Síntese de poli(p-fenilenovinileno)s alcoxilados e sua aplicação em diodos emissores de luz e em sensores de gases / Synthesis of alkoxylated poly(p-phenylenevinylene)s and their application in light emitting diodes and in gas sensors

AUTOR(ES)

Elaine Yuka Yamauchi

DATA DE PUBLICAÇÃO

2006

RESUMO

The present work describes the electrosynthesis of three polymers of the poly(p-phenylenevinylene) (PPV) family, having at least one long chain alkoxy group as substituent. These polymers were characterized by spectroscopic analyses (1H NMR, IR and UV-Vis), thermogravimetry (TG), size exclusion chromatography (SEC), cyclic voltammetry and electrically by current vs. potential plots obtained from metal/polymer/metal sandwich devices. The polymers were tested as active layers in gas sensors for organic vapour analyses aimed for future use in electronic noses. The same polymers were also employed in organic light emitting diodes (OLEDs) in which the luminance and the luminance quantum efficiency were measured. Both the sandwich devices and the OLEDs were made in Curitiba with the collaboration of Prof. Ivo Hümmelgen, head of the Group of Organic Optoelectronic Devices at the Physics Department of the Federal University of Paraná (UFPR).

ASSUNTO(S)

poli(p-fenilenovinileno) poly(p-phenylenevinylene) ppv oled oled sensor de gás polímeros polímero condutor ppv gas sensor polymers conducting polymer

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