Azeotropic
Mostrando 1-12 de 19 artigos, teses e dissertações.
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1. CONCEPTUAL DESIGN OF NON-IDEAL MIXTURE SEPARATION WITH LIGHT ENTRAINERS
Abstract A method is proposed to study the separation of minimum-, maximum-boiling azeotropic, and low volatility mixtures with a light entrainer, to investigate feasible regions of the key operating parameters reboil ratio (S) and entrainer - feed flowrate ratio (FE/F) for continuous processes. The thermodynamic topological predictions are carried out for 1
Braz. J. Chem. Eng.. Publicado em: 2016-12
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2. Synthesis by coprecipitation of india-stabilized zirconia and codoping with MoO3, WO3, TaO2.5, or NbO2.5 for application as thermal barrier coatings
Coprecipitation synthesis of nanocrystalline india-stabilized zirconia with high surface area and codoping with MoO3, WO3, TaO2.5, or NbO2.5 is reported. The concentration of codopants was defined by the charge-compensating mechanism. Ethanol washing followed by azeotropic distillation and freeze drying were compared as dehydration techniques for the gels. A
Mat. Res.. Publicado em: 05/02/2016
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3. THERMODYNAMIC TOPOLOGICAL ANALYSIS OF EXTRACTIVE DISTILLATION OF MAXIMUM BOILING AZEOTROPES
Abstract This paper provides a feasibility study of azeotropic mixture separation based on a topological analysis combining thermodynamic knowledge of residue curve maps, univolatility and unidistribution curves, and extractive profiles. Thermodynamic topological features related to process operations for typical ternary diagram classes 1.0-2 are, for the fi
Braz. J. Chem. Eng.. Publicado em: 2015-12
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4. Simulation of ethanol extractive distillation with mixed glycols as separating agent
Extractive distillation is an alternative for ethanol dehydration processes that has been shown to be more effective than azeotropic distillation and, in close proximity, to be very competitive against the process that uses adsorption with molecular sieves. Glycols have been shown to be the most effective solvents in extractive distillation, mainly ethylene
Braz. J. Chem. Eng.. Publicado em: 2014-03
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5. Simulação do processo de adsorção psa para separação da mistura etanol-água / Simulation of the adsorption process psa for separation of ethanol-water mixtures
One of the problems with ethanol production is the high energy cost which is associated with the separation of ethanol due to of excess water and the existence of an azeotrope in the mixture ethanol-water, by conventional distillation the mixture can be separated up to 95% weight. Currently, there is great interest in the development of technological process
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 04/07/2011
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6. SIMULAÇÃO DE SISTEMAS DE REFRIGERAÇÃO EM SUPERMERCADOS / REFRIGERATION SYSTEMS SIMULATION IN SUPERMARKETS
A thermodynamic model was developed for the evaluation of energy consumption and environmental impact (LCCP and TEWI) of supermarket refrigeration systems operating in three different configurations (direct expansion, secondary fluid and cascade). The model simulates refrigeration systems operating with pure substances or a mixture (azeotropic or non-azeotro
Publicado em: 2010
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7. Separation of ethanol and water by extractive distillation with salt and solvent as entrainer: process simulation
The aim of this work is to simulate and analyze an extractive distillation process for azeotropic ethanol dehydration with ethylene glycol and calcium chloride mixture as entrainer. The work was developed with Aspen Plus® simulator version 11.1. Calculation of the activity coefficients employed to describe vapor liquid equilibrium of ethanol - water - ethyl
Brazilian Journal of Chemical Engineering. Publicado em: 2008-03
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8. Dehydration by azeotropic distillation of glycerine obtained as byproduct of biodiesel production. / Desidratação por destilação azeotrópica da glicerina obtida como subproduto da produção do biodisel.
O trabalho visa substituir processos comercialmente usados na indústria para purificação da glicerina obtida a partir de biodiesel. A purificação da glicerina até grau técnico ou P.A. (99,5 % em massa) implica em um grande consumo de energia nos processos de evaporação e destilação, pela necessidade de altos vácuos. Como alternativa, a desidrata�
Publicado em: 2008
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9. Condensation in plain horizontal tubes: recent advances in modelling of heat transfer to pure fluids and mixtures
Recent work on improving general thermal design methods for condensation inside plain, horizontal tubes is presented, summarizing primarily the advances proposed at the Laboratory of Heat and Mass Transfer at the EPFL in collaboration with the University of Padova and the University of Pretoria. This work has focused on the development of a unified flow patt
Journal of the Brazilian Society of Mechanical Sciences and Engineering. Publicado em: 2005-03
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10. Modeling and simulation of the pervaporation process for separating azeotropic mixtures / Modelagem e simulação do processo de pervaporação na separação de misturas azeotropicas
In this work, a study of the potential of pervaporation process for the separation of azeotropic mixtures was carries out. Two mathematical models were chosen from the literature for pervaporation process based on solution diffusion mechanism and a study, an evaluation and a comparison between these models were made. Two computational programs were developed
Publicado em: 2005
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11. Desacidificação de oleos de babaçu e de algodão por extração liquido-liquido. / Babassu and cottonseed oils deacidification by liquid-liquid extraction.
The liquid-liquid extraction was used for babassu and cottonseed oil deacidification. For the babassu oil the study was performed based on the equilibrium data determined for systems containing refined babassu oil + lauric acid + ethanol + water at 30°C, varying the water concentration in the solvent (aqueous ethanol with 0.26; 5.57; 10.45; 20.29; 29.72 mas
Publicado em: 2005
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12. Recuperação de acidos graxos livres em resina de troca ionica. / Recuperation of free fatty acids in ion exchange resins.
The drastic operational conditions used in the chemical or physical refining of edible oils can in some cases lead to losses of nutraceutical compounds, high losses of neutral oil or even to the darkening of the end product. Liquid-liquid extration can be used as an alternative refining process, since mild operation conditions are employed in this case. But
Publicado em: 2005