Novel Organophosphorus Cage Compound Produced by an Unexpected Oxidative Coupling of 1,2,4-Triphosphole: Crystal and Molecular Structures of Two Isomers of Formula P6C4Bu t4 CHSiMe3
AUTOR(ES)
Araujo, Maria Helena, Rajão, Daniel A., Doriguetto, Antonio C., Ellena, Javier, Castellano, Eduardo E., Hitchcock, Peter B., Caliman, Vinicius
FONTE
Journal of the Brazilian Chemical Society
DATA DE PUBLICAÇÃO
2002-09
RESUMO
Li(P3C2Bu t2) reage com BrCH(SiMe3)2, via adição oxidativa, formando um novo composto organofosforado de fórmula molecular P6C4Bu t4 CHSiMe3 (1). O composto 1 foi caracterizado espectroscopicamente e sua estrutura molecular determinada através de difração de raios X de monocristais. Juntamente com 1, foi caracterizado outro composto (2) com a mesma fórmula molecular, mas apresentando uma estrutura completamente saturada.
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