Especiação redox de crômio em amostras de solos contaminados / Redox especiation of chromium in contaminated soil samples
AUTOR(ES)
Natália Tostes Canevari
FONTE
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia
DATA DE PUBLICAÇÃO
21/03/2012
RESUMO
Chromium and its compounds are employed in various industrial processes, and these activities are responsible for the disposal of significant amounts of materials containing this element in the environment. Due to the known toxic feature of Cr(VI) in biological systems, the determination of chromium species has acquired great importance in environmental chemistry. In this study three analytical strategies were combined, X-ray absorption spectroscopy, flame atomic absorption spectrometry and UV-Vis molecular absorption spectrophotometry, in order to identify and determine Cr(III) and (VI) in contaminated soil samples. The samples were collected around the Comandante Ferraz Antarctic Station, a Brazilian scientific station in Antarctica. For the pseudototal chromium analysis, acid digestion was employed for sample preparation and determinations were performed using a flame atomic absorption spectrometer. Na2CO3 0.28 mol L-1 - NaOH 0.5 mol L-1 extractor solution and heating were used for Cr(VI) extraction in the samples, and preliminary identification of this specie was performed using XANES and EXAFS techniques at the Brazilian Synchrotron Light Laboratory. For Cr(VI) determination, NaOH 0.1 mol L-1 and heating were employed for the extraction of the specie, and determinations were based on the reaction of Cr(VI) with the colorimetric reagent diphenylcarbazide in acid medium, using a flow injection analysis system coupled to a molecular absorption spectrophotometer. The quantification of Cr(III) was carried out by subtraction between the pseudototal chromium concentration and Cr(VI) concentration. Results obtained were compared with those calculated from the determination of Cr(VI) with diphenylcarbazide in batch mode. Chromium (VI) concentrations determined in soil samples using both methods were discordant, and these differences were originated from problems occurred in the developed flow injection analysis system.
ASSUNTO(S)
especiação química redox quimica química analítica solos espectrofotometria análise por injeção de fluxo espectroscopia de absorção de raios x
ACESSO AO ARTIGO
http://www.bdtd.ufscar.br/htdocs/tedeSimplificado//tde_busca/arquivo.php?codArquivo=4988Documentos Relacionados
- Redução de cromo hexavalente por bactérias isoladas de solos contaminados com cromo
- Distribuição e biodisponibilidade de crômio em solos contaminados por resíduos de couro
- Reduction treatment of soil and groundwater contaminated with hexavalent chromium
- Especiação de mercurio em solos contaminados por analise de termodessorção acoplada a absorção atomica
- REMEDIATION OF SOIL CONTAMINATED WITH PESTICIDES BY TREATMENT WITH GAMMA RADIATION