Two-fluid theory and thermodynamic properties of liquid mixtures: Application to simple mixtures of nonelectrolytes
AUTOR(ES)
Brandani, V.
RESUMO
In this last of three articles describing a two-fluid theory of liquid mixtures, the important result is a derivation of local compositions to describe nonrandomness (clustering) of mixing. The model is applied to the system methane/tetrafluoromethane. Although it appears that the two-fluid theory with local compositions may provide an improvement over random-mixing theories, it is likely that the use of local compositions overestimates the effect of nonrandomness.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=346979Documentos Relacionados
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