Copolymer of acrylonitrile and vinyl-imidazole from the chemical modification of polyacrylonitrile / Obtenção do copolímero de acrilonitrila e vinil-imidazol a partir da modificação química da poliacrilonitrila

AUTOR(ES)
FONTE

IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia

DATA DE PUBLICAÇÃO

28/02/2012

RESUMO

Polymers containing heterocyclic rings such as imidazole, have a great scientific and commercial interest due to its use in several areas. Such polymers can be obtained by chemical modification of polymers such as polyacrylonitrile commercial. Generally, this type of reaction is carried out by conventional heating (thermal). However, more recently, the microwave irradiation is also being used as an energy source for this purpose. This thesis was studied in comparison, the chemical modification of the commercial polyacrylonitrile with ethylenediamine under activation P2S5, using as the heating source, the conventional method (heat) and the microwave radiation generated in a microwave oven for domestic and reactor micro-wave oven (CEM Discover) to produce the copolymer of polyacrylonitrile and 2-vinyl-imidazole. The reactions were carried out at different reaction times, temperatures in the reactor at different microwave powers and different domestic oven. The copolymers produced were characterized by infrared spectroscopy (FTIR) and nuclear magnetic resonance of hydrogen nucleus (NMR-1H). The polyacrylonitrile was chemically modified with success in all methods employed, as verified by its FTIR analysis. The best results were as follows: 48 h of thermal heating 20 min of irradiation of microwaves in domestic oven and 20 min at 80 C in a microwave reactor, however all analyzes indicated a derivatization below 10%

ASSUNTO(S)

polimeros e coloides modificação química de polímeros imidazol poliacrilonitrila modificada micro-ondas chemical modification of polymers imidazole polyacrilonitrile microwave

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