Efeito do cromo nas propriedades catalíticas da MCM-41
AUTOR(ES)
Oliveira, Alcineia Conceição, Rangel, Maria do Carmo, Fierro, José Luís Garcia, Reyes, Patrício, Oportus, Marcelo
FONTE
Química Nova
DATA DE PUBLICAÇÃO
2005-02
RESUMO
The effect of chromium on the catalytic properties of MCM-41 was evaluated in order to develop new catalysts for the trimethylbenzene transalkylation with benzene to produce ethylbenzene, a high-value aromatic in the industry. It was found that chromium decreases the specific surface area but increases the acidity, turning MCM-41 into an active and selective catalyst for ethylbenzene and toluene production. The coke produced on the catalyst is hydrogenated and mainly located outside the pores and thus can be easily removed. The catalyst is more active and selective than mordenite, a commercial catalyst, and thus more promising for commercial applications.
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