Tunable Photochemical/Redox Properties of (Phenylthio)ncorannulenes: Application to a Photovoltaic Device

AUTOR(ES)

Steinauer, Angela, Butterfield, Anna M., Linden, Anthony, Molina-Ontario, Agustin, Buck, David C., Cotta, Robert W., Echegoyen, Luis, Baldridge, Kim K., Siegel, Jay S.

FONTE

J. Braz. Chem. Soc.

DATA DE PUBLICAÇÃO

2016-10

RESUMO

The additive substituent effect of phenylmercapto derivatives of corannulene are investigated by spectroscopic, electrochemical, and computational techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.

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