The Modification of (Nd0.5Ta0.5)4+ Complex-Ions on Structure and Electrical Properties of Bi0.5Na0.5TiO3-BaTiO3 Ceramics
AUTOR(ES)
Dou, Runpu
FONTE
Mat. Res.
DATA DE PUBLICAÇÃO
14/03/2019
RESUMO
The (Bi0.5Na0.5)0.94Ba0.06Ti1-x (Nd0.5Ta0.5) xO3 (0.01≤x≤0.05) lead-free ceramics (BNBT-xNT) used (Nd0.5Ta0.5)4+ complex-ions to modify its structure and electrical properties. The BNBT-xNT ceramics exhibit the coexistence of tetragonal and rhombohedral phase. The (Nd0.5Ta0.5)4+ complex-ions prohibit grain growth, and its average grain size decreases from 2.53 µm to 0.84 µm with increasing complex-ion content. The NT doping not only induces the transformation from ferroelectric phase to relaxor ferroelectric phase but also decreases the coercive field and remnant polarization. The permittivity curves are broadened at heavily doping content. The energy storage and strain properties are improved by complex-ions. The maximum energy storage density of 0.475 J/cm3 is obtained at x = 0.035 and 60 kV/cm, the energy storage efficiency achieves the maximum efficiency of 61.5% at x=0.05. As increasing complex-ion content, the typical butterfly-shaped strain curve develops into a sprout-shaped one, and the maximum strain of 0.199% is obtained at x=0.02.
Documentos Relacionados
- Peculiar Properties of Phase Transitions in Na0.5Bi0.5TiO3-xBaTiO3 (0
- Dielectric and Raman spectroscopy studies of (Na0.5Bi0.5)TiO3 lead-free ceramic
- Investigation on Electrical Properties and Microdefects of Nb5+-Doped BaTiO3 Based Ceramics by Positron Annihilation Techniques
- Structural Evolution and Electrical Properties of BaTiO3 Doped with Gd3+
- CARACTERIZAÇÃO ELÉTRICA E DIELÉTRICA DE CERÂMICAS DE BATIO3 E BA0,77CA0,23TIO3 SINTETIZADAS PELO MÉTODO SOL GEL PROTEICO.