Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction

AUTOR(ES)

Gamenara, Daniela, Días, Eduardo, Tancred, Néstor, Heinzen, Horacio, Moyna, Patrick, Forbes, Eric J.

FONTE

Journal of the Brazilian Chemical Society

DATA DE PUBLICAÇÃO

2001-08

RESUMO

É descrita uma síntese eficiente de um aduto de Diels-Alder da tetrametilpurpurogalina (TMPG) e o nitrosobenzeno (NOB). A cinética da decomposição térmica do aduto, que segue um mecanismo de retro-Diels-Alder foi estudada usando espectroscopía de ¹H-RMN.

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