Caracterização de látices acrílicos em função da neutralização de seus grupos carboxilas
AUTOR(ES)
Zilvam Melo dos Santos
DATA DE PUBLICAÇÃO
2007
RESUMO
Latexes based on acrylic acid, acrylamide, ethyl methacrylate, and ethyl acrylate were synthesized via emulsion polymerization with different monomer compositions. The resultant latices were thickened with different molar ratios of NaOH to acrylic acid and were analyzed in terms of acid‐basis titrimetry, turbidimetry, rheology, and tensiometry. Titrimetry, turbidimetry, and rheometry were used to analyze factors such as carboxyl group availability and particle solubilization, tensiometry monitoring the influence of carboxyl neutralization on polymer‐surfactant interactions. For the acrylic acid content used in this work (20 wt%), the results indicated that as carboxyl groups distribution became more homogeneous, the process of latex thickening became more effective
ASSUNTO(S)
rheology. acrylic latex reologia espessamento emulsion polymerization polimerização em emulsão polimeros e coloides látex acrílico thickening
Documentos Relacionados
- Síntese e caracterização de látices acrílicos reticulados com (1,6-diacrilato propoxilato hexanodiol) via polimerização em emulsão
- Caracterização dos grupos econômicos de fato e a responsabilidade de seus componentes
- Caracterização da função de MatE em Gluconacetobacter diazotrophicus.
- Development of Carboxylated Nitrile Latices
- Sintese e caracterização de polimeros acrilicos contenco acrilonitrila, acetato de vinila e metilalilsulfonato de sodio