New Attempts to Synthesize Layered Double Hydroxides Intercalated with SO42-/Cs+ Using Co-Precipitation and Exchange Reactions

AUTOR(ES)
FONTE

Journal of the Brazilian Chemical Society

DATA DE PUBLICAÇÃO

2022

RESUMO

Layered double hydroxides (LDHs) with the compositions (Cs+/NH4+)0.111[M2+0.667Al0.333(OH)2.0 (SO4)0.222] (M2+ = Mn, Zn) and basal distance of ca. 11 Å were obtained by co-precipitating Mn/Al and Zn/Al sulfate salts with aqueous NH3, using excess of Cs2SO4. [Mn0.667Al3+0.333(OH)2]Cl0.333.nH2O and [M2+0.667Al3+0.333(OH)2](NO3)0.333.nH2O (M2+ = Mn, Zn) were also synthesized by co-precipitation, presenting respective basal distances of 8.92 and 7.92 Å. After applying exchange reactions with excess of Cs2SO4, materials with basal distances of ca. 11 Å were obtained, indicating the exchange of chloride and nitrate with sulfate, without incorporation of Cs+. When Na+0.111[M2+0.667Al0.333(OH)2.0(SO4)0.222](M2+ = Mn, Zn) obtained by co-precipitation and having basal distances of ca. 11 Å was exchanged with excess of Cs2SO4, the content of sulfate remained constant and Na+ was partially replaced with Cs+, but the amount was lower, indicating the probable composition (Na+/Cs+)y[M2+0.667Al0.333(OH)2-y(SO4)y/2(SO4)0.222-(y/2)](M2+ = Mn, Zn), where some of the hydroxide anions were replaced with grafted SO42-.

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