA-MPA). Three potentials pulses were selected for the analysis: +0.90 V/50 ms: only PAR was oxidized; +1.20 V/50 ms: oxidation of PAR and PRO withou
Quím. Nova. Publicado em: 2017-10
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7. AMPEROMETRIC DETERMINATION OF 8-CHLOROTHEOPHYLLINE, CAFFEINE, AND DIPHENHYDRAMINE IN A SINGLE RUN
A simple method for simultaneous determination of 8-chlorotheophylline (CTP), caffeine (CAF), and diphenhydramine (DIP) using batch-injection analysis with multiple pulse amperometric detection (BIA-MPA) is reported. A sequence of three potential pulses (+1.10 V, +1.40 V, and +1.70 V) was applied to the boron-doped diamond working electrode with the acquisit
Quím. Nova. Publicado em: 2017-08
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8. Influence of additives on phase stabilization of scandia-doped zirconia
ABSTRACT The effects of small additions of tin, zinc, calcium and boron oxides on phase composition and electrical conductivity of zirconia-10 mol% scandia were investigated. Compounds containing 1 mol% zinc, tin and calcium oxides and 1, 3 and 5 wt.% boron oxide were prepared by solid state reaction and characterized by X-ray diffraction, density measuremen
Matéria (Rio J.). Publicado em: 01/06/2017
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9. Anodic Oxidation of Sulfide to Sulfate: Effect of the Current Density on the Process Kinetics
The kinetics of the conversion of sulfide to sulfate by electro-oxidation, using a boron-doped diamond (BDD) electrode was studied. Different applied current densities were tested, from 10 to 60 mA cm-2. The results showed that the electrochemical conversion of sulfide to sulfate occurs in steps, via intermediate production of other sulfur species. The oxida
J. Braz. Chem. Soc.. Publicado em: 2017-04
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10. Influence of Supporting Electrolytes on RO 16 Dye Electrochemical Oxidation Using Boron Doped Diamond Electrodes
The influence of different supporting electrolytes as well as of different current densities on RO16 dye electrochemical oxidation using BDD electrodes has been systematically studied. The RO16 azo-dye electrooxidation experiments were performed at different current densities and three different supporting electrolytes: H2SO4 0.1 mol L-1, HClO4 0.1 mol L-1 a
Mat. Res.. Publicado em: 13/03/2017
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11. OXIDAÇÃO ELETROQUÍMICA DOS CORANTES REATIVOS PRETO 5 E AZUL 19 UTILIZANDO UM ELETRODO DE DIAMANTE DOPADO COM BORO NÃO COMERCIAL
We have studied the treatment of Reactive Black 5 (RP5) and Blue 19 (RA19), which are respectively azo and anthraquinone textile dyes, by electrochemical oxidation using a non commercial boron doped diamond electrode supported on titanium metallic with a relation between B and C equal to 15,000 ppm. Pt was used as counter electrode and Ag/AgCl(sat) was the r
Quím. Nova. Publicado em: 2016-11
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12. Simultaneous Voltammetric Determination of Antihypertensive Drugs Amlodipine and Atenolol in Pharmaceuticals Using a Cathodically Pretreated Boron-Doped Diamond Electrode
The simultaneous voltammetric determination of antihypertensive drugs amlodipine besylate (AML) and atenolol (ATN) using a cathodically pretreated boron-doped diamond electrode (CP-BDDE) is reported for the first time. The anodic peak potentials of AML and ATN at a CP-BDDE were found to be 0.727 and 1.32 V (vs. Ag/AgCl (3.0 mol L-1 KCl)) in phosphate buffer
J. Braz. Chem. Soc.. Publicado em: 2016-06