Degradation of Hydrocarbons by Members of the Genus Candida III. Oxidative Intermediates from 1-Hexadecene and 1-Heptadecene by Candida lipolytica
AUTOR(ES)
Klug, M. J.
RESUMO
Candida lipolytica (Phaff) was grown in a mineral-salts medium amended with either 1-hexadecene or 1-heptadecene as substrate. Intermediates of the same chain length as the substrate were isolated and identified by various analytical procedures. The following intermediates of 16 and 17 carbon atoms were identified: ω-unsaturated acids, ω-unsaturated primary and secondary alcohols, 1,2-epoxides, 1,2-diols, and 2-hydroxy acids. Based on the chemical structure of these compounds, three oxidative mechanisms are proposed for the degradation of long-chain 1-alkenes by this yeast: (i) methyl-group oxidation, (ii) double-bond oxidation, and (iii) subterminal oxidation.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=252424Documentos Relacionados
- Degradation of Hydrocarbons by Members of the Genus Candida II. Oxidation of n-Alkanes and 1-Alkenes by Candida lipolytica
- Degradation of Hydrocarbons by Members of the Genus Candida1: I. Hydrocarbon Assimilation
- Polyribosomes from Peas: III. Stimulation of Polysome Degradation by Exogenous and Endogenous Calcium 1
- METABOLIC CHARACTERIZATION OF THE GENUS BRUCELLA III. : Oxidative Metabolism of Strains That Show Anomalous Characteristics by Conventional Determinative Methods
- THE BIOLOGICAL DEGRADATION OF LIGNIN III. : Bacterial Degradation of alpha-Conidendrin1