Investigação de dioxinas, furanos, hidrocarbonetos policíclicos aromáticos no material particulado e gases emitidos por motores diesel / Investigation of dioxins, furans and polycyclic aromatic hydrocarbons in particulate material and gases emitted by diesel engines.
Raimundo Paiva da Nobrega
DATA DE PUBLICAÇÃO
To investigate emission of chlorinated dioxins and furans (PCDD/Fs) and polycyclic aromatic hydrocarbons (PAHs) in heavy duty diesel engines, through the analysis of particulate material and gases in the exhaust.To verify mutagenicity of collected particulate material and gasesous sample extracts. Material and Methods: The engine emissions tests were done in dynamometer test bench according to 13-Mode Cycle, using brazilian engines, vehicle application. A mini dilution tunnel was used to obtain particulate matter and gaseous sample. PCDD/Fs and PAHs analyses were carried out in a certified national laboratory. Dioxins and furans were analyzed according with Method 8290 (USEPA, 1994) and PAHs by Method TO13A (USEPA, 1999). The mutagenicity analyses were done in accordance with Ames test (TA98) Results: The measurements of dioxins and furans in diesel engines operating in controlled conditions in dynamomter bench test, had indicated emissions values in general below the detention limit of the analytical method. In one of the samples it was verified that the OCDD was above the detention limit, while in another one this occurred for OCDF and 1,2,3,7,8-PeCDF. In relation to 16 PAHs it was verified the presence of the following compounds: Naphthalene, Acenaphthylene, Acenaphthene, Fluorene, Phenanthrene, Antracene, Fluorantene, Pyrene, Benzo[a]antracene, Chrysene, Benzo[b]fluoranthene and Benzo[k]fluorantene. The average value of the sum of PAHs found in five samples was 3,580.5 µg.g-1. The PAHs found in this study indicates some similarity with available literature for values in % and µg/g of particulate matter.The Ames test showed that the collected particulate material from diesel engines presents high mutagenic activity. Conclusion: The emission of PCDD/Fs, for the level of technology of the tested Diesel engines revealed little significant, considering the specified fuel, method of analysis and limit of detention used. In relation to the 16 PAHs, the tests results had indicated that diesel engines has an important contribution in the formation of these compounds. The high mutagenic activity observed shows that the emissions of Diesel vehicles are potentially toxic. The continuity of studies for definition of the regulation of these pollutants is recommended.
- Desenvolvimento de metodologia para avaliação de hidrocarbonetos policíclicos aromáticos e derivados em emissões de motores usando diesel/biodiesel
- Biorremediação de solos contaminados com hidrocarbonetos aromáticos policíclicos
- THE SEASONAL VARIATION IN THE CONCENTRATION OF POLYCYCLIC AROMATIC HYDROCARBONS AND PARTICULATE MATTER PM10 IN THE ATMOSPHERE OF SÃO PAULO
- Caracterização de enzimas bacterianas de degradação de hidrocarbonetos aromáticos policíclicos
- Dioxinas, furanos e PCBs em leite humano no Brasil