Catalisadores Ni/Al2O3 promovidos com molibdênio para a reação de reforma a vapor de metano

AUTOR(ES)

Maluf, Silvia Sálua, Assaf, Elisabete Moreira, Assaf, José Mansur

FONTE

Química Nova

DATA DE PUBLICAÇÃO

2003-03

RESUMO

Mo-promoted Ni/Al2O3 catalysts for the methane steam reforming reaction were studied in this work. The Ni/Al2O3 catalysts were prepared by precipitation and molibdenum was added by impregnation up to 2%wt. The solids were tested using a micro-reactor under two H2Ov/C conditions and were characterized by ICP-OES, XRD, N2 adsoption, H2 chemisorption and TPR. NiO and NiAl2O4 phases were observed and the metallic area decreased with the increase of the Mo content. From the catalytic tests high stability was verified for H2Ov/C=4.0. On the other hand, only the catalyst containing 0,05% Mo stayed stable during 30 hours of the test at H2Ov/C=2.0.

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